Process for producing cumene and/or ethylbenzene from a mixed hydrocarbon feedstream

Patent metadata

Field	Value
Publication number	US-10647632-B2
Application number	US-201615740125-A
Country	US
Kind code	B2
Filing date	Jun 23, 2016
Priority date	Jun 29, 2015
Publication date	May 12, 2020
Grant date	May 12, 2020

Abstract

A process for producing cumene and/or ethylbenzene from a mixed hydrocarbon feedstream comprising subjecting C6 cut separated from said mixed hydrocarbon feedstream to aromatization to provide an aromatization product stream and subjecting the thus obtained aromatization product stream to alkylation to produce an alkylated aromatic stream.

First claim

The invention claimed is:

1. A process for producing alkylated aromatics comprising:
(a) subjecting a mixed hydrocarbon feedstream to a separation to provide a C6 cut, wherein the C6 cut comprises iso-hexane;
b) subjecting the C6 cut to aromatization to provide an aromatization product stream comprising 25-85 wt-% hexane; and
(c) subjecting the aromatization product stream comprising 25-85 wt-% hexane to alkylation to produce an alkylated aromatic stream.

2. The process according to claim 1 , wherein the separation of the mixed hydrocarbon feedstream to provide a C6 cut involves distillation under distillation conditions and wherein the distillation conditions are suitable to provide a C6 cut having a boiling point range of 45-90° C.

3. The process according to claim 1 , wherein the aromatization comprises contacting the C6 cut with an aromatization catalyst under aromatization conditions.

4. The process according to claim 3 , wherein the aromatization catalyst is a non-acidic zeolite comprising Ge as a framework element.

5. The process according to claim 3 , wherein the aromatization catalyst is non-acidic by base-exchange and/or wherein the aromatization catalyst further comprises a hydrogenation metal.

6. The process according to claim 3 , wherein the aromatization conditions comprise a temperature of 400-600° C., a pressure of 50-1000 kPa gauge, and a Weight Hourly Space Velocity of 0.1-20 h −1 .

7. The process according to claim 1 , wherein the alkylation comprises contacting the aromatization product stream in the presence of ethylene with an alkylation catalyst under alkylation conditions to produce ethylbenzene, wherein said alkylation catalyst comprises beta zeolite, zeolite Y, ZSM-12, MCM-22, ZSM-5 and mordenite and wherein said alkylation conditions comprise a temperature of 120-250° C., a pressure of 1000-5000 kPa, a Weight Hourly Space Velocity of 0.5-20 h −1 , and a benzenelethylene molar ratio of 1-8.

8. The process according to claim 1 , wherein the alkylation comprises contacting the aromatization product stream in the presence of propylene with an alkylation catalyst under alkylation conditions to produce cumene, wherein said alkylation catalyst comprises a zeolite selected from the group consisting of beta zeolite, zeolite Y, ZSM-12, MCM-22, ZSM-5 and mordenite and wherein said alkylation conditions comprise a temperature of 120-250° C., a pressure of 1000-5000 kPa, a Weight Hourly Space Velocity of 0.5-20 h −1 , and a benzene/propylene molar ratio of 1-8.

9. The process according to claim 1 , wherein the mixed hydrocarbon feedstream comprises reformate.

10. The process according to claim 7 , wherein said alkylation conditions comprise a temperature of 150-230° C., a pressure of 2500-3500 kPa, a Weight Hourly Space Velocity of 1-10 h −1 and a benzene/ethylene molar ratio of 1-4.

11. The process according to claim 8 , wherein said alkylation conditions comprise a temperature of 150-230° C., a pressure of 2500-3500 kPa, a Weight Hourly Space Velocity of 1-10 h −1 , and a benzene/propylene molar ratio of 1-4.

12. The process according to claim 1 , wherein the C6 cut comprises 34-56 wt-% iso-hexane, based on a total weight of the C6 cut.

13. The process according to claim 1 , wherein the aromatization product stream comprises 30-85 wt-% hexane.

14. The process according to claim 1 , wherein the aromatization product stream comprises 50-60 wt-% hexane.

Assignees

• Sabic Global Technologies Bv

Inventors

• Okolo Christian

Classifications

• C10G45/70

  with catalysts containing platinum group metals or compounds thereof · CPC title

• C07C2529/70

  of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 · CPC title

• C07C2529/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 · CPC title

• C07C2/66 Primary

  Catalytic processes · CPC title

• C07C2529/44

  Noble metals · CPC title