Heating element including nano-material filler

Patent metadata

Field	Value
Publication number	US-10652957-B2
Application number	US-201615374273-A
Country	US
Kind code	B2
Filing date	Dec 9, 2016
Priority date	Dec 9, 2015
Publication date	May 12, 2020
Grant date	May 12, 2020

Abstract

A heating element includes a matrix material and a nanomaterial filler, wherein the nanomaterial filler includes at least one of a nano-sheet and a nanorod.

First claim

What is claimed is:

1. A heating element comprising:
a matrix material; and
a nanomaterial filler,
wherein the heating element comprises a mixture of the nanomaterial filler and the matrix material, and
wherein the nanomaterial filler is an oxide, a boride, a carbide, a chalcogenide, or a combination thereof, and has a shape of at least one of a nanosheet and a nanorod.

2. The heating element of claim 1 , wherein the matrix material comprises at least one of a glass frit and an organic polymer.

3. The heating element of claim 2 , wherein the glass frit comprises at least one of silicon oxide, lithium oxide, nickel oxide, cobalt oxide, boron oxide, potassium oxide, aluminum oxide, titanium oxide, manganese oxide, copper oxide, zirconium oxide, phosphorus oxide, zinc oxide, bismuth oxide, lead oxide, and sodium oxide.

4. The heating element of claim 2 , wherein the glass frit comprises silicon oxide and at least one additive, wherein the additive comprises at least one of Li, Ni, Co, B, K, Al, Ti, Mn, Cu, Zr, P, Zn, Bi, Pb, and Na.

5. The heating element of claim 2 , wherein the organic polymer comprises at least one of a polyimide, polyphenylene sulfide, polybutylene terephthalate, polyamideimide, liquid crystalline polymer, polyethylene terephthalate, polyetherketone, and polyetheretherketone.

6. The heating element of claim 1 , wherein the nanomaterial filler has a thickness in a range from about 1 nanometer to about 1,000 nanometers.

7. The heating element of claim 1 , wherein the nanomaterial filler has a length in a range from about 0.1 micrometer to about 500 micrometers.

8. The heating element of claim 1 , wherein the content of the nanomaterial filler in the heating element is in a range from about 0.1 volume percent to less than 100 volume percent.

9. The heating element of claim 1 , wherein the nanomaterial filler has an electrical conductivity of at least about 1,250 Siemens per meter.

10. The heating element of claim 1 , wherein the heating element is in a form of a sheet having a two dimensional area.

11. The heating element of claim 1 , wherein the oxide comprises at least one of RuO 2 , MnO 2 , ReO 2 , VO 2 , OsO 2 , TaO 2 , IrO 2 , NbO 2 , WO 2 , GaO 2 , MoO 2 , InO 2 , CrO 2 , and RhO 2 .

12. The heating element of claim 1 , wherein the boride comprises at least one of Ta 3 B 4 , Nb 3 B 4 , TaB, NbB, V 3 B 4 , and VB.

13. The heating element of claim 1 , wherein the carbide comprises at least one of Dy 2 C and Ho 2 C.

14. The heating element of claim 1 , wherein the chalcogenide comprises at least one of AuTe 2 , PdTe 2 , PtTe 2 , YTe 3 , CuTe 2 , NiTe 2 , IrTe 2 , PrTe 3 , NdTe 3 , SmTe 3 , GdTe 3 , TbTe 3 , DyTe 3 , HoTe 3 , ErTe 3 , CeTe 3 , LaTe 3 , TiSe 2 , TiTe 2 , ZrTe 2 , HfTe 2 , TaSe 2 , TaTe 2 , TiS 2 , NbS 2 , TaS 2 , Hf 3 Te 2 , VSe 2 , VTe 2 , NbTe 2 , LaTe 2 , and CeTe 2 .

15. A method of manufacturing a heating element, the method comprising:
mixing a nanomaterial filler with a matrix material to form a mixture of the nanomaterial filler and the matrix material;
coating the mixture of the nanomaterial filler and the matrix material on a substrate to form a coating on the substrate; and
heat treating the coating on the substrate to provide the heating element,
wherein the nanomaterial filler comprises is an oxide, a boride, a carbide, a chalcogenide, or a combination thereof, and has a shape of at least one of a nano-sheet and a nano-rod, and
wherein, in the heating element, the heating element comprises a mixture of the nanomaterial filler and the matrix material.

16. The method of claim 15 , further comprising manufacturing the nanomaterial filler, wherein the manufacturing comprises:
forming a solution comprising a nanomaterial and a solvent;
calculating a concentration of the nanomaterial in the aqueous solution;
measuring a volume of the aqueous solution so that the aqueous solution includes a desired weight of the nanomaterial; and
separating nanomaterial from the measured nanomaterial aqueous solution to provide the nanomaterial filler.

17. The method of claim 15 , wherein the heat treating of the coating on the substrate comprises:
drying the coating on the substrate; and
sintering the dried resultant product.

18. The method of claim 15 , wherein the substrate has a composition that is the same as or different from a composition of the matrix material.

19. The method of claim 15 , wherein the substrate is a silicon wafer or a metal substrate.

20. The method of claim 15 , wherein the coating comprises at least one of a screen printing method, an ink jet method, a dip coating method, a spin coating method, and a spray coating method.

21. The method of claim 15 , wherein the nanomaterial has a thickness in a range from about 1 nanometer to about 1,000 nanometers.

22. The method of claim 15 , wherein a content of the nanomaterial is in a range from about 0.1 volume percent to less than about 100 volume percent of the heating element.

23. An apparatus comprising the heating element of claim 1 .

24. The apparatus of claim 23 , further comprising at least one of an adiabatic member and a thermal reflection member on a side of the heating element.

25. The apparatus of claim 23 , wherein the heating element is disposed to supply heat to a region inside the apparatus.

26. The apparatus of claim 23 , wherein the heating element is disposed to supply heat to a region on an outside of the apparatus.

27. The apparatus of claim 23 , wherein the apparatus is an oven having an inner space configured to receive a food.

28. The apparatus of claim 23 , wherein the heating element is in a form of a sheet heating element having a two dimensional area.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Kim Seyun
• Mizusaki Soichiro
• Koh Haengdeog
• Kim Doyoon
• Kim Hajin
• Lee Changsoo
• Han Intaek

Classifications

• H05B2203/032

  Heaters specially adapted for heating by radiation heating · CPC title

• C23D7/00

  Treating the coatings, e.g. drying before burning · CPC title

• H05B3/141 Primary

  Conductive ceramics, e.g. metal oxides, metal carbides, barium titanate, ferrites, zirconia, vitrous compounds · CPC title

• H05B3/262

  the insulating base being an insulated metal plate · CPC title

• H05B2214/04

  Heating means manufactured by using nanotechnology · CPC title