Hexavalent chromium treatment agent and leather or leather article produced using the same

Patent metadata

Field	Value
Publication number	US-10648048-B2
Application number	US-201716068698-A
Country	US
Kind code	B2
Filing date	Jan 27, 2017
Priority date	Jan 29, 2016
Publication date	May 12, 2020
Grant date	May 12, 2020

Abstract

Provided is a hexavalent chromium treatment agent capable of penetrating inside of a leather and capable of reducing not only hexavalent chromium present in the vicinity of the surface of the leather but also hexavalent chromium present inside the leather into trivalent chromium. The hexavalent chromium treatment agent of the present invention comprises a hexavalent chromium-reducing compound capable of reducing hexavalent chromium into trivalent chromium, a nonionic surfactant, and an aqueous solvent. The hexavalent chromium-reducing compound preferably comprises an organic compound (A) that has a specific structure capable of acting to reduce hexavalent chromium into trivalent chromium, that has a hydroxyphenyl group, and that has no aldehyde groups and no carboxyl groups.

First claim

The invention claimed is:

1. A hexavalent chromium treatment agent comprising a hexavalent chromium-reducing compound capable of reducing hexavalent chromium into trivalent chromium, a nonionic surfactant, and an aqueous solvent,
wherein the hexavalent chromium-reducing compound comprises:
at least one selected from a compound (A-i) represented by the following formula (A-i) and a tannin (A-ii), and
at least one selected from a compound (B-i) represented by the following formula (B-i) and a compound (B-ii) represented by the following formula (B-ii),

wherein
n represents 0, 1, or 2,
R 11 to R 18 each independently represent a hydrogen atom, a hydroxy group, a C 1 to C 4 alkyl group, a C 1 to C 4 alkoxy group, or a group represented by the following formula (a-i),
when n is 0, at least one of R 11 to R 14 , R 16 , and R 17 is a hydroxy group,
when n is 1 or 2, at least one of R 11 to R 18 is a hydroxy group,
when n is 2, a plurality of R 15 may be the same or different, and a plurality of R 18 may be the same or different,
R 16 and R 17 may be linked together to form a five-membered ring or a six-membered ring, and the ring may have a C 1 to C 16 alkyl group as a substituent,

wherein R 19 represents a C 1 to C 4 alkyl group,

wherein X represents a group represented by any one of the following formulas (b-i) to (b-iii),

wherein o represents an integer of 0 to 3, p represents an integer of 1 to 3, and q represents an integer of 1 to 17.

2. The hexavalent chromium treatment agent according to claim 1 , wherein the nonionic surfactant is an ether surfactant and/or an amine oxide surfactant.

3. The hexavalent chromium treatment agent according to claim 1 , wherein the hexavalent chromium treatment agent contains the hexavalent chromium-reducing compound in an amount of 0.01 to 10.0% by mass and the nonionic surfactant in an amount of 0.01 to 1.0% by mass.

4. A leather or leather article comprising a hexavalent chromium-reducing compound capable of reducing hexavalent chromium into trivalent chromium, and a nonionic surfactant,
wherein the hexavalent chromium-reducing compound comprises:
an organic compound (A) that has a structure represented by the following formula (1) and capable of acting to reduce hexavalent chromium into trivalent chromium, that has a hydroxyphenyl group, and that has no aldehyde groups and no carboxyl groups, and
an organic compound (B) that has a structure represented by the following formula (1) and capable of acting to reduce hexavalent chromium into trivalent chromium and that has no hydroxyphenyl groups, no aldehyde groups, and no carboxyl groups,

wherein R 1 , R 2 , R 3 , R 4 , and R 5 are each independently a substituent composed of C, H, O, and R 1 or R 2 and R 3 , R 4 , or R 5 may be linked together to form a ring.

5. A method for producing a leather or leather article, comprising treating a leather or leather article with a hexavalent chromium treatment agent comprising a hexavalent chromium-reducing compound capable of reducing hexavalent chromium into trivalent chromium, a nonionic surfactant, and an aqueous solvent,
wherein the hexavalent chromium-reducing compound comprises:
an organic compound (A) that has a structure represented by the following formula (1) and capable of acting to reduce hexavalent chromium into trivalent chromium, that has a hydroxyphenyl group, and that has no aldehyde groups and no carboxyl groups, and
an organic compound (B) that has a structure represented by the following formula (1) and capable of acting to reduce hexavalent chromium into trivalent chromium and that has no hydroxyphenyl groups, no aldehyde groups, and no carboxyl groups,

wherein R 1 , R 2 , R 3 , R 4 , and R 5 are each independently a substituent composed of C, H, O, and R 1 or R 2 and R 3 , R 4 , or R 5 may be linked together to form a ring.

Assignees

• Citizen Watch Co Ltd

Inventors

• Akao Yuji

Classifications

• C14C3/06

  using chromium compounds · CPC title

• C11D3/0031

  Carpet, upholstery, fur or leather cleansers · CPC title

• C14C3/08 Primary

  by organic agents · CPC title

• C11D3/2058

  aromatic · CPC title

• C11D1/75

  Amino oxides · CPC title