Method for preparing superabsorbent polymer

Patent metadata

Field	Value
Publication number	US-10654959-B2
Application number	US-201615554852-A
Country	US
Kind code	B2
Filing date	Apr 11, 2016
Priority date	Aug 13, 2015
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

The present invention provides a method for preparing a superabsorbent polymer, the method comprising the steps of: forming a function gel polymer by cross-linked polymerization of a monomer mixture under the presence of an internal cross-linking agent, the monomer mixture including a water-soluble ethylene-based unsaturated monomer having an acid group at least part of which is neutralized, a carbonate, a volatile organic solvent, a surfactant, and a bubble promoting agent; forming a base resin powder by drying, grinding, and classifying the function gel polymer; and forming a surface cross-linked layer by additional cross-linking of the surface of the base resin powder under the presence of a surface cross-linking agent. The method for preparing a superabsorbent polymer may provide a superabsorbent polymer which has a porous structure, thereby exhibiting an excellent absorption rate while exhibiting excellent gel strength.

First claim

The invention claimed is:

1. A method of preparing a superabsorbent polymer, the method comprising the steps of:
performing crosslinking polymerization of a monomer mixture to form a water-containing gel polymer, wherein the monomer mixture includes water-soluble ethylene-based unsaturated monomers having acidic groups which are at least partially neutralized, a carbonate, a volatile organic solvent, a surfactant, and a foam promoter, and wherein an internal crosslinking agent is used in the crosslinking polymerization of the monomer mixture;
drying, pulverizing, and size-sorting the water-containing gel polymer to form a base polymer powder; and
additionally crosslinking the surface of the base polymer powder to form a surface-crosslinked layer, wherein a surface crosslinking agent is used in the crosslinking of the surface of the base polymer powder, and
wherein the surfactant is a silicone-based surfactant and is used in an amount of 0.00001% by weight to 0.00100% by weight with respect to a total weight of the monomer mixture,
the foam promoter is an inorganic acid aluminum salt, and
centrifuge retention capacity (CRC) in a physiological saline solution is 29 g/g to 35 g/g, absorbency under load (AUL) of 0.9 psi in the physiological saline solution is 17 g/g to 21 g/g, a vortex time is 30 seconds to 50 seconds, and absorbency under load of the superabsorbent polymer, as measured after swelling the superabsorbent polymer in the physiological saline solution under a load of 0.3 psi for 5 minutes and removing residual liquid under vacuum, is 18 g/g to 21 g/g.

2. The method of claim 1 , wherein one or more selected from the group consisting of magnesium carbonate, calcium carbonate, sodium bicarbonate, sodium carbonate, potassium bicarbonate, and potassium carbonate are used as the carbonate.

3. The method of claim 1 , wherein an organic solvent having a boiling point of 15° C. to 80° C. is used as the volatile organic solvent.

4. The method of claim 1 , wherein a constitutional isomer of pentane, a constitutional isomer of hexane, acetone, methanol, ethanol, or a mixture thereof is used as the volatile organic solvent.

5. The method of claim 1 , wherein the volatile organic solvent and the carbonate are used in an amount of 0.001% by weight to 0.5% by weight with respect to a total weight of the monomer mixture, respectively.

6. The method of claim 1 , wherein the carbonate and the volatile organic solvent are used in a weight ratio of 1:1 to 1:2.

7. The method of claim 1 , wherein the foam promoter is used in an amount of 0.001% by weight to 1% by weight with respect to a total weight of the monomer mixture.

8. The method of claim 1 , wherein the monomer mixture is subjected to crosslinking polymerization in a temperature range of 40° C. to 90° C.

9. The method of claim 1 , wherein one or more polyols selected from the group consisting of ethylene glycol, propylene glycol, 1,4-butanediol, 1,6-hexanediol, 1,2-hexanediol, 1,3-hexanediol, 2-methyl-1,3-propanediol, 2,5-hexanediol, 2-methyl-1,3-pentanediol, 2-methyl-2,4-pentanediol, tripropylene glycol, and glycerol; or one or more carbonate-based compounds selected from the group consisting of ethylene carbonate and propylene carbonate are used as the surface crosslinking agent.

10. The method of claim 1 , wherein the surface crosslinking agent is used in an amount of 0.01% by weight to 3% by weight with respect to a total weight of the base polymer powder.

11. The method of claim 1 , wherein one or more inorganic materials selected from the group consisting of silica, clay, alumina, a silica-alumina composite, titania, zinc oxide, and aluminum sulfate are used in the crosslinking of the surface of the base polymer powder.

12. The method of claim 1 , wherein the surface-crosslinked layer is formed at a temperature of 100° C. to 250° C.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Soo Jin
• Nam Hye Mi
• Lee Sang Gi
• Hwang Min Ho
• Jang Tae Hwan

Classifications

• C08L51/08 Primary

  grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds · CPC title

• C08F220/06 Primary

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C08J2351/08

  grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C08J3/075

  Macromolecular gels · CPC title

• C08F2/10

  Aqueous solvent · CPC title