Prepreg and method for producing same

Patent metadata

Field	Value
Publication number	US-10647828-B2
Application number	US-201314425543-A
Country	US
Kind code	B2
Filing date	Sep 5, 2013
Priority date	Sep 6, 2012
Publication date	May 12, 2020
Grant date	May 12, 2020

Abstract

This prepreg comprises reinforcing fibers and a matrix resin composition. The matrix resin composition comprises at least an epoxy resin (component (A)), a radical polymerizable unsaturated compound (component (B)), and a polymer formed by radical polymerization of the component (B) (component (E)).

First claim

The invention claimed is:

1. A prepreg, comprising reinforcing fibers and a matrix resin composition, wherein the matrix resin composition comprises:
component (A): an epoxy resin;
component (B): a radical polymerizable unsaturated compound;
component (C): an epoxy resin curing agent; and
component (E): a polymer formed by radical polymerization of the component (B),
wherein:
the prepreg is in a sheet form or a tape form;
the prepreg has, on at least one surface of the prepreg, plural regions having mutually different reaction ratios of the matrix resin composition;
the plural regions comprise at least one region having a high reaction ratio of the matrix resin composition and where a lower tackiness exists compared to a region having a relatively low reaction ratio of the matrix resin composition;
the at least one region having the high reaction ratio of the matrix resin composition and the lower tackiness exists in a surface layer portion of the prepreg; and
the component (E) is localized in the surface layer portion of the prepreg but not in a core of the prepreg, where the core of the prepreg is a portion deeper than 40% of a thickness of the prepreg from a surface of the prepreg relative to 100% of the thickness of the prepreg.

2. The prepreg according to claim 1 , wherein the component (B) is a (meth)acrylate resin.

3. A method for producing the prepreg according to claim 1 , the method comprising:
producing a prepreg precursor by impregnating a reinforcing fiber substrate comprising the reinforcing fibers with a resin composition for impregnation including the component (A), the component (B), and the component (C); and
irradiating a portion of at least one surface of the prepreg precursor with at least one energy wave selected from the group consisting of ultraviolet radiation, infrared radiation, visible light and electron beam to thereby cause a portion of the component (B) to react, and thereby producing the component (E) at the surface of the prepreg precursor.

4. The prepreg according to claim 1 , wherein the matrix resin composition further comprises:
component (D): a polymerization initiator that generates a radical, and wherein, in at least one surface of the prepreg, a tack value measured at a pressing pressure of 40 kPa is 70 kPa or less, while a tack value measured at a pressing pressure of 80 kPa is 150 kPa or more.

5. The prepreg according to claim 4 , wherein, when a sum of contents of the component (A), the component (B), and the component (E) is 100 parts by mass, a sum of contents of the component (B) and the component (E) is 10 parts by mass to 25 parts by mass.

6. The prepreg according to claim 4 , wherein the reinforcing fibers are in the form of a reinforcing fiber sheet obtained by gathering and arranging reinforcing fiber bundles.

7. The prepeg of claim 4 , wherein the reinforcing fibers are carbon fibers.

8. The prepreg according to claim 1 , wherein:
a protective film is laminated on at least one surface of the prepreg; and
an index of tackiness of the prepreg is 50 g or more.

9. The prepreg according to claim 1 , wherein the reinforcing fibers are carbon fibers.

Assignees

• Mitsubishi Chem Corp

Inventors

• Teranishi Takuya
• Kaneko Manabu
• Ichino Masahiro
• Miura Teppei
• Samejima Tadao
• Miyauchi Akira
• Numata Kiharu
• Mori Shouhei
• KUSUMI Masaki

Classifications

• B32B2260/021

  Fibrous or filamentary layer · CPC title

• C08J2463/10

  Epoxy resins modified by unsaturated compounds · CPC title

• B32B2250/20

  All layers being fibrous or filamentary · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• B32B2305/076

  Prepregs · CPC title