Materials for use with aqueous redox flow batteries and related methods and systems

Patent metadata

Field	Value
Publication number	US-10658848-B2
Application number	US-201715785009-A
Country	US
Kind code	B2
Filing date	Oct 16, 2017
Priority date	Feb 18, 2014
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

Described herein are redox flow batteries comprising a first aqueous electrolyte comprising a first type of redox active material and a second aqueous electrolyte comprising a second type of redox active material. The first type of redox active material may comprise one or more types of quinoxalines, or salts thereof. Methods for storing and releasing energy utilizing the described redox flow batteries are also provided.

First claim

What is claimed is:

1. A redox flow battery comprising:
a first aqueous electrolyte comprising a first type of redox active material;
a second aqueous electrolyte comprising a second type of redox active material;
wherein the first type of redox active material comprises a quinoxaline moiety, a salt of the quinoxaline moiety, or a mixture thereof.

2. The battery of claim 1 , further comprising a first electrode in contact with the first aqueous electrolyte and a second electrode in contact with the second aqueous electrolyte.

3. A method of storing energy, comprising applying a potential difference across the first electrode and second electrode of a flow battery of claim 2 , wherein the first type of redox active material is reduced.

4. The method of claim 3 , wherein a quinoxaline moiety in the first type of redox active material is converted from a compound comprising Formula (I):

or salt thereof, to a compound comprising Formula (I-B):

5. A method of releasing energy, comprising applying a potential difference across the first electrode and second electrode of a flow battery of claim 2 , wherein the first type of redox active material is oxidized.

6. The method of claim 5 , wherein a quinoxaline in the first type of redox active material is converted from a compound comprising Formula (I-B):

or salt thereof, to a compound comprising Formula (I):

7. The battery of claim 1 , further comprising a separator between the first aqueous electrolyte and second aqueous electrolyte.

8. The battery of claim 1 , wherein the first aqueous electrolyte has a pH between about 7 and about 10, or between about 10 and about 12, or between about 12 and about 14.

9. The battery of claim 1 , wherein the first type of redox active material is present in the first aqueous electrolyte in a concentration of at least about 0.5 M, at least about 1 M, at least about 2 M, at least about 4 M, or at least about 6 M.

10. The battery of claim 1 , wherein the first type of redox active material is present in the first aqueous electrolyte in a concentration of between about 0.5 and about 2 M.

11. The battery of claim 1 , wherein the quinoxaline moiety comprises a compound comprising Formula (I):

or a salt thereof, wherein:
each R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 is independently hydrogen, halogen, optionally substituted alkyl, optionally substituted carbocyclyl, optionally substituted heterocyclyl, optionally substituted aryl, optionally substituted heteroaryl, —CN, —NO 2 , —OR a , —N(R a ) 2 , —C(═O)R a , —C(═O)OR a , —S(═O) 2 R a , or —S(═O) 2 OR a ;
each R a is independently hydrogen, optionally substituted alkyl, optionally substituted carbocyclyl, optionally substituted heterocyclyl, optionally substituted aryl, optionally substituted heteroaryl, an oxygen protecting group, or a nitrogen protection group; and
optionally, any two adjacent groups selected from R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are joined to form an optionally substituted aryl or optionally substituted heteroaryl ring.

12. The battery of claim 11 , wherein:
each of R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 is independently hydrogen, halogen, optionally substituted alkyl, optionally substituted haloalkyl, —CN, —NO 2 , —OR a , —N(R a ) 2 , —C(═O)OR a , or —S(═O) 2 OR a ; and
each R a is independently hydrogen or optionally substituted alkyl.

13. The battery of claim 11 , wherein none of, any two of, any three of, any four of, or any five of R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are hydrogen.

14. The battery of claim 11 , wherein the compound of Formula (I) comprises the structure:

or a salt thereof.

15. The battery of claim 1 , wherein the first aqueous electrolyte comprises between 0.5 and 5 M LiCl, between 0.5 M and 5 M NaCl, or between 0.5 M and 5 M KCl, or a mixture thereof such that the combined concentration is between 0.5 M and 5 M.

16. The battery of claim 1 , wherein the quinoxaline moiety comprises Formula (IV):

or a salt thereof, wherein:
each R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 is independently hydrogen, halogen, optionally substituted alkyl, optionally substituted carbocyclyl, optionally substituted heterocyclyl, optionally substituted aryl, optionally substituted heteroaryl, —CN, —NO 2 , —OR a , —N(R a ) 2 , —C(═O)R a , —C(═O)OR a , —S(═O) 2 R a , or —S(═O) 2 OR a ;
each R a is independently hydrogen, optionally substituted alkyl, optionally substituted carbocyclyl, optionally substituted heterocyclyl, optionally substituted aryl, optionally substituted heteroaryl, an oxygen protecting group, or a nitrogen protection group;
provided at least one of the nitrogen labeled a, the nitrogen labeled b, R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 is associated with a metal center, and
wherein the metal center is optionally associated with one or more auxiliary ligands.

17. The battery of claim 1 , wherein the second type of redox active material comprises a hexacyanoiron complex, a quinone, a hydroquinone, or an organic dye, or a salt or mixture thereof.

18. The battery of claim 17 , wherein the second type of redox active material comprises ferrocyanide, ferricyanide, 1,2-dihydroxy-3,5-benzenedisulfonate, 1,2,4-trihydroxy-3,5-benzenedisulfonate, or indigo carmine, a salt of any one of these compounds, or a mixture thereof.

19. The battery of claim 1 , further comprising:
a first circulation loop comprising a storage tank containing the first aqueous electrolyte, piping for transporting the first aqueous electrolyte, a chamber in which a first electrode is in contact with the first aqueous electrolyte, and a pump to circulate the first aqueous electrolyte through the first circulation loop;
optionally a second circulation loop comprising a storage tank containing the second aqueous electrolyte, piping for transporting the second aqueous electrolyte, a chamber in which a second electrode is in contact with the second aqueous electrolyte, and a pump to circulate the second aqueous electrolyte through the second circulation loop; and
control hardware and software.

20. The battery of claim 1 , wherein the first type of redox active material is present in the first aqueous electrolyte in a concentration of between about 2 M and about 4 M.

21. The battery of claim 1 , wherein the first type of redox active material is present in the first aqueous electrolyte in a concentration of between about 4 M and about 6 M.

22. The battery of claim 1 , wherein the first type of redox active material is present in the first aqueous electrolyte in a concentration of between about 6 M and about 10 M.

Assignees

• Massachusetts Inst Technology
• Uchicago Argonne Llc

Inventors

• Brushett Fikile Richard
• Jansen Andrew Norbert
• Vaughey John Thomas
• Su Liang
• Milshtein Jarrod D

Classifications

• H01M8/20

  Indirect fuel cells, e.g. fuel cells with redox couple being irreversible (H01M8/18 takes precedence) · CPC title

• H01M8/0215

  Glass; Ceramic materials · CPC title

• H01M8/188

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M4/58

  of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates · CPC title

• H01M4/608

  containing heterocyclic rings · CPC title