Separator for an energy store and an energy store

Patent metadata

Field	Value
Publication number	US-10673043-B2
Application number	US-201214234018-A
Country	US
Kind code	B2
Filing date	May 30, 2012
Priority date	Jul 22, 2011
Publication date	Jun 2, 2020
Grant date	Jun 2, 2020

Abstract

A separator for an energy store. The separator may be used in a lithium-sulfur battery in particular. To achieve improved cycle stability, the separator has at least one first layer and at least one second layer, the at least one first layer containing a material having an affine property with respect to at least one active electrode material, and the at least one second layer containing a material having a repellent property with respect to at least one active electrode material. The at least one first layer and the at least one second layer may be situated directly adjacent to one another. Also described is an energy store including the separator.

First claim

What is claimed is:

1. A lithium-sulfur battery comprising:
a cathode including an active electrode material;
an anode;
at least one separator, including:
at least one first layer; and
at least one second layer;

wherein:
each of the at least one first layer contains a material due to which the each of the at least one first layer is affine with respect to, and thereby attracts and does not repel bonding with, the active electrode material of the cathode;
each of the at least one second layer contains a material due to which the each of the at least one second layer is repellant with respect to, and therefore repels and does not attract bonding with, the active electrode material of the cathode;
the at least one first layer and the at least one second layer are situated directly adjacent to one another;
of all of the layers of the separator, one of the at least one second layer is nearest to the cathode;
the at least one first layer contains a conductive additive;
at least one of the at least one second layer does not contain any of the conductive additive;
the at least one second layer contains a polymer functionalized with anionic groups, the polymer being polystyrene or a derivative thereof; and
the at least one first layer contains a polymer having at least one heteroatom.

2. The energy store of claim 1 , wherein the separator has a number of 3+2n layers, and the 3+2n layers are situated in alternation with respect to the first layer and the second layer.

3. The energy store of claim 1 , wherein each of the at least one first layer is situated between a respective pair of the second layers.

4. The energy store of claim 1 , wherein the conductive additive is graphite or carbon black.

5. The energy store of claim 1 , wherein the at least one first layer has a thickness in a range of >1 μm to <100 μm.

6. The energy store of claim 1 , wherein the polymer of the at least one first layer is polyethylene oxide or a derivative thereof.

7. The energy store of claim 1 , wherein the at least one first layer is porous to accommodate a liquid electrolyte.

8. The energy store of claim 1 , wherein the at least one first layer has a thickness in a range of >10 μm to <50 μm or the at least one second layer has a thickness in a range of >10 μm to <50 μm.

9. The energy store of claim 1 , wherein the at least one second layer has a thickness in a range of >1 μm to <100 μm.

10. The energy store of claim 1 , wherein the at least one second layer is porous to accommodate a liquid electrolyte.

11. The energy store of claim 1 , wherein the at least one second layer has a thickness in a range of >10 μm to <50 μm.

12. A lithium-sulfur battery comprising:
a cathode including an active electrode material;
an anode; and
a separator that includes a first layer and second layers between which the first layer is arranged;
wherein:
the first layer of the separator consists of material due to which the first layer is affine with respect to, and thereby attracts and does not repel bonding with, the active electrode material of the cathode;
each of the second layers consists of material due to which the each of the second layers is repellant to, and therefore repels and does not attract bonding with, the active electrode material of the cathode;
the first layer and the second layers are situated directly adjacent to each other;
of all of the layers of the separator, one of the at least one second layers is nearest to the cathode;
each of at least one of the second layers contains a polymer functionalized with anionic groups, the polymer being polystyrene or a derivative thereof; and
the first layer contains a polymer having at least one heteroatom.

13. The energy store of claim 1 , wherein the at least one of the at least one second layer is immediately adjacent the anode.

14. The energy store of claim 1 , wherein:
the at least one second layer includes at least two second layers;
each of the at least one first layer is surrounded by a respective pair of the at least two second layers; and
one of the second layers is nearest, of all of the layers of the separator, to the anode and is the only one of the layers of the separator that does not contain any of the conductive additive.

15. The energy store of claim 1 , wherein:
the at least one first layer contains polyethylene oxide or a derivative thereof; and
the active electrode material is a polysulfide.

16. The energy store of claim 1 , wherein one of the at least one second layer is immediately adjacent to the anode, and none of the at least one first layer is immediately adjacent to the anode.

17. The energy store of claim 1 , wherein the one of the at least one second layer is immediately adjacent to the cathode.

Assignees

• Wegner Marcus
• Grimminger Jens
• Tenzer Martin
• Fanous Jean
• Bosch Gmbh Robert

Inventors

• Wegner Marcus
• Grimminger Jens
• Tenzer Martin
• Fanous Jean

Classifications

• H01M2/1653

  Electricity · mapped topic

• H01M2/1686

  Electricity · mapped topic

• H01M10/052

  Li-accumulators · CPC title

• H01M4/5815

  Sulfides · CPC title

• H01M4/38 Primary

  of elements or alloys · CPC title