Method for producing thermoplastic resin

Patent metadata

Field	Value
Publication number	US-10654972-B2
Application number	US-201615769486-A
Country	US
Kind code	B2
Filing date	Nov 2, 2016
Priority date	Nov 4, 2015
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

The present invention provides a method for producing a thermoplastic resin by reacting reactants comprising a dihydroxy compound. In this production method, the dihydroxy compound comprises a dihydroxy compound represented by the following formula (1), wherein the total weight of a compound represented by the following formula (A), a compound represented by the following formula (B), and a compound represented by the following formula (C) in the dihydroxy compound is 1,500 ppm or less, based on 100 parts by weight of the dihydroxy compound represented by the formula (1):

First claim

The invention claimed is:

1. A method for producing a thermoplastic resin by reacting reactants comprising a dihydroxy compound, wherein
the dihydroxy compound comprises a dihydroxy compound represented by the following formula (1), wherein
the total weight of a compound represented by the following formula (A), a compound represented by the following formula (B), and a compound represented by the following formula (C) in the dihydroxy compound is 1,500 ppm or less, based on 100 parts by weight of the dihydroxy compound represented by the formula (1):

wherein X represents an alkylene group containing 1 to 4 carbon atoms,
wherein the dihydroxy compound further comprises 9,9-bis(4-(2-hydroxyethoxy)-3-phenylphenyl)fluorine, and
the molar ratio of the compound of formula (1) to the 9,9-bis(4-(2-hydroxyethoxy)-3-phenylphenyl)fluorine is 40/60 to 50/50, and
wherein (A), (B), and (C) are:

2. The production method according to claim 1 , wherein the weight average molecular weight of the thermoplastic resin is 35,000 to 70,000.

3. The production method according to claim 1 , wherein the weight of the compound represented by the formula (A) in the dihydroxy compound is 300 ppm or less, based on 100 parts by weight of the dihydroxy compound represented by the formula (1).

4. The production method according to claim 1 , wherein the weight of the compound represented by the formula (B) in the dihydroxy compound is 100 ppm or less, based on 100 parts by weight of the dihydroxy compound represented by the formula (1).

5. The production method according to claim 1 , wherein the weight of the compound represented by the formula (C) in the dihydroxy compound is 100 ppm or less, based on 100 parts by weight of the dihydroxy compound represented by the formula (1).

6. The production method according to claim 1 , wherein the purity of the dihydroxy compound represented by the formula (1) is 99% or more.

7. The production method according to claim 1 , wherein the thermoplastic resin is selected from the group consisting of a polycarbonate resin, a polyester resin, and a polyester carbonate resin.

8. The production method according to claim 7 , wherein the thermoplastic resin is a polycarbonate resin.

9. The production method according to claim 1 , wherein the reactants further comprise carbonic acid diester.

10. The production method according to claim 1 , wherein the saturated water absorption rate of the thermoplastic resin is 0.39% by weight or less.

11. A method for producing an optical element, comprising forming the optical element with the thermoplastic resin produced by the production method according to claim 1 .

12. A method for producing an optical lens, comprising forming the optical lens with the thermoplastic resin produced by the production method according to claim 1 .

13. A method for producing an optical film, comprising forming the optical film with the thermoplastic resin produced by the production method according to claim 1 .

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Kato Noriyuki
• Kondo Mitsuteru
• SHIRATAKE Munenori
• Ishihara Kentaro
• Hirose Koji
• Ikeda Shinya

Classifications

• G02B1/04

  made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title

• G02B1/041

  Lenses · CPC title

• C08G63/668

  derived from polycarboxylic acids and polyhydroxy compounds · CPC title

• C08G63/66

  Polyesters containing oxygen in the form of ether groups (C08G63/42, C08G63/58 take precedence) · CPC title

• C08G64/16 Primary

  Aliphatic-aromatic or araliphatic polycarbonates · CPC title