Optoelectronic nuclear batteries based on radionuclide nanoencapsulation and organic photodiodes

Patent metadata

Field	Value
Publication number	US-10665359-B2
Application number	US-201715709782-A
Country	US
Kind code	B2
Filing date	Sep 20, 2017
Priority date	Oct 18, 2013
Publication date	May 26, 2020
Grant date	May 26, 2020

Abstract

Embodiments of the present disclosure relate to compositions including a doped material, batteries including the composition, photovoltaic devices including the battery, and the like.

First claim

We claim at least the following:

1. A photovoltaic device, comprising:
a core comprising a composition including a homogeneous mixture of a material doped with radioactive nuclides to form a homogeneous doped material, wherein the homogeneous doped material absorbs a radiation emission from the radioactive nuclides and re-emits a photon, the core formed with an outer surface wherein the homogeneous doped material is transparent to the photon;
a transparent material, wherein the homogeneous doped material is disposed within the transparent material, wherein the transparent material is transparent to photons, wherein the transparent material and the homogeneous doped material are not the same material; and
an organic photovoltaic cell, wherein the core and the organic photovoltaic cell have a core-shell structure where the outer surface of the core is wrapped with the organic photovoltaic cell so that the entire core is within the organic photovoltaic cell and wherein the photovoltaic cell is disposed only on the outer surface of the core so that re-emitted photons produced by the homogeneous doped material are captured by the photovoltaic cell regardless of scattering angle.

2. The photovoltaic device of claim 1 , wherein the transparent material is selected from: a glass or a polymer, wherein the glass is formed from a glass former selected from the group consisting of: B, Si, Ge, Al, B, P, V, As, Sb, Zr, and a combination thereof, or the glass is formed from an intermediate former selected from the group consisting of: Ti, Zn, Pb, Al, Th, Be, Zr, Cd, and a combination thereof, and wherein the polymer is selected from the group consisting of: low density polyethylene, high density polyethylene, polypropylene, polystyrene, polytetrafluoroethylene, polyvinylchloride, polychlorotrifluoroethylene, and a combination thereof.

3. The photovoltaic device of claim 1 , wherein the radioactive nuclides are beta emitters, gamma emitters, or both.

4. The photovoltaic device of claim 3 , wherein the beta emitters are selected from the group consisting of: 63 Ni, 32 Si, 151 Sm, 90 Sr, 66 Cu, 209 Pb, 145 Pr, 127 Te, 121 Sn, 66 Ni, 210 Bi, 169 Er, 143 Pr, 32 P, 89 Sr, 91 Y, 188 W, 35 S, 123 Sn, 45 Ca, 249 Bk, 106 Ru, 171 Tm, 147 Pm, 85 Kr, 3 H, 113m Cd, 241 Pu, 42 Ar, 39 Ar, 14 C, 99 Tc, 79 Se, 10 Be, 135 Cs, 107 Pd, 187 Re, 115 In, 113 Cd, and a combination thereof.

5. The photovoltaic device of claim 3 , wherein the gamma emitters are selected from the group consisting of: 228 Ac, 241 Am, 124 Sb, 125 Sb, 126 Sb, 137m Ba, 139 Ba, 140 Ba, 141 Ba, 142 Ba, 7 Be, 211 Bi, 213 Bi, 213 Bi, 214 Bi, 82 Br, 84 Br, 11 C, 47 Ca, 141 Ce, 143 Ce, 144 Ce, 134 Cs, 134m Cs, 136 Cs, 137 Cs, 138 Cs, 38 Cl, 51 Cr, 56 Co, 57 Co, 58 Co, 60 Co, 61 Cu, 64 Cu, 243 Cm, 245 Cm, 247 Cm, 152 Eu, 154 Eu, 155 Eu, 156 Eu, 18 F, 221 Fr, 223 Fr, 67 Ga, 198 Au, 166m Ho, 123 I, 130 I, 131 I, 132 I, 133 I, 134 I, 135 I, 111 In, 113m In, 192 Ir, 59 Fe, 85 Kr, 85m Kr, 87 Kr, 88 Kr, 140 La, 142 La, 211 Pb, 212 Pb, 214 Pb, 52 Mn, 52m Mn, 54 Mn, 56 Mn, 203 Hg, 99 Mo, 147 Nd, 237 Np, 238 Np, 239 Np, 240 Np, 57 Ni, 65 Ni, 95m Nb, 97 Nb, 13 N, 15 O, 40 K, 42 K, 43 K, 148 Pm, 148m Pm, 149 Pm, 151 Pm, 231 Pa, 233 Pa, 234 Pa, 233 Ra, 224 Ra, 226 Ra, 219 Rn, 105 Rh, 106 Rh, 103 Rh, 89 Rb, 105 Ru, 97 Ru, 153 Sm, 44 Sc, 47 Sc, 46 Sc, 48 Sc, 75 Se, 110 Ag, 110m Ag, 111 Ag, 22 Na, 85 Sr, 87m Sr, 91 Sr, 92 Sr, 101 Tc, 99m Tc, 129 Te, 129m Te, 131 Te, 131m Te, 132 Te, 133 Te, 133m Te, 134 Te, 135 Te, 160 Tb, 169 Tb, 180 Tb, 89 Tb, 201 Tl, 208 Ti, 209 Ti, 227 Th, 229 Th, 125 Sn, 187 W, 235 U, 237 U, 48 V, 131m Xe, 133m Xe, 135 Xe, 138 Xe, 169 Yb, 92 Y, 93 Y, 65 Zn, and 97 Zr and a combination thereof.

6. A photovoltaic device, comprising:
a core comprising a composition including a homogeneous mixture of a material doped with radioactive nuclides to form a homogeneous doped material, wherein the homogeneous doped material absorbs a radiation emission from the radioactive nuclides and re-emits a photon, wherein the radioactive nuclides are beta emitters and the material is a fluorescent material, the core formed with an outer surface, wherein the homogeneous doped material is transparent to the photon; and
an organic photovoltaic cell, wherein the core and the organic photovoltaic cell have a core-shell structure where the outer surface of the core is wrapped with the organic photovoltaic cell so that the entire core is within the organic photovoltaic cell and wherein the photovoltaic cell is disposed only on the outer surface of the core so that re-emitted photons produced by the homogeneous doped material are captured by the photovoltaic cell regardless of scattering angle.

7. The photovoltaic device of claim 6 , wherein the fluorescent material is selected from the group consisting of: ZnSiO 4 :Mn:Sb 2 O 3 , SrB 4 O 7 :Eu, (La,Ce)PO 4 :Ce, (CeMg)SrAl 11 O 18 :Ce, (CeMg)BaAl 11 O 18 :Ce, BaSi 2 O 5 :Pb, (Y,Gd)MgB 5 O 10 :Ce,Pr, La2O3:Eu, (Y,Ce)PO 4 :Ce, BaMgAl 16 O 27 :Eu:Mn, (La,Ce,Tb)PO 4 :Ce:Tb, (Ce,Tb)MgAl 11 O 19 :Ce:Tb, MgWO 4 , Mg 4 (F)GeO 6 :Mn, CaWO 4 :Pb, (Ba,Ti) 2 P 2 O 7 :Ti, Sr 2 P 2 O 7 :Sn:Eu, Sr 5 F(PO 4 ) 3 :Sb:Mn, (Ba,Mg) 2 Al 16 O 27 :Eu, GdMgB 5 O 10 :Ce:Tb, YVO 4 :Bi:Eu, YAG:Ce:Cr:Nd (yttrium aluminum garnet), MgSrAl 10 O 17 :Eu:Cr, BaMgAl 10 O 17 :Eu, Sr 5 Cl(PO 4 ) 3 :Eu, (Sr,Ba,Mg,Ca) 5 Cl(PO 4 ) 3 :Eu, Sr 6 P 5 BO 20 :Eu, (Ca,Zn,Mg) 3 (PO 4 ) 2 :Sn, SrB 4 O 7 :Sm:Eu, (Sr,Mg) 3 (PO 4 ) 2 :Sn, CaSiO 3 :Pb:Mn, Cr—Yb doped fluorosilicate glass, ZnO—LiYbO 2 , Yb doped glass ceramics containing ZnO nanocrystals, LiYbMo 2 O 8 :Pb, CaLaGa 3 S 6 O:Yb, Yb doped LaSi 3 N 5 , Ag—Yb co-doped oxyfluoride glasses, Yb-doped glass ceramics containing YF 3 nanocrystals, Cu doped glasses, Tb doped glasses, LaVO 4 :Dy, Bi-doped oxide glasses, and a combination thereof.

8. The photovoltaic device of claim 7 , further comprising a transparent material, wherein the homogeneous doped material is disposed within the transparent material, wherein the transparent material is transparent to photons, wherein the transparent material and the homogeneous doped material are not the same material.

9. The photovoltaic device of claim 8 , wherein the transparent material is selected from: a glass or a polymer, wherein the glass is formed from a glass former selected from the group consisting of: B, Si, Ge, Al, B, P, V, As, Sb, Zr, and a combination thereof, or the glass is formed from an intermediate former selected from the group consisting of: Ti, Zn, Pb, Al, Th, Be, Zr, Cd, and a combination thereof, and wherein the polymer is selected from the group consisting of: low density polyethylene, high density polyethylene, polypropylene, polystyrene, polytetrafluoroethylene, polyvinylchloride, polychlorotrifluoroethylene, and a combination thereof.

10. The photovoltaic device of claim 1 , wherein the radioactive nuclides are gamma emitters and the material is a fluorescent material.

11. The photovoltaic device of claim 10 , wherein the fluorescent material is selected from the group consisting of: LiBaF 3 , KMgF 3 , KCaF 3 , KYF 4 , BaLu 2 F 8 , BaF 2 , CsF, RbF, CeF 3 , BaY 2 F 8 :Ce, BaLu 2 F 8 :Ce, CaF 2 :Eu, LaF 3 :Ce, LuF 3 :Ce, CsCaCl 3 , Li 3 YCl 6 , Cs 2 NaCeCl 6 , Cs 2 LiYCl 6 , LiYCl 6 :Ce, CeCl 3 :Ce, LuCl 3 :Ce, K 2 LaCl 5 :Ce, RbGd 2 Cl 7 :Ce, Cs 2 LiYCl 6 :Ce, Cs 2 NaLaCl 6 :ce, Cs 2 NaLuCl 6 :Ce, Cs 3 LuCl 6 :Ce, CsLu 2 Cl 9 :Ce, LaCl 3 :Ce, LuBr 3 :Ce, CeBr 3 , RbGd 2 Br 7 :Ce, RbLu 2 Br 7 :Ce, LaBr 3 :Ce, CsI, CaI 2 , HgI 2 , NaI:Tl, CsI:Tl, CsI:Na, CaI 2 :Eu, LiI:Eu, BiI 3 , CdS:Te, Gd 2 O 2 S

Assignees

• Univ Florida

Inventors

• Nino Juan Claudio
• Johns Paul M
• Baciak James Edward

Classifications

• G21H1/12 Primary

  Cells using conversion of the radiation into light combined with subsequent photoelectric conversion into electric energy · CPC title

• G21G4/04

  Radioactive sources other than neutron sources (radioactive dressings A61N5/1029) · CPC title

• H02S40/38

  Energy storage means, e.g. batteries, structurally associated with PV modules · CPC title

• G21H3/02

  in which material is excited to luminesce by the radiation (lamps in which a gas filling or screen or coating is excited to luminesce by radioactive material structurally associated with the lamp  H01J65/00) · CPC title

• Y02E70/30

  Systems combining energy storage with energy generation of non-fossil origin · CPC title