Lithium-sulfur accumulator

Patent metadata

Field	Value
Publication number	US-10658668-B2
Application number	US-201715488048-A
Country	US
Kind code	B2
Filing date	Apr 14, 2017
Priority date	Oct 16, 2014
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

A lithium-sulfur battery which includes an electrolyte containing lithium-ions, an anode and a cathode containing sulfur. The lithium-sulfur battery also contains a surface layer which is arranged between the anode and the cathode. The lithium-sulfur battery further includes areas on the cathode side which contain polysulfides. The surface layer of the lithium-sulfur battery contains at least one graphene layer which is permeable to lithium ions and impermeable to polysulfides.

First claim

What is claimed is:

1. A rechargeable lithium-sulfur battery, comprising:
an electrolyte containing lithium ions,
an anode,
a sulfur-containing cathode,
a surface layer arranged between the anode and the cathode,
wherein the rechargeable lithium-sulfur battery further comprises areas on the cathode containing polysulfides,
and wherein the surface layer comprises at least one graphene layer which is permeable to the lithium ions and impermeable to the polysulfides, and wherein the at least one graphene layer has negatively charged functional groups which are suitable for repelling polysulfides, and positively charged functional groups.

2. The rechargeable lithium-sulfur battery according to claim 1 , wherein the surface layer is arranged on the cathode.

3. The rechargeable lithium-sulfur battery according to claim 1 , further comprises a separator arranged between the anode and the cathode, with the surface layer being arranged on the separator.

4. The rechargeable lithium-sulfur battery according to claim 1 , wherein the surface layer is arranged on the anode.

5. The rechargeable lithium-sulfur battery according to claim 1 , wherein the surface layer is not electrically connected to the anode or the cathode.

6. The rechargeable lithium-sulfur battery according to claim 1 , further comprises at least one further surface layer arranged between the anode and the cathode, wherein the further surface layer comprises at least one graphene layer which is permeable to the lithium ions and impermeable to the polysulfides.

7. The rechargeable lithium-sulfur battery according to claim 1 , wherein the graphene layer comprises pores having a diameter in the range from 0.15 nm to 2 nm.

8. The rechargeable lithium-sulfur battery according to claim 1 , wherein the graphene layer comprises pores having a diameter in the range from 0.15 to 1 nm.

9. The rechargeable lithium-sulfur battery according to claim 1 , wherein the graphene layer comprises O-containing functional groups selected from hydroxyl, carboxyl, carbalkoxy, carbonyl or alkoxy groups.

10. The rechargeable lithium-sulfur battery according to claim 1 , wherein anions which are suitable for repelling polysulfides are bound to the graphene layer.

11. The rechargeable lithium-sulfur battery according to claim 1 , wherein the surface layer comprises less than 10 percent by weight of sulfur, based on the total weight of the surface layer.

12. The rechargeable lithium-sulfur battery according to claim 1 , wherein the surface layer comprises less than 2 percent by weight of sulfur, based on the total weight of the surface layer.

13. The rechargeable lithium-sulfur battery according to claim 1 , wherein the surface layer comprises less than 0.5 percent by weight of sulfur, based on the total weight of the surface layer.

14. The rechargeable lithium-sulfur battery according to claim 1 , wherein the surface layer is entirely free of sulfur.

15. The rechargeable lithium-sulfur battery according to claim 1 , wherein the cathode has a proportion of sulfur of at least 50 percent by weight based on the total cathode.

16. The rechargeable lithium-sulfur battery according claim 1 , wherein the surface layer comprises from 1 to 20 graphene layers which are permeable to the lithium ions and impermeable to the polysulfides.

17. The rechargeable lithium-sulfur battery according claim 1 , wherein the surface layer comprises from 1 to 10 graphene layers which are permeable to the lithium ions and impermeable to the polysulfides.

18. The rechargeable lithium-sulfur battery according to claim 1 , wherein the surface layer has a thickness of less than 10 nm.

19. The rechargeable lithium-sulfur battery according to claim 1 , wherein the polysulfides has the general formula S x 2− , wherein x is an integer and wherein x≥2.

Assignees

• Bayerische Motoren Werke Ag

Inventors

• Lux Simon
• Oberhumer Philipp
• Stiaszny Barbara
• Gentschev Ann-Christin
• Reiter Jakub

Classifications

• H01M4/5815

  Sulfides · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/628 Primary

  Inhibitors, e.g. gassing inhibitors, corrosion inhibitors · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M10/0585

  of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators · CPC title