Surface modified carbon black to simultaneously improve rolling resistance, wet traction, and wear resistance
US-12116485-B2 · Oct 15, 2024 · US
US10669409B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10669409-B2 |
| Application number | US-201515320894-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 24, 2015 |
| Priority date | Jun 27, 2014 |
| Publication date | Jun 2, 2020 |
| Grant date | Jun 2, 2020 |
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A rubber composition includes a diene rubber (A), a silica (B), a silane coupling agent (C), and an acid-modified polyolefin (D); the diene rubber (A) containing not less than 30 mass % of an aromatic vinyl-conjugated diene copolymer rubber; the acid-modified polyolefin (D) having at least one type of repeating unit selected from the group consisting of propylene, 1-butene, and 1-octene; a content of the silica (B) being from 5 to 150 parts by mass per 100 parts by mass of the diene rubber (A); and a total content of the silane coupling agent (C) and the acid-modified polyolefin being from 5 to 30 parts by mass per 100 parts by mass of the diene rubber (A). Such rubber composition is capable of achieving both excellent vulcanization properties and low heat build-up. A pneumatic tire includes such rubber composition.
Opening claim text (preview).
The invention claimed is: 1. A rubber composition containing a diene rubber (A), a silica (B), a silane coupling agent (C), and an acid-modified polyolefin (D); the diene rubber (A) containing not less than 30 mass % of a styrene butadiene rubber and a butadiene rubber; the acid-modified polyolefin (D) is a maleic acid-modified ethylene/1-butene copolymer; a content of the silica (B) being from 5 to 150 parts by mass per 100 parts by mass of the diene rubber (A); a content of each of the silane coupling agent (C) and the acid-modified polyolefin (D) being not less than 1 part by mass per 100 parts by mass of the diene rubber (A); and a total content of the silane coupling agent (C) and the acid-modified polyolefin being from 5 to 30 parts by mass per 100 parts by mass of the diene rubber (A), wherein a part of the silica (B) and the acid-modified polyolefin (D) are contained as a mixture (E) prepared by mixing the part of the silica (B) and the acid-modified polyolefin (D) in advance, wherein at least a part of the silica (B) in the mixture (E) bonds to an acid-modified site of the acid-modified polyolefin (D). 2. The rubber composition according to claim 1 , wherein a mass ratio of the acid-modified polyolefin (D) and the silica (B) in the mixture (E) is from 100:5 to 100:60. 3. The rubber composition according to claim 1 , wherein a content of the mixture (E) is from 3 to 30 parts by mass per 100 parts by mass of the diene rubber (A). 4. A pneumatic tire comprising the rubber composition according to claim 1 in a structural member thereof.
modified by chemical after-treatment (saponified copolymers C08L23/0861; unsaturated acid salts C08L23/0876) · CPC title
Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title
containing three or more polymers in a blend · CPC title
containing two or more polymers of the same C08L -group · CPC title
Copolymers with styrene · CPC title
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