Gypsum additive to control mercury

Patent metadata

Field	Value
Publication number	US-10654753-B2
Application number	US-201716289379-A
Country	US
Kind code	B2
Filing date	Aug 7, 2017
Priority date	Sep 1, 2016
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

Additives including sulfur-containing compounds are used in methods of treating synthetic gypsum. The additives can thermally stabilize heavy metals, such as mercury. This thermal stabilization reduces mercury release from the synthetic gypsum. Illustrative, non-limiting examples of sulfur-containing compounds include inorganic sulfides, organic sulfides, organic compounds containing nitrogen and sulfur, organic compounds containing oxygen and sulfur, and polymers containing sulfur.

First claim

What is claimed is:

1. A method of treating synthetic gypsum, comprising:
transporting the synthetic gypsum from a wet flue gas desulfurizer; and
contacting the synthetic gypsum with an additive, the additive comprising a sulfur-containing compound and water, wherein the sulfur-containing compound is a polymer comprising sulfur that is modified to contain at least one of a sulfide and a dithiocarbamate salt group.

2. The method of claim 1 , wherein the polymer comprising sulfur comprises about 5 mole % to about 100 mole % of dithiocarbamate salt groups.

3. The method of claim 1 , wherein the polymer comprising sulfur comprises the following structure:

4. The method of claim 1 , wherein the polymer comprising sulfur is formulated with a sulfide precipitant.

5. The method of claim 1 , wherein the polymer comprising sulfur is formed by reacting glycidyl (meth)acrylate, allyl glycidyl ether or [(vinyloxy)methyl]oxirane with ammonia or a primary amine to form a first product, reacting the first product with one or more of acrylic acid, vinyl alcohol, vinyl acetate, acrylamide, methylacrylic acid, and methylacrylamide to form a second product, and reacting the second product with a dithiocarbamic acid salt.

6. The method of claim 1 , wherein the synthetic gypsum is contacted by the additive in a conduit leading to a kiln.

7. A method of treating synthetic gypsum, comprising:
transporting the synthetic gypsum from a wet flue gas desulfurizer; and
contacting the synthetic gypsum with an additive, the additive comprising a sulfur-containing compound, wherein the sulfur-containing compound is a polymer comprising sulfur that comprises a weight average molecular weight of about 500 g/mol to about 200,000 g/mol.

8. A composition comprising synthetic gypsum, mercury, and an additive, the additive comprising a sulfur-containing compound, wherein the sulfur-containing compound comprises a polymer including at least an acrylic-x monomer and an alkylamine, wherein the acrylic-x monomer comprises the following generic structure:

wherein X may be OR, OH, salts of OR, salts of OH, or NHR 2 ;
R 1 and R 2 are independently selected from H, an alkyl group, or an aryl group; and R is an alkyl group or an aryl group.

9. The composition of claim 8 , wherein the polymer comprises at least one of a sulfide and a dithiocarbamate salt group.

10. The composition of claim 8 , wherein the alkylamine comprises a member selected from the group consisting of an ethyleneamine, a polyethylenepolyamine, an ethylenediamine, a diethylenetriamine, a triethylenetetraamine, a tetraethylenepentamine, a pentaethylenehexamine, and any combination thereof.

Assignees

• Ecolab Usa Inc

Inventors

• Keiser Bruce A
• Carlson Wayne M
• Denny Nicholas R
• Yuan Jianwei
• Chen Tommy Hung-Ting

Classifications

• C04B11/007 Primary

  After-treatment of the dehydration products, e.g. aging, stabilisation · CPC title

• C04B24/121 Primary

  Amines, polyamines · CPC title

• C04B24/2641

  Polyacrylates; Polymethacrylates · CPC title

• C04B24/38

  Polysaccharides or derivatives thereof {(C04B24/243 takes precedence)} · CPC title

• C04B24/14

  Peptides; Proteins; Derivatives thereof · CPC title