Proton conducting membrane comprising monolithic 2D material and ionomer, a process for preparing same and use of same in fuel cell and hydrogen gas sensor

Patent metadata

Field	Value
Publication number	US-10651490-B2
Application number	US-201515511560-A
Country	US
Kind code	B2
Filing date	Sep 15, 2015
Priority date	Sep 18, 2014
Publication date	May 12, 2020
Grant date	May 12, 2020

Abstract

The present invention relates to a graphene-based or other 2-D material membrane which allows the passage of protons and deuterons and to a method of facilitating proton or deuteron permeation through such a membrane. Monocrystalline membranes made from mono- and few-layers of graphene, hBN, molybdenum disulfide (MoS2), and tungsten disulfide (WS2) etc. are disclosed. In effect, the protons or deuterons are charge carriers that pass through the graphene or other 2-D material membrane. This process can be contrasted with the passage of gaseous hydrogen. Hydrogen is an uncharged gaseous species which is diatomic. In other words, the gas is in molecular form when considering the normal barrier properties whereas in the case of the present invention, the species which is being transported through the membrane is a charged ion comprising a single atom. Membranes of the invention find use in a number of applications such as fuel cells.

First claim

The invention claimed is:

1. A proton conducting membrane comprising: monolithic, continuous layer of a two-dimensional (2D) material formed from a single crystal, wherein the 2D material is selected from the group consisting of monolayer graphene and monolayer and bilayer hexagonal boron nitride (hBN); and
an ionomer coating provided on at least one side of the single piece of the 2D material; characterized in that said single piece of the 2D material has a discontinuous coating of a catalytic metal selected from Groups 8 to 10 of the periodic table.

2. The membrane as claimed in claim 1 , wherein the ionomer is a proton conducting polymer.

3. The membrane as claimed in claim 2 , wherein the polymer is a sulfonated polymer.

4. The membrane as claimed in claim 1 , wherein the ionomer is provided on one side of the 2D material, or alternatively, is provided on both sides of the 2D material.

5. The membrane as claimed in claim 1 , further including a substrate.

6. The membrane as claimed in claim 5 , wherein the ionomer and substrate are provided as a single entity.

7. The membrane as claimed in claim 1 , wherein the 2D material is monolayer graphene.

8. The membrane as claimed in claim 1 , wherein the 2D material is monolayer or bilayer hBN.

9. A method of separating protons from other materials, the method comprising:
allowing the protons to pass through the membrane of claim 1 .

10. The method of claim 9 , wherein a proton concentration gradient exists between different sides of the 2D material.

11. The method of claim 9 , wherein an electrical potential is applied across the membrane.

12. A process for preparing the proton-conducting membrane of claim 1 , said process comprising the following steps:
providing a monolithic, continuous layer of a two-dimensional (2D) material formed from a single crystal, wherein the 2D material is selected from the group consisting of monolayer graphene and monolayer and bilayer hBN; and
either coating an ionomer on at least one side of the 2D material so that one side of the ionomer is in contact with the 2D material and the other side is exposed, or applying a layer of material comprising an ionomer and a nonconductive structural component to one side of the 2D material;
characterized in that the process further comprises applying a discontinuous coating of a catalytic metal to the 2D material, wherein the catalytic metal is selected from Groups 8 to 10 of the periodic table.

13. The membrane of claim 3 , wherein the sulfonated polymer is Nafion®.

14. The membrane of claim 1 , further comprising a substrate.

15. The process of claim 12 , further comprising the step of providing a substrate in contact with an exposed side of the at least one ionomer coating.

Assignees

• Univ Manchester

Inventors

• Lozada Marcelo
• Geim Andre K

Classifications

• H01M8/1051

  Non-ion-conducting additives, e.g. stabilisers, SiO2 or ZrO2 · CPC title

• H01M8/1011

  Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC] · CPC title

• H01M4/881

  Electrolytic membranes · CPC title

• H01M8/1023

  having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes · CPC title

• H01M4/92

  Metals of platinum group (H01M4/94 {, H01M4/9058} take precedence) · CPC title