Hydrogel forming composition and hydrogel formed thereof

Patent metadata

Field	Value
Publication number	US-10655000-B2
Application number	US-201415035891-A
Country	US
Kind code	B2
Filing date	Nov 10, 2014
Priority date	Nov 11, 2013
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

An organic/inorganic composite hydrogel can be prepared only through mixing at a room temperature and that has high modulus of elasticity and a self-supporting property that allows a shape to be maintained in water, and a method produces the hydrogel. A hydrogel forming composition that is capable of forming a hydrogel having a self-supporting property, includes: a water-soluble organic polymer having an organic acid structure, an organic acid salt structure, or an organic acid anion structure; a silicate salt; a dispersant for the silicate salt; and a compound having or generating divalent or higher valent positive charge; a hydrogel formed of the composition, and a method for producing the hydrogel.

First claim

The invention claimed is:

1. A hydrogel forming composition that is capable of forming a hydrogel having a self-supporting property, comprising:
a water-soluble organic polymer having an organic acid structure, an organic acid salt structure, or an organic acid anion structure, and having a weight average molecular weight of 1,000,000 to 10,000,000;
a silicate salt, comprising water-swellable silicate salt particles selected from the group consisting of smectite and vermiculite;
a dispersant for the water-swellable silicate salt particles, comprising one or more selected from the group consisting of sodium polyacrylate having a weight average molecular weight of 1,000 to 20,000, ammonium poly(meth)acrylate, a sodium acrylate/sodium maleate copolymer, an ammonium acrylate/ammonium maleate copolymer, hydroxylamine, sodium carbonate, sodium silicate, polyethylene glycol, polypropylene glycol, sodium humate, and sodium ligninsulfonate; and
a compound having or generating divalent or higher valent positive charge, which is one or more selected from the group consisting of magnesium chloride, magnesium bromide, magnesium sulfate, magnesium nitrate, magnesium carbonate, magnesium acetate, a hydroxide of magnesium, an oxide of magnesium, a salt of calcium, a hydroxide of calcium, an oxide of calcium, a salt of aluminum, a hydroxide of aluminum, an oxide of aluminum, a diamine, and a salt of a diamine.

2. The hydrogel forming composition according to claim 1 , wherein the compound is one or more selected from the group consisting of magnesium chloride, magnesium bromide, magnesium sulfate, magnesium nitrate, magnesium carbonate, magnesium acetate, magnesium hydroxide, magnesium oxide, calcium chloride, calcium bromide, calcium sulfate, calcium nitrate, calcium carbonate, calcium acetate, calcium hydroxide, calcium oxide, calcium lactate, calcium phosphate, calcium diphosphate, calcium hexametaphosphate, aluminum sulfate, aluminum hydroxide, aluminum oxide, ethylenediamine, ethylenediamine dihydrochloride, ethylenediamine sulfate, bis(aminoethoxy)ethane, bis(aminoethoxy)ethane dihydrochloride, and bis(aminoethoxy)ethane sulfate.

3. The hydrogel forming composition according to claim 1 , wherein the water-soluble organic polymer is a water-soluble organic polymer having a carboxylic acid structure, a carboxylate salt structure, or a carboxy anion structure.

4. The hydrogel forming composition according to claim 3 , wherein the water-soluble organic polymer is a fully neutralized or partially neutralized polyacrylate salt.

5. The hydrogel forming composition according to claim 1 , further comprising a water-containing alcohol, a water-containing polyhydric alcohol, or a mixture thereof.

6. The hydrogel forming composition according to claim 5 , wherein the water-containing alcohol, water-containing polyhydric alcohol, or mixture thereof comprises alcohol in an amount of 0.1% by mass to 80% by mass, based on 100% by mass of the water-containing alcohol, water-containing polyhydric alcohol, or mixture thereof, the balance being water.

7. A method for producing a hydrogel having a self-supporting property from the hydrogel forming composition according to claim 1 , comprising:
mixing and gelatinizing the water-soluble organic polymer, the silicate salt, the dispersant for the water-swellable silicate salt particles, the compound having or generating divalent or higher valent positive charge and water or a water-containing solvent.

8. A hydrogel having a self-supporting property, formed from the hydrogel forming composition as claimed in claim 1 .

9. The hydrogel according to claim 8 , wherein the hydrogel comprises, based on 100% by mass of the hydrogel:
the water-soluble organic polymer in an amount of 0.1% by mass to 20% by mass;
the silicate salt in an amount of 0.01% by mass to 20% by mass;
the dispersant in an amount of 0.001% by mass to 20% by mass; and
the compound having or generating divalent or higher valent positive charge in an amount of 0.01% by mass to 20% by mass.

10. The hydrogel according to claim 8 , wherein the hydrogel comprises, based on 100% by mass of the hydrogel:
the water-soluble organic polymer in an amount of 0.1% by mass to 10% by mass;
the silicate salt in an amount of 0.1% by mass to 10% by mass;
the dispersant in an amount of 0.01% by mass to 10% by mass; and
the compound having or generating divalent or higher valent positive charge in an amount of 0.05% by mass to 10% by mass.

11. The hydrogel according to claim 8 , wherein the hydrogel exhibits a modulus of elasticity of 5 kPa to 10,000 kPa.

12. The hydrogel according to claim 11 , wherein the modulus of elasticity of the hydrogel is 20 kPa to 10,000 kPa.

13. The hydrogel according to claim 8 , wherein the hydrogel comprises, based on 100% by mass of the hydrogel:
0.1% by mass to 20% by mass of the water-soluble organic polymer;
0.01% by mass to 20% by mass of the silicate salt;
0.001% by mass to 20% by mass of the dispersant for the water-swellable silicate salt particles;
0.01% by mass to 20% by mass of the compound having or generating divalent or higher valent positive charge; and
greater than 0% by mass to 80% by mass of a water-containing alcohol, a water-containing polyhydric alcohol, or a mixture thereof, the water-containing alcohol, water-containing polyhydric alcohol, or mixture thereof comprising alcohol in an amount of 0.1% by mass to 80% by mass, based on 100% by mass of the water-containing alcohol, water-containing polyhydric alcohol, or mixture thereof, the balance being water.

14. The hydrogel according to claim 13 , wherein the hydrogel exhibits a modulus of elasticity of 5 kPa to 10,000 kPa.

15. The hydrogel according to claim 14 , wherein the modulus of elasticity of the hydrogel is 20 kPa to 10,000 kPa.

Assignees

• Nissan Chemical Ind Ltd
• Riken

Inventors

• Kudo Yoshihiro
• Nakazawa Taichi
• Aida Takuzo
• Ishida Yasuhiro
• Tamesue Shingo
• Ohtani Masataka

Classifications

• C08K3/011

  Crosslinking or vulcanising agents, e.g. accelerators · CPC title

• C08J3/075

  Macromolecular gels · CPC title

• C08F220/10

  Esters · CPC title

• C08L33/06

  of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical · CPC title

• C08L33/02 Primary

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title