Porous nanocrystalline cellulose structures

Patent metadata

Field	Value
Publication number	US-10669390-B2
Application number	US-201515114220-A
Country	US
Kind code	B2
Filing date	Jan 29, 2015
Priority date	Jan 29, 2014
Publication date	Jun 2, 2020
Grant date	Jun 2, 2020

Abstract

Provided is a unique class of foam materials characterized by regions of material unidirectionality. The foam materials are configured for a great variety of end-use applications as core materials or as materials in construction of multilayered structures. The novel and ingenious process for making the composite materials of the invention, permits modifying the foam materials to suite any specific end use.

First claim

The invention claimed is:

1. A process for producing nanocrystalline cellulose (NCC) from a cellulose-containing sludge, the process comprising:
contacting the cellulose-containing sludge with acid,
wherein the cellulose-containing sludge is treated with an aqueous sulfuric acid solution comprising 61 to 63% sulfuric acid to form treated cellulose-containing material, said treatment does not alter the morphology of the cellulose present in the cellulose-containing material;
maintaining the treated cellulose-containing material at a temperature of about 50° C. thereby causing preferential degradation of cellulose amorphous domains while maintaining intact the cellulose crystalline domains; and
isolating crystalline NCC;
wherein the only acid that contacts the cellulose-containing sludge consists of sulfuric acid.

2. The process according to claim 1 , wherein the cellulose-containing sludge comprises at least one member selected from the group consisting of paper mill sludge, paper pulp, paper waste water, cellulose source recycled from agricultural or industrial by-products, municipal sludge, municipal sewage, dairy farms sludge, and agricultural cellulosic waste.

3. The process according to claim 1 , wherein the cellulose-containing sludge is treated with the aqueous sulfuric acid solution comprising 62 to 63% sulfuric acid.

4. The process according to claim 1 , wherein the NCC produced is characterized by nanocrystals having an average length of 250±100 nm.

5. The process according to claim 1 , wherein the NCC produced is characterized by a charge in the range of ˜0.3-0.9 mmol/g.

6. The process according to claim 1 , wherein the cellulose-containing sludge is selected from at least one member of the group consisting of paper mill sludge discharged from a paper mill, toilet paper scraps, vegetable fibers, wheat straw, sunflower stalks, garment industry scraps.

7. The process according to claim 1 , wherein the cellulose-containing sludge comprises paper mill sludge discharged from a paper mill.

8. The process according to claim 1 , wherein the cellulose-containing sludge comprises at least one member selected from the group consisting of paper pulp and paper waste water.

9. The process according to claim 1 , wherein the cellulose-containing sludge comprises at least one member selected from the group consisting of cellulose source recycled from agricultural or industrial by-products, municipal sludge, municipal sewage, dairy farms sludge, and agricultural cellulosic waste.

10. The process according to claim 1 , wherein the treated cellulose-containing sludge is maintained with the aqueous sulfuric acid solution comprising 61 to 63% sulfuric acid for 1 to 4 hours.

11. The process according to claim 10 , wherein the isolated crystalline NCC are fibers having an average length of between 150 and 350 nm.

12. The process according to claim 11 , wherein the treated cellulose-containing sludge is maintained with the aqueous sulfuric acid solution comprising 62 to 63% sulfuric acid for 1 to 4 hours.

13. The process according to claim 1 , wherein the cellulose-containing sludge contains between 5 percent and 60 percent of cellulose based on total amount of solid matter.

14. The process according to claim 13 , wherein the cellulose-containing sludge comprises at least one member selected from the group consisting of cellulose source recycled from paper mill waste discharge from paper mills or paper mill sludge discharge from paper mills.

15. The process according to claim 14 , wherein the treated cellulose-containing sludge the sludge is not contacted with acid other than sulfuric acid.

16. The process according to claim 15 , wherein the cellulose-containing sludge is not pretreated prior to contact with sulfuric acid.

17. The process according to claim 1 , wherein the cellulose-containing sludge is not pretreated prior to contact with sulfuric acid.

Assignees

• Yissum Res Dev Co Of Hebrew Univ Jerusalem Ltd
• Melodea Ltd

Inventors

• Lapidot Shaul
• Roth Shalev Sigal
• Slattegard Rikard
• Shoseyov Oded
• Azerraf Clarite
• Braslavsky Ido
• Yashunsky Victor

Classifications

• C08J2201/0484

  the liquid phase being aqueous · CPC title

• C08J2301/00

  Characterised by the use of cellulose, modified cellulose or cellulose derivatives · CPC title

• C08B15/08 Primary

  Fractionation of cellulose, e.g. separation of cellulose crystallites · CPC title

• C08J2301/02

  Cellulose; Modified cellulose · CPC title

• C08J9/28 Primary

  by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum · CPC title