Corn syrup, an inversion aid for water-in-oil polymer emulsions

Patent metadata

Field	Value
Publication number	US-10655080-B2
Application number	US-201715435414-A
Country	US
Kind code	B2
Filing date	Feb 17, 2017
Priority date	Feb 17, 2016
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

The present invention generally relates to the method of using corn syrup to improve the inversion properties of water-in-oil (w/o) friction reducing polymers.

First claim

What is claimed is:

1. A method of inverting a water-in-oil emulsion comprising contacting an aqueous liquid with water-in-oil emulsion comprising a polymer and from about 5 wt. % to about 25 wt. % corn syrup, whereby the water-in-oil emulsion inverts and releases the polymer and wherein the aqueous liquid comprises a high salinity brine.

2. The method of claim 1 whereby friction of an aqueous liquid flowing in a pipe is reduced.

3. The method of claim 2 , wherein the water-in-oil emulsion further comprises a surfactant, a stabilizer, or a combination thereof.

4. The method of claim 1 , wherein the aqueous liquid further comprises purified water, produced water, or a combination thereof.

5. The method of claim 1 , wherein the polymer is derived from an anionic monomer, a cationic monomer, a nonionic monomer, or a combination thereof.

6. The method of claim 5 , wherein the anionic monomer comprises acrylic acid, methacrylic acid, maleic acid, itaconic acid, 2-propenoic acid, 2-methyl-2-propenoic acid, 2-acrylamido-2-methyl propane sulfonic acid, sulfopropyl acrylic acid, sulphomethylated acrylamide, allyl sulphonic acid, vinyl sulphonic acid, a quaternary salt of acrylic acid, a quaternary salt of methacrylic acid, acrylamidoglycolic acid, -allyloxy-2-hydroxy-1-propanesulfonic acid, dialkyl aminoethyl acrylate, styrene sulfonic acid, 2-acrylamido-2-methylpropane phosphonic acid, an acid or salt of these monomers, or a combination of these monomers.

7. The method of claim 6 , wherein the anionic monomer comprises acrylic acid or salt thereof, 2-acrylamido-2-propane sulfonic acid or salt thereof, or a combination thereof.

8. The method of claim 5 , wherein the cationic monomer comprises a salt or a quaternary salt of a dialkylaminoalkyl acrylate, a salt or a quaternary salt of a dialkylaminoalkyl methacrylate, a salt or a quaternary salt of a dialkylaminoalkylacrylamide, a salt or a quaternary salt of a dialkylaminoalkylmethacrylamide, a N,N-diallyldialkyl ammonium halide, or a combination thereof.

9. The method of claim 5 wherein the cationic monomer comprises dimethylaminoethylacrylate methyl chloride quaternary salt (DMAEA.MCQ), dimethylaminoethylmethacrylate methyl chloride quaternary salt (DMAEM.MCQ), dimethylaminoethylacrylate hydrochloric acid salt, dimethylaminoethylacrylate sulfuric acid salt, dimethylaminoethyl acrylate benzyl chloride quaternary salt (DMAEA.BCQ) dimethylaminoethylacrylate methyl sulfate quaternary salt, dimethylaminopropyl acrylamide hydrochloric acid salt, dimethylaminopropyl acrylamide sulfuric acid salt, dimethylaminopropyl methacrylamide hydrochloric acid salt, dimethylaminopropyl methacrylamide sulfuric acid salt, methacrylamidopropyl trimethyl ammonium chloride, acrylamidopropyl trimethyl ammonium chloride, diallyldimethyl ammonium chloride (DAD MAC), or a combination thereof.

10. The method of claim 9 , wherein the cationic monomer comprises dimethyl-aminoethyl-acrylate methyl chloride quaternary salt (DMAEA-MCQ), dimethyl-aminoethyl-methacrylate methyl chloride quaternary salt (DMAEM-MCQ), diallyl-dimethyl-ammonium chloride (DADMAC), or a combination thereof.

11. The method of claim 5 , wherein the nonionic monomer comprises N-isopropylacrylamide, N,N-dimethylacrylamide, N,N-diethylacrylamide, dimethylaminopropyl acrylamide, dimethylaminopropyl methacrylamide, acryloylmorpholine, hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, hydroxypropyl methacrylate, dimethylaminoethylacrylate (DMAEA), dimethylaminoethyl methacrylate (DMAEM), maleic anhydride, N-vinyl pyrrolidone, vinyl acetate, N-vinyl formamide, acrylamide, methacrylamide, N-methylacrylamide, methyl acrylate, methyl methacrylate, acrylonitrile, N-vinyl methylformamide, acrolein, N,N-diallylamine, or a combination thereof.

12. The method of claim 10 , wherein the nonionic monomer comprises acrylamide, methacrylamide, or a combination thereof.

13. The method of claim 3 , wherein the surfactant comprises an alcohol ethoxylate, a quaternary ammonium salt, an anionic surfactant sulfate, an anionic surfactant sulfonate, a zwitterionic surfactant comprising a quaternary ammonium cation and a carboxylate (betaine), or a combination thereof.

14. The method of claim 3 , wherein the stabilizer comprises sodium thiosulfate, ammonium thiosulfate, sodium thiocyanate, ammonium thiocyanate, sodium metabisulfite, or a combination thereof.

15. The method of claim 1 , wherein the polymer is derived from acrylamide and sodium acrylate monomers and the amount of sodium acrylate repeat units incorporated into the polymer is from about 22 mole % to about 30 mole %.

16. The method of claim 1 , wherein the polymer is derived from acrylamide and dimethyl-aminoethyl-methacrylate methyl chloride quaternary salt (DMAEM-MCQ) monomers and the amount of dimethyl-aminoethyl-methacrylate methyl chloride quaternary salt (DMAEM-MCQ) repeat units incorporated into the polymer is from about 0.5 mole % about to about 30 mole %.

17. The method of claim 16 , wherein the amount of dimethyl-aminoethyl-methacrylate methyl chloride quaternary salt (DMAEM-MCQ) repeat units incorporated into the polymer is from about 1 mole % to about 10 mole %.

18. The method of claim 1 , wherein the water-in-oil emulsion is contacted to an aqueous liquid at a concentration from about 0.1 gallons per thousand gallons (gpt) to about 5 gpt.

19. The method of claim 1 , wherein the high salinity brine has a salinity of up to 300,000 mg/L of total dissolved solids.

20. The method of claim 19 , wherein the salinity of the high salinity brine is from about 4 wt. % to about 30 wt. % dissolved solids.

21. The method of claim 1 , wherein the high salinity brine comprises about 4 wt. % of a sodium chloride solution.

Assignees

• Ecolab Usa Inc

Inventors

• El Ojaimi Maya
• Street Joseph Paul
• Kurian Pious

Classifications

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10M107/42

  Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C10M2209/084

  Acrylate; Methacrylate · CPC title

• C10M2217/0245

  used as base material · CPC title

• C10M2209/12

  Polysaccharides, e.g. cellulose, biopolymers · CPC title