Solid polymer composition obtained by polymerization of an acid group-containing monomer in the presence of a polyether compound

Patent metadata

Field	Value
Publication number	US-10655088-B2
Application number	US-201916395423-A
Country	US
Kind code	B2
Filing date	Apr 26, 2019
Priority date	Jul 3, 2013
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

The present invention relates to a process for preparing a polymer composition, in which an α,β-ethylenically unsaturated carboxylic acid is subjected to a free-radical polymerization in the presence of at least one polyether component, to the polymer composition obtainable by this process and to the use thereof.

First claim

The invention claimed is:

1. A method for at least partially ensheathing a liquid or solid washing and cleaning composition, comprising utilizing a polymer composition in solid form obtained by a process comprising:
a) providing a monomer composition M) comprising
A) at least one α,β-ethylenically unsaturated carboxylic acid, and
B) less than 0.1% by weight, based on the total weight of the monomer composition M), of crosslinking monomers having two or more polymerizable α,β-ethylenically unsaturated double bonds per molecule,
where component A) is optionally partly or fully replaced by C) at least one unsaturated sulfonic acid or unsaturated phosphonic acid,

b) subjecting the monomer composition M) provided in step a) to a free-radical polymerization in the presence of at least one polyether component PE), which does not have any copolymerizable double bonds, selected from the group consisting of polyetherols having a number-average molecular weight of at least 200 g/mol and the mono- and di-(C 1 -C 6 -alkyl) ethers thereof, surfactants containing polyether groups and mixtures thereof.

2. The method according to claim 1 , wherein the process further comprises
c) converting the polymer obtained in step b) to a film, to a solid coating on a substrate or to particles.

3. The method according to claim 1 , wherein the polyether component PE) comprises a polyetherol having repeat propylene oxide units or a mono- or di-(C 1 -C 6 -alkyl ether) of a polyetherol having repeat propylene oxide units, and the proportion of these repeat propylene oxide units averages not more than 18 units per molecule.

4. The method according to claim 1 , wherein the free-radical polymerization in step b) is additionally effected in the presence of a solvent S) selected from the group consisting of water, C 1 -C 6 -alkanols, polyols other than PE), the mono- and dialkyl ethers thereof, and mixtures thereof.

5. The method according claim 1 , wherein the α,β-ethylenically unsaturated carboxylic acid A) is selected from the group consisting of acrylic acid, methacrylic acid, ethacrylic acid, α-chloroacrylic acid, crotonic acid, maleic acid, itaconic acid, citraconic acid, mesaconic acid, glutaconic acid, aconitic acid, fumaric acid and mixtures thereof.

6. The method according to claim 1 , wherein the monomer composition M) further comprises, as component C), at least one unsaturated sulfonic acid or unsaturated phosphonic acid.

7. The method according to claim 1 , wherein the monomer composition M) comprises at least 80% by weight, based on the total weight of the monomer composition M), of at least one α,β-ethylenically unsaturated acid selected from the group consisting of acrylic acid, methacrylic acid, 2-acrylamido-2-methylpropanesulfonic acid and mixtures thereof.

8. The method according to claim 1 , wherein the polymer composition has a solubility in water at 40° C. and a pH of 8 of at least 5 g/l.

9. The method according to claim 1 , wherein the polymer composition has a weight-average molecular weight of from 1,000 to 150,000 daltons.

10. The method according to claim 1 , wherein the polymer composition has a solvent content of not more than 10% by weight, based on the total weight of polymer composition and solvent.

11. The method according to claim 1 , wherein the polymer composition has a content of acid groups of 1.5 mmol/g to 15 mmol/g.

12. The method according to claim 1 , wherein the polymer composition is a film.

13. The method according to claim 12 , wherein the composition has a transparency, reported as the T L measured at 500 nm, of at least 85%, based on the transparency of water.

14. The method according to claim 1 , wherein the polymer composition is a film or coating, wherein the thickness of the film or the coating is 0.5 μm to 10 mm.

15. The method according to claim 1 , wherein the polymer composition has a glass transition temperature T G in the range from 0 to 50° C.

16. The method according to claim 1 , wherein polymer composition is in the form of a particulate solid substance.

17. The method according to claim 16 , wherein the particulate solid substance comprises particles having a particle size within a range from 50 μm to 10 mm.

18. The method according to claim 2 , wherein the free-radical polymerization in step c) is effected in the presence of a solvent S) comprising at least 50% by weight, based on the total weight of the solvent S), of water.

19. The method according to claim 1 , wherein the weight ratio of the monomer mixture M) to the component PE) is in the range from 1:10 to 10:1.

20. A polymer composition in the form of a particulate solid substance, having a glass transition temperature T G in the range from 15 to 150° C.; said polymer composition obtained by a process comprising:
a) providing a monomer composition M) comprising
C) at least one α,β-ethylenically unsaturated carboxylic acid, and
D) less than 0.1% by weight, based on the total weight of the monomer composition M), of crosslinking monomers having two or more polymerizable α,β-ethylenically unsaturated double bonds per molecule,
where component A) is optionally partly or fully replaced by C) at least one unsaturated sulfonic acid or unsaturated phosphonic acid,

b) subjecting the monomer composition M) provided in step a) to a free-radical polymerization in the presence of at least one polyether component PE), which does not have any copolymerizable double bonds, selected from the group consisting of polyetherols having a number-average molecular weight of at least 200 g/mol and the mono- and di-(C 1 -C 6 -alkyl) ethers thereof, surfactants containing polyether groups and mixtures thereof.

Assignees

• Basf Se

Inventors

• Fuchs Yannick
• Witteler Helmut
• Weber Heike
• Garcia Marcos Alejandra
• Detering Jürgen

Classifications

• C08F120/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C08L33/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• C09D133/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• C08F283/06 Primary

  on to polyethers, polyoxymethylenes or polyacetals {(C08F283/004 takes precedence)} · CPC title

• C09J133/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title