Graphite heater with tailored resistance characteristics for HPHT presses and products made therein

Patent metadata

Field	Value
Publication number	US-10668539-B2
Application number	US-201514936682-A
Country	US
Kind code	B2
Filing date	Nov 10, 2015
Priority date	Nov 10, 2014
Publication date	Jun 2, 2020
Grant date	Jun 2, 2020

Abstract

A method for sintering includes loading a tool material into a resistance heating element within a HPHT press and heating the resistance heating element at a first axial portion to a control temperature, where a temperature difference is measured between the control temperature and a second temperature measured at a distal axial portion along the resistance heating element, wherein a difference between the control temperature and the second temperature ranges between about 5 percent to about 11 percent of the control temperature.

First claim

What is claimed is:

1. A method for sintering, comprising:
loading a tool material into a non-uniform resistance heating element having a variation in one or more dimensions and/or one or more material properties within a HPHT press; and
heating the resistance heating element at a first axial portion to a control temperature, where a temperature difference is measured between the control temperature and a second temperature measured at a distal axial portion along the resistance heating element, wherein a difference between the control temperature and the second temperature ranges between about 5 percent to about 11 percent of the control temperature.

2. The method of claim 1 , further comprising:
designing a reaction cell of the HPHT press to have a varied distribution of heat along an axial dimension, the reaction cell comprising the resistance heating element.

3. The method of claim 2 , wherein the reaction cell further comprises at least one end disk disposed at an axial end of the resistance heating element.

4. The method of claim 1 , wherein the standard deviation of the second temperature at the distal axial portion is within 10 degrees Celsius.

5. The method of claim 1 , wherein the HPHT press further comprises pressure transmitting material disposed between the resistance heating element and the tool material.

6. The method of claim 1 , wherein the temperature difference is greater than 100 degrees.

7. The method of claim 1 , wherein the resistance heating element comprises graphite having a fine grain size ranging from about 5 micrometers to about 30 micrometers.

8. The method of claim 7 , wherein the graphite has a substantially monomodal grain size distribution.

9. The method of claim 1 , wherein the resistance heating element comprises a material with a resistivity of greater than 8 microohm·m.

10. The method of claim 1 , wherein the tool material comprises at least one layer of carbide material and at least one layer of diamond powder disposed on the at least one layer of carbide material, and wherein after the heating, at least one cutting element is formed from the tool material, each cutting element having a polycrystalline diamond layer attached to a carbide substrate.

11. The method of claim 10 , wherein the polycrystalline diamond layer comprises a binder phase substantially uniformly distributed among a plurality of diamond grains, such that the volume percent of the binder phase measured around the perimeter of the polycrystalline diamond layer varies within 15 percent of the average volume percent of the binder phase around the perimeter.

12. The method of claim 1 , wherein during heating, material from a refractory can enclosing the tool material migrates into the tool material substantially uniformly around the perimeter of the tool material.

13. The method of claim 1 , wherein at the control temperature, a maximum voltage drop along an axial dimension of the resistance heating element varies by less than 5 percent around the perimeter of the resistance heating element.

14. The method of claim 1 , wherein the one or more material properties varies along at least one direction of the resistance heating element.

15. The method of claim 1 , wherein the one or more dimensions is wall thickness and/or width.

16. The method of claim 1 , wherein the one or more material properties is grain size, density, thermal conductivity, electrical conductivity, material composition, and/or electrical resistivity.

17. The method of claim 1 , wherein the one or more dimensions and/or the one or more material properties varies along an axial dimension of the resistance heating element.

18. The method of claim 1 , wherein the temperature difference is generated by varying the one or more material properties along at least one direction of the resistance heating element, and wherein the one or more material properties is grain size, density, thermal conductivity, electrical conductivity, material composition, and/or electrical resistivity.

19. The method of claim 1 , wherein the tool material comprises a carbide substrate assembled with a ultra-hard material, wherein during the heating, the carbide substrate is sintered to the ultra-hard material.

Assignees

• Smith International

Inventors

• Middlemiss Stewart
• Eyre Ronald

Classifications

• C22C26/00

  Alloys containing diamond {or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes} · CPC title

• B22F2005/001

  Cutting tools, earth boring or grinding tool other than table ware · CPC title

• B22F2999/00

  Aspects linked to processes or compositions used in powder metallurgy · CPC title

• B22F3/14 Primary

  simultaneously · CPC title

• B22F3/105

  by using electric current {other than for infrared radiant energy}, laser radiation or plasma (B22F3/11 takes precedence){; by ultrasonic bonding (B22F3/115 takes precedence)} · CPC title