Catalyzed non-staining high alkaline CIP cleaner

Patent metadata

Field	Value
Publication number	US-10655086-B2
Application number	US-201715589443-A
Country	US
Kind code	B2
Filing date	May 8, 2017
Priority date	Jun 20, 2014
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

A catalyzed highly alkaline cleaning composition for cleaning stainless steel and other surfaces, namely those treated in clean-in-place processes, is disclosed. The composition comprises gluconic acid or salt thereof (e.g. gluconate) to serve as a corrosion and stain inhibitor for the high alkalinity compositions. The composition retains the cleaning and corrosion prevention properties of conventional clean-in-place solutions while being less expensive to produce.

First claim

What is claimed is:

1. A corrosion inhibiting and non-staining composition comprising:
an alkali metal hydroxide alkalinity source, wherein the pH of a use solution of the composition is at least about 12;
from about 0.1 weight percent to about 50 weight percent of at least one chelant, wherein the at least one chelant is gluconic acid;
from about 0.001 weight percent to about 1 weight percent of a catalyst capable of decomposing an active oxygen source, wherein the catalyst is iron sulfate;

a nonionic surfactant; and
water;
wherein the composition is free of phosphates.

2. The composition of claim 1 , comprising from about 50 to 99 weight percent of the alkalinity source.

3. The composition of claim 1 , comprising from about 80 to 99 weight percent of the alkalinity source, from about 1 to 25 weight percent of the chelant, and from about 0.1 to 1 weight percent of the catalyst.

4. The composition of claim 1 , wherein said composition is a premix formulation requiring combination with a commodity alkalinity source to generate a use solution having the pH of at least about 12.

5. The composition of claim 1 , wherein a use solution provides between about 2000 ppm of the alkalinity source to about 4 weight percent of the alkalinity source, between about 100 ppm to about 5000 ppm of the chelant, and between about 0.5 ppm to about 25 ppm of the catalyst.

6. The composition of claim 5 , wherein the pH of the use solution of the composition is at least about 13.

7. A method of cleaning soils from industrial equipment using a CIP process that does not stain and/or corrode metal surfaces under highly alkaline and oxidizing conditions, the method comprising:
providing an alkaline cleaning composition to soils in industrial equipment, wherein the alkaline cleaning composition comprises an alkali metal hydroxide alkalinity source, from about 0.1 weight percent to about 50 weight percent of gluconic acid, from about 0.001 weight percent to about 1 weight percent of a catalyst capable of decomposing an active oxygen source, wherein the catalyst is iron sulfate, a nonionic surfactant, and water, wherein a use solution of the alkaline cleaning composition has a pH of at least about 12, and wherein the composition is free of phosphates;
providing an oxidizing composition to the soils in the industrial equipment, wherein the oxidizing composition comprises hydrogen peroxide, a peroxycarboxylic acid composition and/or percarbonates;
allowing the alkaline cleaning composition and oxidizing composition to remain on the soil for a period of time sufficient to facilitate soil removal; and
circulating the alkaline cleaning composition and oxidizing composition through the equipment.

8. The method of claim 7 , wherein the alkaline cleaning composition is diluted at a point of use with a commodity alkalinity source and/or water to provide a use solution pH of at least about 13.

9. The method of claim 7 , wherein the alkalinity source is sodium hydroxide.

10. The method of claim 7 , wherein the alkaline cleaning composition does not stain and/or corrode in either liquid or vapor phases of the composition.

11. The method of claim 7 , wherein the equipment comprises pipes, vessels, or a combination thereof of heat transfer equipment.

12. The method of claim 7 , further comprising the step of rinsing the equipment after the alkaline cleaning composition and oxidizing composition are circulated through the equipment.

13. A method of cleaning soils from industrial equipment using a CIP process, the method comprising:
providing a concentrate alkaline cleaning composition to soils in industrial equipment, wherein the alkaline cleaning composition comprises an alkali metal hydroxide alkalinity source, from about 0.1 weight percent to about 50 weight percent of gluconic acid, from about 0.001 weight percent to about 1 weight percent of a catalyst capable of decomposing an active oxygen source, wherein the catalyst is iron sulfate, a nonionic surfactant, and water; wherein the composition is free of phosphates;
allowing the alkaline cleaning composition to remain on the soil for a period of time sufficient to facilitate soil removal; and
circulating the alkaline cleaning composition through the equipment.

14. The method of claim 13 , further comprising the step of rinsing the equipment after the alkaline cleaning composition is circulated through the equipment.

15. The method of claim 13 , wherein the equipment comprises heat transfer equipment, pipes, vessels, or a combination thereof.

16. The method of claim 13 , further comprising the step of generating a use solution of the alkaline cleaning composition having a pH of at least about 12.

17. The method of claim 16 , further comprising adding a commodity source of alkalinity and/or water to generate the use solution.

18. The method of claim 17 , wherein the concentrate alkaline cleaning composition comprises from about 50 to 99 weight percent alkalinity source wherein the alkalinity source is a sodium hydroxide, from about 1 to 25 weight percent gluconic acid, from about 0.1 to 1 weight percent catalyst wherein the catalyst is iron sulfate, and wherein the use solution provides between about 2000 ppm alkalinity source to about 4 weight percent alkalinity source.

19. The method of claim 16 , further comprising adding an oxidizing agent and/or an oxidizing composition comprising an oxidizer selected from the group consisting of hydrogen peroxide, peroxycarboxylic acid compounds, percarbonates and mixtures thereof.

20. The method of claim 19 , wherein the equipment treated with the alkaline cleaning composition and oxidizing agent and/or an oxidizing composition does not stain and/or corrode in either liquid or vapor phases of the compositions.

Assignees

• Ecolab Usa Inc

Inventors

• Cabanas Jesus
• Schacht Paul
• Williams Brian
• Miralles Altony
• Court Colin
• Power Caleb

Classifications

• C11D3/0073 Primary

  Anticorrosion compositions · CPC title

• C11D3/2086

  Hydroxy carboxylic acids-salts thereof · CPC title

• C11D7/10

  Salts · CPC title

• B08B9/0328

  by purging the pipe with a gas or a mixture of gas and liquid · CPC title

• C11D7/265

  Carboxylic acids or salts thereof · CPC title