Transparent laminate

Patent metadata

Field	Value
Publication number	US-10653560-B2
Application number	US-201515329779-A
Country	US
Kind code	B2
Filing date	Jul 9, 2015
Priority date	Jul 30, 2014
Publication date	May 19, 2020
Grant date	May 19, 2020

Abstract

A transparent laminate including: transparent substrate; and structure layer which contains protrusion portions, depression portions, or both on a surface thereof, average distance between the protrusion portions adjacent or the depression portions adjacent being equal to or less than wavelength of visible light; the structure layer including polymerized product of active-energy-ray-curable resin composition including composition of (meth)acrylate-based-polymerizable compound; the composition including at least any of the following (A) and (B), and the following (C) and (D): (A) ester (meth)acrylate of trihydric alcohol having main and side chain each including alkyl chain; (B) ester di(meth)acrylate of ethylene-oxide-modified bisphenol A; (C) polyalkylene glycol di(meth)acrylate; and (D) ester di(meth)acrylate of dihydric alcohol having main chain including linear alkyl chain; water contact angle on the surface of the structure layer being 26° or more and 74° or less; and storage elastic modulus at 180° C. of the structure layer being less than 0.5 GPa.

First claim

The invention claimed is:

1. A transparent laminate comprising:
a transparent substrate; and
a structure layer,
wherein the structure layer contains protrusion portions, depression portions, or both on a surface thereof,
the structure layer comprises a polymerized product of an active energy ray curable resin composition;
the active energy ray curable resin composition comprises a composition of a (meth)acrylate-based polymerizable compound;
the composition of a (meth)acrylate-based polymerizable compound comprises at least any of the following (A) and (B), and the following (C) and (D):
(A) an ester (meth)acrylate of a trihydric alcohol having a main chain and a side chain each comprising an alkyl chain;
(B) an ester di(meth)acrylate of ethylene oxide-modified bisphenol A;
(C) a polyalkylene glycol di(meth)acrylate; and
(D) an ester di(meth)acrylate of a dihydric alcohol having a main chain comprising a linear alkyl chain;

a water contact angle on a surface of the structure layer is 26° or more and 74° or less; and
a storage elastic modulus at 180° C. of the structure layer is less than 0.5 GPa,
when the structure layer has the protrusion portions, an average distance between the protrusion portions adjacent is equal to or less than a wavelength of visible light,
when the structure layer has the depression portions, an average distance between the depression portions adjacent is equal to or less than a wavelength of visible light, and
when the structure layer has the protrusion portions and the depression portions, the average distance between the adjacent protrusion portions and the average distance between the adjacent depression portions is each equal to or less than a wavelength of visible light.

2. The transparent laminate according to claim 1 , wherein the composition of a (meth)acrylate-based polymerizable compound comprises the (A), (B), (C) and (D).

3. The transparent laminate according to claim 1 , wherein the composition of a (meth)acrylate-based polymerizable compound comprises the (A) or the (B), the (C), and the (D), and the water contact angle is 26° or more and 60° or less.

4. The transparent laminate according to claim 1 , wherein the ester (meth)acrylate (A) of a trihydric alcohol having a main chain and a side chain each comprising an alkyl chain is trimethylolpropane triacrylate.

5. The transparent laminate according to claim 4 , wherein a content of the trimethylolpropane triacrylate in the composition of a (meth)acrylate-based polymerizable compound is less than 24.8% by mass.

6. The transparent laminate according to claim 1 , wherein the polyalkylene glycol di(meth)acrylate (C) contains polyethylene glycol diacrylate having more than 8 ethylene oxide (EO) chain repeating units.

7. The transparent laminate according to claim 1 , wherein a tensile elongation at break of the structure layer is 0.65% or more.

8. The transparent laminate according to claim 1 , for use as a face protective optical element.

Assignees

• Dexerials Corp

Inventors

• Kakinuma Masayasu
• Takenouchi Masaki
• Ohta Eiji
• Kawamura Satoshi
• Ogawa Maki

Classifications

• C08F2/46

  Polymerisation initiated by wave energy or particle radiation · CPC title

• B32B3/30 Primary

  characterised by a layer formed with recesses or projections, e.g. {hollows, grooves, protuberances, ribs (apertured layer B32B3/266; layer with cavities or internal voids B32B3/26)} · CPC title

• G02B1/111

  using layers comprising organic materials · CPC title

• A41D13/1184

  with protection for the eyes, e.g. using shield or visor · CPC title

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title