Light converting nanoparticle, method of making the light converting nanoparticle, and composition and optical film comprising the same

Patent metadata

Field	Value
Publication number	US-10649098-B2
Application number	US-201815882055-A
Country	US
Kind code	B2
Filing date	Jan 29, 2018
Priority date	Jan 29, 2018
Publication date	May 12, 2020
Grant date	May 12, 2020

Abstract

A light converting nanoparticle represented by Chemical Formula 1,

AX x   Chemical Formula 1

wherein, in Chemical Formula 1,
A comprises an alkaline metal element, an alkaline-earth metal element, or a combination thereof, X comprises a halogen element, and x is 1 or 2 and is selected such that Chemical Formula 1 is electrically neutral, and a dopant substituted for a portion of A, wherein the dopant comprises Tl + , In + , Pb 2+ , Bi 3+ , Ag + , Cu + , Eu 2+ , Mn 2+ , or a combination thereof, wherein a content of the dopant is less than 15 mole percent, based on a total moles of A, wherein the light converting nanoparticle has a particle diameter of less than or equal to about 100 nanometers, and the light converting nanoparticle has a structure, cubic structure, an orthorhombic structure, a rhombic dodecahedron structure, or a combination thereof.

First claim

What is claimed is:

1. A light converting nanoparticle comprising:
a compound represented by Chemical Formula 1,
AX x   Chemical Formula 1

wherein, in Chemical Formula 1,
A comprises an alkaline metal element or an alkaline-earth metal element,
X comprises a halogen element, and
x is 1 or 2 and is selected such that Chemical Formula 1 is electrically neutral, and
a dopant substituted for a portion of A, wherein the dopant comprises Tl + , In + , Pb 2+ , Ag + , Cu + , Eu 2+ , Mn 2+ , or a combination thereof,
wherein a content of the dopant is less than 15 mole percent, based on a total moles of A,
wherein the light converting nanoparticle has a particle diameter of less than or equal to about 100 nanometers, and
wherein the light converting nanoparticle has a cubic structure, an orthorhombic structure, a rhombic dodecahedron structure, or a combination thereof.

2. The light converting nanoparticle of claim 1 , wherein a bandgap energy of the light converting nanoparticle is greater than or equal to about 3.5 electron volts.

3. The light converting nanoparticle of claim 1 , wherein A and X each independently comprise a Period 3 element to a Period 6 element of the Periodic Table of the Elements, and
wherein a maximum difference between a value of the period of A and a value of the period of X is 1.

4. The light converting nanoparticle of claim 1 , wherein A comprises Rb, Cs, Sr, Ba, or a combination thereof, and X comprises Br, I, or a combination thereof.

5. The light converting nanoparticle of claim 1 , wherein the light converting nanoparticle has a particle diameter of about 20 nanometers to about 50 nanometers.

6. The light converting nanoparticle of claim 1 , wherein an amount of the dopant is about 0.05 mole percent to about 1 mole percent, based on a total moles of A.

7. The light converting nanoparticle of claim 1 , further comprising a ligand, which is attached to a surface of the light converting nanoparticle.

8. The light converting nanoparticle of claim 7 , wherein the ligand comprises a cationic organic surfactant, an anionic organic surfactant, or a combination thereof.

9. The light converting nanoparticle of claim 8 , wherein the ligand comprises oleic acid, octanoic acid, phosphonic acid, oleyl amine, octyl amine, or a combination thereof.

10. The light converting nanoparticle of claim 1 , wherein an absorption wavelength of the light converting nanoparticle is less than or equal to about 300 nanometers, and wherein an emission wavelength of the light converting nanoparticle is about 380 nanometers to about 780 nanometers.

11. The light converting nanoparticle of claim 9 , wherein a central emission wavelength of the light converting nanoparticle is about 500 nanometers to about 600 nanometers.

12. A composition for forming a light converting layer, the composition comprising the light converting nanoparticle of claim 1 .

13. An optical film comprising the light converting nanoparticle of claim 1 .

14. A method of making a light converting nanoparticle, the method comprising:
adding a first precursor solution comprising a halogen element into a reaction vessel;
adding a dopant comprising Tl + , In + , Pb 2+ , Ag + , Cu + , Eu 2+ , Mn 2+ , or a combination thereof to the reaction vessel;
heating the reaction vessel to a selected temperature; and
contacting the first precursor solution with a second precursor solution, the second precursor solution comprising an alkaline metal element, an alkaline-earth metal element, or a combination thereof to form the light converting nanoparticle,
wherein the light converting nanoparticle comprises a compound represented by Chemical Formula 1,
AX x   Chemical Formula 1

wherein, in Chemical Formula 1,
A comprises an alkaline metal element or an alkaline-earth metal element,
X comprises a halogen element,
x is 1 or 2 and is selected such that Chemical Formula 1 is electrically neutral, and
a dopant substituted for a portion of A, wherein the dopant comprises Tl + , In + , Pb 2+ , Ag + , Cu + , Eu 2+ , Mn 2+ , or a combination thereof,
wherein a content of the dopant is less than 15 mole percent, based on a total moles of A,
wherein the light converting nanoparticle has a particle diameter of less than or equal to about 100 nanometers, and
wherein the light converting nanoparticle comprises an orthorhombic structure, a cubic structure, a rhombic dodecahedron structure, or a combination thereof.

15. The method of claim 14 , which further comprises reacting the light converting nanoparticle with a ligand precursor to attach the ligand to a surface of the light converting nanoparticle.

16. The method of claim 14 , wherein the predetermined temperature is about 100° C. to about 400° C.

17. The method of claim 14 , further comprising maintaining a temperature of the reaction vessel for about 1 second to about 10 minutes after adding the first precursor solution into the reaction vessel.

18. The method of claim 14 , wherein an absorption wavelength of the light converting nanoparticle is less than or equal to about 300 nanometers and an emission wavelength of the light converting nanoparticle is about 380 nanometers to about 780 nanometers.

Assignees

• Samsung Electronics Co Ltd
• Univ California

Inventors

• Kim Kwanghee
• Bekenstein Yehonadav
• Kim Yong Chul
• Alivisatos Paul
• Han In Taek

Classifications

• C09K11/7435

  with alkali or alkaline earth metals · CPC title

• G01T1/2023 Primary

  Selection of materials · CPC title

• C09K11/665

  with alkali or alkaline earth metals · CPC title

• H01L27/14663

  Electricity · mapped topic

• H10F39/1898

  Indirect radiation image sensors, e.g. using luminescent members · CPC title