Conductive thin-films for direct membrane surface electroheating

Patent metadata

Field	Value
Publication number	US-10654001-B2
Application number	US-201816023530-A
Country	US
Kind code	B2
Filing date	Jun 29, 2018
Priority date	Jun 30, 2017
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

A method is disclosed for preventing carbon nanotube degradation in ionizable environments. The method includes immersing a porous thin-film nanotube (CNT)/polymer composite Joule heating element in an ionizable environment; and applying an alternating current at a frequency of at least 100 Hz to the porous thin-film nanotube (CNT)/polymer composite Joule heating element in the ionizable environment.

First claim

What is claimed is:

1. A method for preventing carbon nanotube degradation in ionizable environments, the method comprising:
immersing a porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element in an ionizable environment;
applying an alternating current at a frequency of at least 100 Hz to the porous thin-film nanotube (CNT)/polymer composite Joule heating element in the ionizable environment; and
wherein the porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element acts as a resistor as the alternating current is applied through the porous thin-film nanotube (CNT)/polymer composite Joule heating element.

2. The method according to claim 1 , further comprising:
applying the alternating current at the frequency of at least 1000 Hz to the porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element in the ionizable environment.

3. The method according to claim 1 , further comprising:
applying the alternating current at the frequency of between 100 Hz and 10,000 Hz to the porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element in the ionizable environment.

4. The method according to claim 1 , further comprising:
applying the alternating current at the frequency of between 1000 Hz and 10,000 Hz to the porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element in the ionizable environment.

5. The method according to claim 1 , further comprising:
applying the alternating current at 20 Vpp (Voltage peak-to-peak).

6. The method according to claim 1 , wherein the ionizable environment is a membrane distillation (MD) desalination facility, the method further comprising:
heating a surface of the porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element.

7. The method according to claim 6 , further comprising:
flowing salinity brine through the surface of the porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element.

8. The method according to claim 1 , wherein the porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element is formed by:
preparing carbon nanotube films by sequential spray deposition of carbon nanotube (CNT) and polyvinyl alcohol (PVA) solutions on a porous polymeric membrane surface.

9. The method according to claim 1 , wherein the porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element is a hydrophilic-hydrophobic membrane.

10. A method of preparing a Joule heating element for ionizable media and desalination processes, the method comprising:
preparing a carbon nanotube (CNT) solution by suspending multiwalled CNTs functionalized with carboxylic groups and dodecylbenzenesulfonic acid (DDBS) in deionized (DI) water and sonicating the suspension in an ice bath and then centrifuging the suspension and collecting a supernatant; and
preparing carbon nanotube films by sequential spray deposition of the carbon nanotube (CNT) solution and a polyvinyl alcohol (PVA) solution on a porous polymeric membrane surface.

11. The method according to claim 10 , further comprising:
preparing the polyvinyl alcohol PVA solution by first dissolving PVA in DI water, followed by dilution with DI water before the sequential spray deposition.

12. The method according to claim 10 , further comprising:
heating the porous polymeric membrane surface using an air heater to facilitate solvent evaporation;
crosslinking and heating a network of the CNT solution and the PVA solution in a glutaraldehyde and a hydrochloric acid solution; and
drying the network of the CNT solution and the PVA solution and the porous polymeric membrane surface to form the Joule heating element.

13. A porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element configured for use in an ionizable media or a desalination process, the heating element comprising:
a carbon nanotube film comprising carbon nanotubes (CNT) and polyvinyl alcohol (PVA) on a porous polymeric membrane surface;
a pair of metal plates arranged on ends of the heating element;
an alternating current applied at a frequency of at least 100 Hz to the pair of metal plates and the heating element in the ionizable environment or the desalination process; and
wherein the porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element acts as a resistor as the alternating current is applied through the porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element between the pair of metal plates.

14. The heating element according to claim 13 , wherein the alternating current is applied to the heating element at the frequency of at least 1000 Hz.

15. The heating element according to claim 13 , wherein the alternating current is applied to the heating element at the frequency of between 100 Hz and 10,000 Hz.

16. The heating element according to claim 13 , wherein the alternating current is applied to the heating element at the frequency of between 1000 Hz and 10,000 Hz.

17. The heating element according to claim 13 , wherein the alternating current is applied at 20 Vpp (Voltage peak-to-peak).

18. The heating element according to claim 13 , wherein the heating element is a hydrophilic-hydrophobic membrane.

19. The method according to claim 1 , wherein the porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element has a carbon nanotube film thickness of 15±2 μm, an electrical conductivity (in water) of 1,700±200 S m −1 , and a hydrophilic surface having an air contact angle of 160±4°.

20. The heating element according to claim 13 , wherein the porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element has a carbon nanotube film thickness of 15±2 μm, an electrical conductivity (in water) of 1,700±200 S m −1 , and a hydrophilic surface having an air contact angle of 160±4°.

Assignees

• Univ California

Inventors

• Jassby David
• Dudchenko Alexander V

Classifications

• C02F1/447

  by membrane distillation (distillation and evaporation without the use of membranes C02F1/04) · CPC title

• C02F2303/08

  Corrosion inhibition · CPC title

• B01D61/368 Primary

  Accessories; Auxiliary operations · CPC title

• C02F2305/08

  Nanoparticles or nanotubes · CPC title

• C02F2103/08

  Seawater, e.g. for desalination · CPC title