Multilayer capacitor having external electrode including conductive resin layer

Patent metadata

Field	Value
Publication number	US-10658116-B2
Application number	US-201916265548-A
Country	US
Kind code	B2
Filing date	Feb 1, 2019
Priority date	Apr 15, 2016
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

A multilayer ceramic capacitor comprises a body including dielectric layers and internal electrodes; and external electrodes disposed on external surfaces of the body, respectively, wherein each of the external electrodes includes a first electrode layer disposed on the one surface of the body and contacting the internal electrodes; a conductive resin layer disposed on the first electrode layer and including a plurality of metal particles, a conductive connecting part surrounding the plurality of metal particles, a base resin, and an intermetallic compound contacting the first electrode layer and the conductive connecting part; and a second electrode layer disposed on the conductive resin layer and contacting the conductive connecting part.

First claim

What is claimed is:

1. A method of manufacturing a multilayer capacitor, comprising:
preparing a body including dielectric layers and internal electrodes;
forming a first electrode layer by applying a paste including a conductive metal and glass to one surface of the body to be electrically connected to one end of the internal electrodes and then firing the paste;
applying a conductive resin composite to the first electrode layer, the conductive resin composite including metal particles, a thermosetting resin, and a low-melting-point metal having a melting point lower than a hardening temperature of the thermosetting resin;
forming a conductive resin layer so that a melted low-melting-point metal becomes a conductive connecting part surrounding the metal particles and an intermetallic compound is formed between the first electrode layer and the conducive connecting part by hardening the conductive resin composite; and
forming a second electrode layer on the conductive resin layer by plating,
wherein the first electrode layer includes copper,
the metal particles of the conductive resin layer are formed of at least one selected from the group consisting of copper, nickel, silver, copper coated with silver, and copper coated with tin,
the intermetallic compound is formed of copper-tin,
low-melting-point metal particles included in the thermosetting resin are composed of Sn—Bi, and a content (x) of Sn in Sn x —Bi y is 10 wt % or more with respect to a total content of metal,
the forming of the conductive resin layer includes:
removing oxide films from surfaces of metal particles and the low-melting-point metal particles included in the thermosetting resin; and
forming the conductive connecting part by a reaction between the metal particles from which the oxide films are removed and the low-melting-point metal particles from which the oxide films are removed and forming the intermetallic compound contacting the first electrode layer by allowing the low-melting-point metal particles having flowability to flow into the surroundings of the first electrode layer, and

after removing the oxide films, a content of carbon in the low-melting-point metal particles formed of Sn—Bi is 0.5% to 1.0%.

2. The method of manufacturing a multilayer capacitor of claim 1 , wherein the metal particles are formed of copper, and the low-melting-point metal particles further include at least one selected from the group consisting of Sn—Pb, Sn—Cu, Sn—Ag, and Sn—Ag—Cu.

3. The method of manufacturing a multilayer capacitor of claim 1 , wherein the metal particles have a size of 0.2 μm to 20 μm.

4. The method of manufacturing a multilayer capacitor of claim 1 , wherein a content of the low-melting-point metal is 10 wt % to 90 wt % with respect to a total content of metal.

5. The method of manufacturing a multilayer capacitor of claim 1 , wherein the melting point of the low-melting-point metal is 300° C. or less.

6. A method of manufacturing a multilayer capacitor, comprising:
preparing a body including dielectric layers and internal electrodes;
forming a first electrode layer by applying a paste including a conductive metal and glass to one surface of the body to be electrically connected to one end of the internal electrodes and then firing the paste;
applying a conductive resin composite to the first electrode layer, the conductive resin composite including metal particles, a thermosetting resin, and a low-melting-point metal having a melting point lower than a hardening temperature of the thermosetting resin;
forming a conductive resin layer so that a melted low-melting-point metal becomes a conductive connecting part surrounding the metal particles and an intermetallic compound is formed between the first electrode layer and the conducive connecting part by hardening the conductive resin composite; and
forming a second electrode layer on the conductive resin layer by plating,
wherein in the forming of the conductive resin layer, the intermetallic compound is formed in a form of a plurality of islands,
low-melting-point metal particles included in the thermosetting resin are formed of Sn—Bi, and a content (x) of Sn in Sn x —Bi y is 10 wt % or more with respect to a total content of metal,
the forming of the conductive resin layer includes:
removing oxide films from surfaces of metal particles and the low-melting-point metal particles included in the thermosetting resin; and
forming the conductive connecting part by a reaction between the metal particles from which the oxide films are removed and the low-melting-point metal particles from which the oxide films are removed and forming the intermetallic compound contacting the first electrode layer by allowing the low-melting-point metal particles having flowability to flow into the surroundings of the first electrode layer, and

after removing the oxide films, a content of carbon in the low-melting-point metal particles formed of Sn—Bi is 0.5% to 1.0%.

7. The method of manufacturing a multilayer capacitor of claim 6 , wherein the plurality of islands are formed in a layer form.

8. A method of manufacturing a multilayer capacitor, comprising:
preparing a body including dielectric layers and internal electrodes;
forming a first electrode layer by applying a paste including a conductive metal and glass to one surface of the body to be electrically connected to one end of the internal electrodes and then firing the paste;
applying a conductive resin composite to the first electrode layer, the conductive resin composite including metal particles, a thermosetting resin, and a low-melting-point metal having a melting point lower than a hardening temperature of the thermosetting resin;
forming a conductive resin layer so that a melted low-melting-point metal becomes a conductive connecting part surrounding the metal particles and an intermetallic compound is formed between the first electrode layer and the conducive connecting part by hardening the conductive resin composite;
forming a nickel (Ni) plating layer on the conductive resin layer by plating; and
forming a tin (Sn) plating layer on the nickel (Ni) plating layer by plating,
wherein the first electrode layer includes copper,
the metal particles of the conductive resin layer are formed of at least one selected from the group consisting of copper, nickel, silver, copper coated with silver, and copper coated with tin,
the intermetallic compound is formed of copper-tin,
the forming of the conductive resin layer includes:
removing oxide films from surfaces of metal particles and low-melting-point metal particles included in the thermosetting resin; and
forming the conductive connecting part by a reaction between the metal particles from which the oxide films are removed and the low-melting-point metal particles from which the oxide films are removed and forming the intermetallic compound contacting the first electrode layer by allowing the low-melting-point metal particles having flowability to flow into the surroundings of the first electrode layer,

the low-melting-point metal particles included in the thermosetting resin are formed of Sn—Bi, and a content (x) of Sn in Sn x —Bi y is 10 wt % or more with respect to a total content of metal, and
after removing the oxide films, a content of carbon in the low-melting-point metal particles formed of Sn—Bi is 0.5% to 1.0%.

9. The method of manufacturing a multilayer capacitor of claim 8 , wherein the metal particles are formed of copper, and the low-melting-point metal particles additionally include one selected from the group consisting of Sn—Pb, Sn—Cu, Sn—Ag, and Sn—Ag—Cu.

10. The method of manufacturing a multilayer capacitor of claim 8 , wherein the metal

Assignees

• Samsung Electro Mech

Inventors

• Kim Jung Min
• Koo Bon Seok
• Seo Jung Wook
• Lee Yoon Hee
• Koo Kun Hoi

Classifications

• H01G4/2325 Primary

  characterised by the material of the terminals · CPC title

• H01G4/12

  Ceramic dielectrics {(H01G4/085 takes precedence)} · CPC title

• H01G4/30

  Stacked capacitors (H01G4/33 takes precedence) · CPC title

• H01G4/232 Primary

  electrically connecting two or more layers of a stacked or rolled capacitor · CPC title