Polyalkylene terephthalate resin composition

Patent metadata

Field	Value
Publication number	US-10655007-B2
Application number	US-201515539958-A
Country	US
Kind code	B2
Filing date	Dec 14, 2015
Priority date	Dec 26, 2014
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

Disclosed are: a polyalkylene terephthalate resin composition comprising (A) a polyalkylene terephthalate resin and (B) an acrylic-based core-shell polymer which has an average particle size of 2 μm or greater and in which an amount of the core layer component is more than 80% by mass but less than 100% by mass relative to a total mass of the core layer component and a shell layer component; and a molded article which is obtained by molding the polyalkylene terephthalate resin composition.

First claim

The invention claimed is:

1. An insert molded article obtained by performing insert molding using a polyalkylene terephthalate resin composition and an insert member comprising a metal or an inorganic solid, wherein
the polyalkylene terephthalate resin composition comprises (A) a polyalkylene terephthalate resin, and (B) an acrylic-based core-shell polymer which has an average particle size of 2 μm or greater and in which an amount of a core layer component is at least 85% by mass but not more than 95% by mass relative to a total mass of the core layer component and a shell layer component, an amount of (B) the acrylic-based core-shell polymer is at least 10 parts by mass but not more than 30 parts by mass per 100 parts by mass of (A) the polyalkylene terephthalate resin,
the polyalkylene terephthalate resin composition further comprises (C) a filler in an amount of at least 10 parts by mass but not more than 100 parts by mass per 100 parts by mass of (A) the polyalkylene terephthalate resin,
(A) the polyalkylene terephthalate resin comprises a polybutylene terephthalate resin, the core layer component of (B) the acrylic-based core-shell polymer comprises a polymer formed using a C 1 to C 12 alkyl acrylate, the shell layer component of (B) the acrylic-based core-shell polymer comprises a polymer formed using a C 1 to C 20 alkyl methacrylate, and
the polyalkylene terephthalate resin composition is a composition wherein, when the following insert molded article A is produced, the insert molded article A satisfies the following heat shock resistance condition A, wherein
insert molded article A: an insert molded article into which an L-shaped iron plate with 21 mm in a width×90 mm×90 mm and a thickness of 1.6 mm is inserted, and in which a resin portion is an L-shaped plate with 25 mm in a width×70 mm×70 mm and a thickness of 3.6 mm, in which a minimum wall thickness in part of the resin portion is 1 mm, and
heat shock resistance condition A: in a heat shock resistance test using a thermal shock tester in which a process of performing heating at 140° C. for 1 hour and 30 minutes, subsequently lowering a temperature to −40° C. and performing cooling for 1 hour and 30 minutes, and then raising a temperature back to 140° C. is deemed one cycle, a number of cycles performed before cracking appears in the molded article is at least 100, and
the insert member is a plate-like electrical connection conductor, and the insert member has a ratio of 12.5 or greater for a maximum width relative to a maximum thickness in a cross-section perpendicular to a lengthwise direction of a planar surface of the plate-like conductor.

2. The insert molded article according to claim 1 , wherein the average particle size of the component (B) is at least 2.5 μm but not more than 20 μm, and the amount of the core layer component is at least 85% by mass but not more than 95% by mass relative to the total mass of the core layer component and the shell layer component.

3. The insert molded article according to claim 1 , wherein the average particle size of the component (B) is at least 3 μm but not more than 10 μm, and the amount of the core layer component is at least 90% by mass but not more than 92% by mass relative to the total mass of the core layer component and the shell layer component.

4. The insert molded article according to claim 1 , wherein the average particle size of the component (B) is about 3 μm, and the amount of the core layer component is about 90% by mass relative to the total mass of the core layer component and the shell layer component.

5. The insert molded article according to claim 1 , wherein the polyalkylene terephthalate resin composition is a composition wherein, when the following insert molded article B is produced, the insert molded article B satisfies the following heat shock resistance condition B, wherein
insert molded article B: an insert molded article into which an I-shaped iron plate with 20 mm in a width×150 mm and a thickness of 1.6 mm is inserted, and in which a resin portion is an I-shaped plate with a 25 mm in a width×120 mm and a thickness of 4 mm, in which a minimum wall thickness in part of the resin portion is 1 mm, and
heat shock resistance condition B: in a heat shock resistance test using a thermal shock tester in which a process of performing heating at 140° C. for 1 hour and 30 minutes, subsequently lowering a temperature to −40° C. and performing cooling for 1 hour and 30 minutes, and then raising a temperature back to 140° C. is deemed one cycle, a number of cycles performed before cracking appears in the molded article is at least 40.

6. An insert molded article obtained by performing insert molding using a polyalkylene terephthalate resin composition and an insert member comprising a metal or an inorganic solid, wherein:
the polyalkylene terephthalate resin composition comprises (A) a polyalkylene terephthalate resin, and (B) an acrylic-based core-shell polymer which has an average particle size of 2 μm or greater and in which an amount of a core layer component is at least 85% by mass but not more than 95% by mass relative to a total mass of the core layer component and a shell layer component, an amount of (B) the acrylic-based core-shell polymer is at least 10 parts by mass but not more than 30 parts by mass per 100 parts by mass of (A) the polyalkylene terephthalate resin,
the polyalkylene terephthalate resin composition further comprises (C) a filler in an amount of at least 10 parts by mass but not more than 100 parts by mass per 100 parts by mass of (A) the polyalkylene terephthalate resin, (A) the polyalkylene terephthalate resin comprises a polybutylene terephthalate resin, the core layer component of (B) the acrylic-based core-shell polymer comprises a polymer formed using a C 1 to C 12 alkyl acrylate, the shell layer component of (B) the acrylic-based core-shell polymer comprises a polymer formed using a C 1 to C 20 alkyl methacrylate, and
the polyalkylene terephthalate resin composition is a composition wherein, when the following insert molded article B is produced, the insert molded article B satisfies the following heat shock resistance condition B, wherein
insert molded article B: an insert molded article into which an I-shaped iron plate with 20 mm in a width×150 mm and a thickness of 1.6 mm is inserted, and in which a resin portion is an I-shaped plate with a 25 mm in a width×120 mm and a thickness of 4 mm, in which a minimum wall thickness in part of the resin portion is 1 mm, and
heat shock resistance condition B: in a heat shock resistance test using a thermal shock tester in which a process of performing heating at 140° C. for 1 hour and 30 minutes, subsequently lowering a temperature to −40° C. and performing cooling for 1 hour and 30 minutes, and then raising a temperature back to 140° C. is deemed one cycle, a number of cycles performed before cracking appears in the molded article is at least 40, and
the insert member is a plate-like electrical connection conductor, and the insert member has a ratio of 12.5 or greater for a maximum width relative to a maximum thickness in a cross-section perpendicular to a lengthwise direction of a planar surface of the plate-like conductor.

7. The insert molded article according to claim 6 , wherein the average particle size of the component (B) is at least 2.5 μm but not more than 20 μm, and the amount of the core layer component is at least 85% by mass but not more than 95% by mass relative to the total mass of the core layer component and the shell layer component.

8. The insert molded article according to claim 6 , wherein the average particle size of the component (B) is at least 3 μm but not more than 10 μm, and the amount of the core layer component is at least

Assignees

• Wintech Polymer Ltd
• Kaneka Corp
• Polyplastics Co

Inventors

• Sakata Kouichi
• Yamada Shinya
• Yamamoto Nobuhiro
• Yamamoto Tetsuro
• Matsuoka Yoshiaki
• Fujimoto Toyohisa

Classifications

• Y10T428/24777

  Edge feature · CPC title

• B32B15/04

  comprising metal as the main or only constituent of a layer, {which is} next to another layer of {the same or of} a {different material (next to a bituminous or tarry layer B32B11/08; next to a water-setting substance layer B32B13/06; next to a glass layer B32B17/061; next to a cellulosic plastic layer B32B23/042)} · CPC title

• B29K2867/006

  PBT, i.e. polybutylene terephthalate · CPC title

• B32B27/06

  as the main or only constituent of a layer, {which is} next to another layer of {the same or of} a {different material (next to a layer of a particular substance B32B9/045; next to a bituminous or tarry layer B32B11/046; next to a water setting substance layer B32B13/12; next to a metal layer B32B15/08; next to a glass layer B32B17/10; next to a layer formed of natural mineral fibres or particles B32B19/045; next to a wood layer B32B21/08; next to a cellulosic plastic layer B32B23/08; next to a natural or synthetic rubber layer B32B25/08)} · CPC title

• Y10T428/2982

  Particulate matter [e.g., sphere, flake, etc.] · CPC title