Process for producing a synthesis gas

Patent metadata

Field	Value
Publication number	US-10669154-B2
Application number	US-201515524845-A
Country	US
Kind code	B2
Filing date	Oct 6, 2015
Priority date	Nov 6, 2014
Publication date	Jun 2, 2020
Grant date	Jun 2, 2020

Abstract

Process for manufacturing a hydrogen-containing synthesis gas from a natural gas feedstock, comprising the conversion of said natural gas into a raw product gas and purification of said product gas, the process having a heat input provided by combustion of a fuel; said process comprises a step of conversion of a carbonaceous feedstock, and at least a portion of said fuel is a gaseous fuel obtained by said step of conversion of said carbonaceous feedstock.

First claim

The invention claimed is:

1. A process for manufacturing a hydrogen-containing synthesis gas from a natural gas feedstock, comprising the conversion of said natural gas into a raw product gas and purification of said raw product gas, the process having a heat input provided by combustion of a fuel,
wherein said process comprises a step of conversion of a carbonaceous feedstock and at least a portion of said fuel is a gaseous fuel obtained by said step of conversion of said carbonaceous feedstock,
wherein said carbonaceous feedstock is solid or liquid and said step of conversion of said carbonaceous feedstock into gaseous fuel is carried out with a gasification process in a gasifier, said conversion of natural gas into said raw product gas includes a reforming step in a reforming section,
the effluent of said gasifier is used as fuel, not as reforming feedstock, and provides at least part of the total amount of fuel directed to said reforming section.

2. The process according to claim 1 , wherein said carbonaceous feedstock comprises at least one of coal, lignite, coal-derived coke, petroleum coke or heavy fuel oil.

3. The process according to claim 1 , wherein the conversion of said carbonaceous feedstock is carried out with an oxygen-containing stream and water or steam.

4. The process according to claim 1 , wherein the conversion of said solid or liquid carbonaceous feedstock is carried out in a fluidized bed or in a transport reactor.

5. The process according to claim 4 , wherein said conversion is carried out in the presence of a sulphur sorbent.

6. The process according to claim 1 , wherein said gaseous fuel, after the conversion step of said solid or liquid carbonaceous feedstock, is subjected to a purification including at least the removal of solid particles and removal of sulphur compounds, said removal of sulphur compounds being carried out after said removal of solid particles.

7. The process according to claim 1 , wherein a methane-rich stream is removed from said gaseous fuel, and said methane-rich stream is used to provide at least part of the process natural gas feedstock or at least part of the fuel required to drive a gas turbine or gas engine.

8. The process according to claim 1 , wherein at least some of carbon dioxide contained in the gaseous fuel is removed from the gaseous fuel after the conversion of said carbonaceous feedstock.

9. The process according to claim 1 , said conversion of the natural gas including steam reforming, primary reforming, gas heated reforming, secondary reforming, auto-thermal reforming, and/or partial oxidation.

10. The process according to claim 1 , said gaseous fuel being fired in at least one of the following:
one or more burners of a radiant section of a primary reformer;
one or more burners of a convective section of a primary reformer;
one or more burners of a desulphurizer pre-heater arranged to preheat said natural gas before desulphurization and subsequent reforming;
one or more burners of a process fired heater;
one or more burners of an auxiliary steam generator or steam super-heater;
one or more burners of a heat recovery steam generator downstream a gas turbine;
one or more gas turbines.

11. The process according to claim 1 , said hydrogen-containing synthesis gas being used for any of the following: synthesis of ammonia, ammonia-urea synthesis, synthesis of methanol, production of hydrogen, production of carbon monoxide, Fischer-Tropsch products, oxo-alcohols, gasoline.

12. The process according to claim 11 , wherein said hydrogen-containing synthesis gas is used to make a methanol make-up gas suitable for the synthesis of methanol, and at least a portion of carbon dioxide is separated from said gaseous fuel and is used to balance the molar ratio of said methanol make-up gas.

13. The process according to claim 11 , wherein said hydrogen-containing synthesis gas is used for ammonia-urea synthesis, the urea being synthesized from ammonia and carbon dioxide, and at least a portion of said carbon dioxide for the synthesis of urea is separated from said gaseous fuel.

14. The process according to claim 1 , wherein at least a portion of said gaseous fuel is subjected to water-gas shift.

15. The process according to claim 1 , wherein the conversion of the natural gas consists of steam reforming.

16. The process according to claim 15 , wherein said steam reforming is followed by high temperature shift and low temperature shift, or by a near-isothermal medium temperature shift and optionally a step of methanation.

17. The process according to claim 1 wherein the effluent of said gasifier is treated before combustion to remove impurities.

18. The process according to claim 5 , wherein, said sorbent is a mineral.

19. The process according to claim 6 , wherein said removal of sulphur compounds is carried out by absorption in a liquid or adsorption on metal oxides.

20. The process according to claim 7 , wherein said methane-rich stream is removed from said gaseous fuel by cryogenic separation or by separation through membrane.

21. The process according to claim 14 , wherein said water-gas shift being a sour water gas shift converting sulphur compounds into hydrogen sulphide (H2S).

Assignees

• Casale Sa

Inventors

• Ostuni Raffaele
• Skinner Geoffrey Frederick
• Filippi Ermanno

Classifications

• C01B2203/1241

  Natural gas or methane · CPC title

• F25J3/0233

  separation of CnHm with 1 carbon atom or more · CPC title

• C10J2300/1668

  to urea; to ammonia · CPC title

• C10J2300/0976

  as steam · CPC title

• C01B2203/0485

  the impurity being a sulfur compound · CPC title