Process for manufacturing a purified aqueous hydrogen peroxide solution

Patent metadata

Field	Value
Publication number	US-10647576-B2
Application number	US-201816024078-A
Country	US
Kind code	B2
Filing date	Jun 29, 2018
Priority date	Oct 2, 2013
Publication date	May 12, 2020
Grant date	May 12, 2020

Abstract

A process includes preparing a crude aqueous hydrogen peroxide solution by auto-oxidation of at least one alkylanthraquinone in a working solution that includes at least one organic solvent and the at least one alkylanthraquinone; and washing the crude aqueous hydrogen peroxide solution with a mixture of at least one organic solvent and an organophosphorous chelating agent to create a purified aqueous hydrogen peroxide solution having less than 100 ppb Cr; wherein the organic solvent used for the washing is not part of the working solution and is not recycled into it.

First claim

The invention claimed is:

1. A process, comprising:
preparing a crude aqueous hydrogen peroxide solution by auto-oxidation of at least one alkylanthraquinone in a working solution comprising at least one organic solvent and the at least one alkylanthraquinone;
washing the crude aqueous hydrogen peroxide solution with a mixture of at least one organic solvent and an organophosphorous chelating agent to create a purified aqueous hydrogen peroxide solution having less than 100 ppb Cr; and
reacting the purified aqueous hydrogen peroxide solution with propylene,
wherein the organic solvent used for the washing is not part of the working solution and is not recycled into it.

2. The process of claim 1 , wherein the crude aqueous hydrogen peroxide is washed as least two times with the mixture to create a purified aqueous hydrogen peroxide solution having less than 100 ppb Cr.

3. The process of claim 1 , wherein the at least one organic solvent is an organophosphorus compound different from the organophosphorus chelating agent.

4. The process of claim 1 , wherein the organophosphorus chelating agent is di-(2-ethylhexyl) phosphoric acid and the organic solvent is selected from the group consisting of trioctylphosphate, triethylhexylphosphate, dibutyl phosphoric acid, tributyl phosphate, trialkylphosphine oxides, and mixtures thereof.

5. A process for manufacturing propylene oxide (1,2-epoxypropane), comprising:
reacting propylene with hydrogen peroxide;
wherein the hydrogen peroxide is in an aqueous solution and is obtained by the auto-oxidation of at least one alkylanthraquinone, and
wherein the hydrogen peroxide solution contains less than 100 ppb of Cr.

6. The process of claim 5 , wherein the solution further contains one or more of:
Al in an amount of less than 100 ppb, and
Fe in an amount of less than 100 ppb.

7. The process of claim 6 , wherein the solution contains the one or more of Al and Fe in an amount of the range of the ppb.

8. The process of claim 6 , wherein the solution contains below a ppb of the one or more of Al and Fe.

9. The process of claim 5 , wherein the solution contains Cr in the range of the ppb.

10. The process of claim 5 , wherein the solution contains below a ppb of Cr.

11. A process for manufacturing propylene oxide (1,2-epoxypropane), comprising:
reacting propylene with hydrogen peroxide;
wherein the hydrogen peroxide is in an aqueous solution and is obtained by the auto-oxidation of at least one alkylanthraquinone, and
wherein the hydrogen peroxide solution contains less than 100 ppb of Al, less than 100 ppb of Fe, or less than 100 ppb of Al and less than 100 ppb of Fe.

12. The process of claim 11 , wherein the solution contains Al, Fe, or Al and Fe in the range of the ppb.

13. The process of claim 11 , wherein the solution contains below a ppb of Al, Fe, or Al and Fe.

14. The process of claim 11 , wherein the solution further contains Cr in an amount of less than 100 ppb.

15. The process of claim 11 , wherein the solution further contains Cr in an amount of the range of the ppb.

16. The process of claim 11 , wherein the solution further contains Cr in an amount below a ppb.

17. A process, comprising:
preparing a crude aqueous hydrogen peroxide solution by auto-oxidation of at least one alkylanthraquinone in a working solution comprising at least one organic solvent and the at least one alkylanthraquinone; and
washing the crude aqueous hydrogen peroxide solution with a mixture of at least one organic solvent and an organophosphorous chelating agent to create a purified aqueous hydrogen peroxide solution having less than 100 ppb Cr;
wherein the organic solvent used for the washing is not part of the working solution and is not recycled into it, and
wherein the organophosphorus chelating agent is di-(2-ethylhexyl) phosphoric acid and the organic solvent is selected from the group consisting of trioctylphosphate, triethylhexylphosphate, dibutyl phosphoric acid, tributyl phosphate, trialkylphosphine oxides, and mixtures thereof.

18. The process of claim 17 , wherein the crude aqueous hydrogen peroxide is washed as least two times with the mixture to create a purified aqueous hydrogen peroxide solution having less than 100 ppb Cr.

Assignees

• Solvay

Inventors

• Carlier Juan-Teva
• Dournel Pierre
• Venbrux Henk
• Lieven Hooghe

Classifications

• C07D303/04

  containing only hydrogen and carbon atoms in addition to the ring oxygen atoms · CPC title

• C01B15/013 Primary

  Separation; Purification; Concentration · CPC title

• C07D303/02

  Compounds containing oxirane rings · CPC title