Methods of catalyst activation

Patent metadata

Field	Value
Publication number	US-10647796-B2
Application number	US-201916270699-A
Country	US
Kind code	B2
Filing date	Feb 8, 2019
Priority date	Nov 17, 2008
Publication date	May 12, 2020
Grant date	May 12, 2020

Abstract

A method comprising preparing a multi-component catalyst system comprising a catalyst and a cocatalyst, and adjusting the level of at least one component of the catalyst system to maintain a user-desired level of catalyst activity throughout a process, wherein the component comprises a catalyst activator and wherein the catalyst activator comprises the catalyst or the cocatalyst. A method comprising contacting a polymerization catalyst system comprising a Ziegler-Natta catalyst and a cocatalyst with a catalyst activator at least twice during a polymerization process, wherein the polymerization process is carried out in a reactor system comprising multiple reactor types.

First claim

What is claimed is:

1. A method comprising:
preparing a multi-component catalyst system comprising a catalyst and a cocatalyst; and
adjusting a level of a plurality of components of the multi-component catalyst system to maintain a user-desired level of catalyst activity throughout a polymerization process;
wherein at least one component of the plurality of components comprises a catalyst activator, wherein the catalyst activator is the cocatalyst, wherein an amount of the cocatalyst introduced to a reaction zone is reduced as compared to an amount of the cocatalyst normally present in the polymerization process and an amount of catalyst introduced to the reaction zone is increased compared to an amount of the catalyst normally present in the polymerization process, wherein the amount of increase in the catalyst is between 10% and 25% and the amount of reduction in the cocatalyst is between 20% and 40%.

2. The method of claim 1 , wherein the catalyst activator functions to maintain the catalyst system activity to a user-desired threshold level throughout the polymerization process.

3. The method of claim 1 , wherein the multi-component catalyst system further comprises an electron donor.

4. The method of claim 1 , wherein the multi-component catalyst comprises a metallocene catalyst.

5. The method of claim 1 , wherein the cocatalyst comprises an organoaluminum compound.

6. The method of claim 5 , wherein the organoaluminum compound comprises triethylaluminum, tri-isobutylaluminum, diethylaluminum chloride, diethylaluminum hydride, methylalumoxane, tri-isobutylaluminum, or combinations thereof.

7. The method of claim 1 , wherein the multi-component catalyst system functions as a polymerization catalyst.

Assignees

• Fina Technology

Inventors

• Blackmon Kenneth P
• Ribour David
• Malbari Shabbir
• Coffy Tim
• Daumerie Michel

Classifications

• C08F210/06 Primary

  Propene · CPC title

• C08F10/00

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C08F4/6465

  containing silicium · CPC title

• C08F4/642

  Component covered by group C08F4/64 with an organo-aluminium compound {(C08F4/64003 - C08F4/64196 take precedence)} · CPC title

• C08F2500/12

  Melt flow index or melt flow ratio · CPC title