Cellular geopolymer product

Patent metadata

Field	Value
Publication number	US-10669214-B2
Application number	US-201214348331-A
Country	US
Kind code	B2
Filing date	Sep 28, 2012
Priority date	Sep 30, 2011
Publication date	Jun 2, 2020
Grant date	Jun 2, 2020

Abstract

A method for manufacturing a cellular geopolymer product, which method comprises the steps: (a) forming an activated geopolymer premix by addition to a geopolymer premix of an activator compound that initiates a condensation reaction in the geopolymer premix; (b) casting the activated geopolymer premix in a desired configuration; and (c) generating gas bubbles in the activated geopolymer premix as the condensation reaction proceeds and the activated geopolymer premix stiffens to produce a self-supporting cellular structure; and (d) curing the self-supporting cellular structure to produce the cellular geopolymer product, wherein in step (c) the characteristics of the activated geopolymer premix and the reaction kinetics of the condensation reaction are controlled to achieve formation of the self-supporting cellular structure.

First claim

The invention claimed is:

1. A method for manufacturing a cellular geopolymer product, which method comprises the following steps:
(a) forming an activated geopolymer premix by addition to a geopolymer premix of an activator compound that initiates a condensation reaction in the geopolymer premix;
(b) incorporating a gas generating agent in the activated geopolymer premix, wherein (i) the gas generating agent is aluminum powder consisting of aluminum particles having a particle size of 40-80 microns; (ii) the surface of the particles of aluminum powder is oxidized in order to reduce/optimize the reactivity of the aluminum in the activated geopolymer premix; and (iii) wherein the amount of aluminum powder is between about 0.009% and about 0.15% by weight of the activated geopolymer premix;
(c) casting the activated geopolymer premix in a mould in a desired configuration;
(d) allowing gas bubbles to be generated in the activated geopolymer premix as the condensation reaction proceeds and the activated geopolymer premix stiffens to produce a self-supporting cellular structure; and
(e) curing the self-supporting cellular structure to produce the cellular geopolymer product, wherein the geopolymer product has a SiO 2 /Al 2 O 3 molar ratio of 1.5 to 3.5,
wherein the viscosity of the activated premix when generation of gas bubbles in the activated premix is commenced, the rate at which the condensation reaction proceeds and the rate at which gas bubbles are generated in the activated geopolymer premix are controlled to achieve in step (d) formation of the self-supporting cellular structure, and wherein gas bubbles at an upper surface of the activated geopolymer premix are caused to collapse thereby producing a skin on the upper surface of the activated geopolymer premix having a density greater than the remaining activated geopolymer premix.

2. The method of claim 1 , wherein the viscosity of the activated geopolymer premix immediately before casting is 155-175 mm in accordance with ASTMC 1437-07.

3. The method of claim 1 , wherein the temperature of the activated geopolymer premix immediately before casting is 18-34° C.

4. The method of claim 1 , wherein after casting gas generation continues in the premix to achieve a volume increase of the premix of 30-90% (based on the volume of ungassed premix).

5. The method of claim 1 , wherein gas bubbles are generated in the premix by including in the premix aluminium powder and the temperature of the premix is 25 to 45° C.

6. The method of claim 1 , wherein the activated geopolymer premix has a pot life of 10 to 90 minutes.

7. The method of claim 1 , wherein the temperature at which the activated geopolymer premix is formed is from 30 to 40° C.

8. The method of claim 1 , wherein the temperature at which the activated geopolymer premix is formed is less than 30° C.

9. The method of claim 1 , wherein the geopolymer premix comprises an additive to prevent efflorescence in the cellular geopolymer product.

10. The method of claim 1 , wherein collapsing of gas bubbles at an upper surface of the activated geopolymer premix is achieved by using a mould with a lid.

11. The method of claim 1 , wherein collapsing of gas bubbles at an upper surface of the activated geopolymer premix is achieved by screeding, trowelling and/or rolling.

Assignees

• Commw Scient Ind Res Org

Inventors

• Sagoe-Crentsil Kwesi Kurentsir
• Devenish David Alan
• Shapiro Genrietta
• Yan Shiqin
• Gesthuizen Leigh
• Brown Trevor

Classifications

• C04B2111/32

  Expansion-inhibited materials · CPC title

• C04B38/02 Primary

  by adding chemical blowing agents · CPC title

• C04B18/141

  Slags · CPC title

• Y02P40/165

  Cross-Sectional Technologies · mapped topic

• C04B40/0032

  Controlling the process of mixing, e.g. adding ingredients in a quantity depending on a measured or desired value (B28C7/00 takes precedence) · CPC title