Apparatus for salt separation under supercritical water conditions

Patent metadata

Field	Value
Publication number	US-10654738-B2
Application number	US-201615543864-A
Country	US
Kind code	B2
Filing date	Jan 13, 2016
Priority date	Jan 16, 2015
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

Apparatus for salt separation ( 2 ) under supercritical water conditions, comprising a heat exchanger ( 4 ) and a fluidized bed reactor ( 6 ). The fluidized bed reactor comprising a supercritical water pressure containing wall ( 8 ) defining therein a fluidized bed chamber ( 10 ) connected to an inlet system ( 16 ) at one end thereof and an outlet system ( 18 ) configured to separate solids from supercritical fluid at another end thereof. The fluidized bed chamber receives a fluidized bed ( 12 ) therein and is configured to receive through the inlet system ( 16 ) a liquefied aqueous substance ( 14 ) for treatment in the fluidized bed chamber. The inlet system ( 16 ) comprises an inlet chamber ( 20 ) and a fluidization plate ( 22 ) positioned between the inlet chamber ( 20 ) and the fluidized bed chamber ( 10 ). The fluidized bed chamber extends between the inlet system ( 16 ) and outlet system ( 18 ) and comprises an entry section ( 10 a ) adjacent the inlet system ( 16 ), an outlet section ( 10 c ) adjacent the outlet system ( 18 ), and a mid-section ( 10 b ) extending between the entry section and the outlet section. The heat exchanger ( 4 ) extends along the fluidized bed chamber ( 10 ) and is configured to generate a decreasing temperature gradient in the fluidized bed chamber from the outlet section ( 10 c ) to the entry section ( 10 a ), the temperature gradient in the outlet section and mid-section being supercritical for aqueous substances and being subcritical for aqueous substances in the entry section ( 10 a ) adjacent the fluidization plate ( 22 ).

First claim

The invention claimed is:

1. An apparatus for salt separation from an aqueous liquefied stream under supercritical water conditions, comprising:
a fluidized bed reactor including:
a fluidized bed chamber defined by a supercritical water pressure containing wall, and containing a fluidized bed therein;
an inlet system at one end of said fluidized bed reactor, said inlet system including an inlet in fluid communication with an inlet chamber and a fluidization plate positioned between the inlet chamber and the fluidized bed chamber;
an outlet system to separate solids from supercritical fluid at the other end of said fluidized bed reactor and spaced from the fluidized bed chamber;
wherein the fluidized bed chamber extends between the inlet system and outlet system and comprises an entry section adjacent the inlet system, an outlet section adjacent the outlet system, and a mid-section extending between the entry section and the outlet section; and

a heat exchanger extending through the fluidized bed chamber and comprising, in operation, a decreasing temperature gradient in the fluidized bed chamber from the outlet section to the inlet section, the temperature gradient in the outlet section and mid -section being supercritical for aqueous substances and being subcritical for aqueous substances in at least a first portion of the entry section adjacent the fluidization plate; and
wherein an aqueous liquefied stream is introduced into the inlet chamber, passes through said fluidization plate for treatment in the fluidized bed chamber, and solid particles in supercritical fluid exiting the fluidized bed chamber are removed by the outlet system.

2. An apparatus according to claim 1 , wherein the heat exchanger comprises a plurality of heat exchanger elements positioned within the fluidized bed chamber in a distributed manner, the heat exchanger elements receiving a heat exchange fluid therein and are connected to a heat exchange fluid inlet positioned at a level of the outlet system of the fluidized bed reactor, the heat exchange system comprising a heat exchange fluid outlet at a level of the inlet system of the fluidized bed reactor.

3. Apparatus according to claim 2 , wherein the heat exchange elements comprise a plurality of tubular elements arranged in a spaced apart and distributed manner and extend from the heat exchange fluid inlet to the heat exchange fluid outlet.

4. Apparatus according to claim 1 , wherein the heat exchanger comprises at least first and second heat exchange elements, the first heat exchange element being positioned in the entry section of the fluidized bed chamber to heat the liquefied aqueous substance in the fluidized bed chamber at a temperature that remains subcritical adjacent the fluidization plate, and the at least second heating element positioned in at least the mid-section to heat the liquefied aqueous substance at a supercritical temperature.

5. Apparatus according to claim 4 , comprising a heating element in at least the outlet section of the fluidized bed chamber for maintaining the aqueous substance at a supercritical temperature.

6. Apparatus according to claim 1 , wherein the fluidized bed reactor comprises a plurality of reactor elements each containing a fluidized bed chamber enclosed by a supercritical water pressure containing wall, the plurality of reactor elements with fluidized bed chambers being arranged in a distributed spaced apart manner and immersed in a heat exchanger chamber to receive a heat exchange fluid therein.

7. Apparatus according to claim 6 , wherein the heat exchange chamber comprises a heat exchange fluid inlet positioned at a level of the outlet system of the fluidized bed reactor, and a heat exchange fluid outlet at a level of the inlet system of the fluidized bed reactor.

8. Apparatus according to claim 6 , wherein the heat exchange chamber comprises one or more baffles to impart transverse flow to the heat exchange fluid across the plurality of fluidized bed chamber elements.

9. Apparatus according to claim 1 , wherein the fluidized bed reactor is arranged such that inlet system is vertically lower than the outlet system such that gravitational force on grains of the fluidized bed pull the grains towards the fluidization plate against the flow of fluid in the fluidized bed chamber.

Assignees

• Ecole Polytechnique Fed Lausanne Epfl
• Ecole Polytechnique Foderale De Lausanne Epfl

Inventors

• Favrat Daniel
• Marechal François
• Mian Alberto
• Viana Ensinas Adriano

Classifications

• C02F11/086 Primary

  in the supercritical state · CPC title

• C02F3/085

  Fluidized beds · CPC title

• C02F1/38

  by centrifugal separation · CPC title

• B01J3/008

  Processes carried out under supercritical conditions · CPC title

• Y02W10/15

  Cross-Sectional Technologies · mapped topic