Carbon nanotube pellets and method for manufacturing same

Patent metadata

Field	Value
Publication number	US-10647579-B2
Application number	US-201615746945-A
Country	US
Kind code	B2
Filing date	Oct 17, 2016
Priority date	Jan 20, 2016
Publication date	May 12, 2020
Grant date	May 12, 2020

Abstract

The method for producing carbon nanotube pellets according to the present invention can reduce the particle size of the carbon nanotubes contained in the pellet by a repetitive extrusion process to produce pellets having improved dispersion characteristics in a solvent. The present invention can improve the problems of the change of the content generated by scattering of powders and safety issues by using carbon nanotubes in the form of pellet. And since the density of the pellet form is higher than that of the powder form, transport, transfer and improvement become easier. Therefore, it can be more effectively applied to the manufacturing of composite materials.

First claim

What is claimed is:

1. A method for producing carbon nanotube pellets comprising the steps of:
mixing carbon nanotubes and a solvent to form a first carbon nanotube mixture;
extruding the first carbon nanotube mixture into first pellets;
mixing the first pellets with the solvent to form a second carbon nanotube mixture; and
extruding the second carbon nanotube mixture into second pellets.

2. The method for producing carbon nanotube pellets according to claim 1 , wherein a particle size of the carbon nanotubes contained in the pellets is decreased in proportion to the number of times of extrusion.

3. The method for producing carbon nanotube pellets according to claim 2 , wherein a decreasing ratio of D90 of the carbon nanotubes according the number of times of extrusion satisfies the following Expression 2:
−167.3 x+ 650 ≤y≤− 167.3 x+ 670  [Expression 2]

wherein x is the number of times of extrusion of the carbon nanotubes, and y is D90 in μm of the carbon nanotubes.

4. The method for producing carbon nanotube pellets according to claim 1 , wherein the method comprises the steps of:
premixing the carbon nanotubes and the solvent;
mixing the premixed solution of carbon nanotubes in a screw mixer; and
transferring the mixed solution of carbon nanotubes from the screw mixer to an extruder and extruding the mixture into pellets.

5. The method for producing carbon nanotube pellets according to claim 4 , wherein the method further comprises the steps of:
mixing carbon nanotubes and a solvent to prepare a first premixture as a first step;
adding additional predetermined solvent to the first premixture to prepare a second premixture as a second step; and
adding a solvent to the second premixture to prepare a premixed solution.

6. The method for producing carbon nanotube pellets according to claim 5 , wherein the time to complete the first step and the second step is 2 hours or less, respectively.

7. The method for producing carbon nanotube pellets according to claim 5 , wherein an average particle size of the carbon nanotubes after the first step is 20 μm or less.

8. The method for producing carbon nanotube pellets according to claim 4 , wherein D90 of the carbon nanotubes contained in the carbon nanotube pellets produced by the method is 50 μm or less.

9. The method for producing carbon nanotube pellets according to claim 1 , wherein the solvent is at least one selected from the group consisting of water, alcohols, ketones, amides, esters, ethers, aromatic hydrocarbons such as benzene or toluene, and aliphatic hydrocarbons.

10. The method for producing carbon nanotube pellets of claim 9 , wherein the solvent is hexane or heptane.

Assignees

• Lg Chemical Ltd

Inventors

• Kang Kyung Yeon
• Woo Jihee
• Lee Seungyong
• Jang Hyungsik
• Cho Dong Hyun

Classifications

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01B32/168 Primary

  After-treatment · CPC title

• C01B32/174 Primary

  Derivatisation; Solubilisation; Dispersion in solvents · CPC title

• B30B11/22

  Extrusion presses; Dies therefor (extruding by the use of roller-and-ring machines B30B11/20) · CPC title

• C01P2002/30

  Three-dimensional structures · CPC title