Cleaning compositions comprising alkoxylated esteramines

Patent metadata

Field	Value
Publication number	US-10640736-B2
Application number	US-201816028453-A
Country	US
Kind code	B2
Filing date	Jul 6, 2018
Priority date	Jul 7, 2017
Publication date	May 5, 2020
Grant date	May 5, 2020

Abstract

Cleaning compositions that include alkoxylated esteramines. Related methods of preparation and use.

First claim

What is claimed is:

1. A cleaning composition comprising:
from about 1% to about 70%, by weight of the composition, of a surfactant system, and
from about 0.1% to about 10% of an esteramine according to Formula (I) and/or a salt thereof,

wherein independently from each other
n being an integer from 0 to 12,
m being an integer for each repetition unit n independently selected from 0 to 12;
p being an integer from 0 to 12,
o being an integer for each repetition unit p independently selected from 0 to 12;
r being an integer from 0 to 12,
q being an integer for each repetition unit r independently selected from 0 to 12;
s being an integer from 0 to 100;
t being an integer from 1 to 100;
u being an integer from 0 to 100;
v being an integer from 0 to 100;
with the sum of s, t, u, and v being equal to or greater than 1;
A 1 , A 2 , A 3 , and A 4 are independently from each other and independently for each repetition units, t, u, or v, selected from the list consisting of ethyleneoxy group, propyleneoxy group, 1,2-butyleneoxy group, 2,3-butyleneoxy group, i-butyleneoxy group, pentyleneoxy group, hexyleneoxy group, styryloxy group, decenyloxy group, dodecenyloxy group, tetradecenyloxy group, and hexadecanyloxy group, wherein when s, t, u, and/or v equal to or greater than 1, the oxygen atom of the first A 1 , A 2 , A 3 , and A 4 group is bound to the B group and the subsequent A 1 , A 2 , A 3 , and A 4 groups, when they exist, are bound via an oxygen atom to the previous A 1 , A 2 , A 3 , and A 4 group;
B 1 , B 2 , B 3 , and B 4 are independently from each other selected from the group consisting of a bond, linear C 1 to C 12 alkanediyl groups, and branched C 1 to C 12 alkanediyl groups;
R 4 , R 8 , and R 12 being selected from the group consisting of H, linear alkyl, branched alkyl, and cycloalkyl;
R 1 , R 2 , and R 3 being independently for each repetition unit o of each repetition unit p being selected from the group consisting of H, linear alkyl, branched alkyl, and cycloalkyl;
R 5 , R 6 , and R 7 being independently for each repetition unit m of each repetition unit n being selected from the group consisting of H, linear alkyl, branched alkyl, and cycloalkyl;
R 9 , R 10 , and R 11 being independently for each repetition unit q of each repetition unit r being selected from the group consisting of H, linear alkyl, branched alkyl, and cycloalkyl;
Z 1 , Z 2 , Z 3 , and/or Z 4 , if present, being independently selected from the group consisting of —OH, alanine, arginine, asparagine, aspartic acid, cysteine, glutamine, glycine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, proline, serine, threonine, tryptophan, tyrosine, valine, and a compound according to Formula (II),
wherein said compound according to Formula (II) connects to the compound according to Formula (I) via the bond labeled with *,

with independently from each other
w being an integer from 0 to 12;
R 13 and R 14 independently for each repetition unit w being selected from the group consisting of H, linear alkyl, branched alkyl, and cycloalkyl;
R 15 , R 16 , R 17 , and Rig being selected from the group consisting of H, linear alkyl, branched alkyl, and cycloalkyl,
with the proviso that at least one of Z 1 , Z 2 , Z 3 , and/or Z 4 is present and is not —OH.

2. A cleaning composition according to claim 1 , wherein
n, p, and r are each equal to zero, and
Z 1 is selected from the group consisting of alanine, arginine, asparagine, aspartic acid, cysteine, glutamine, glycine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, proline, serine, threonine, tryptophan, tyrosine, valine, and a compound according to Formula (II),
wherein said compound according to Formula (II) connects to the compound according to Formula (I) via the bond labeled with *, with the proviso of at least one group R 4 , R 8 , and/or R 12 containing at least 7 or more carbon atoms;

with independently from each other
w being an integer from 0 to 12;
R 13 and R 14 independently for each repetition unit w being selected from the group consisting of H, linear alkyl, branched alkyl, and cycloalkyl;
R 15 , R 16 , R 17 , and Rig being selected from the group consisting of H, linear alkyl, branched alkyl, and cycloalkyl.

3. A cleaning composition according to claim 1 , wherein
p and r are both equal to 0,
n is at least 1, and
Z 1 and Z 2 , are independently selected from the group consisting of OH, alanine, arginine, asparagine, aspartic acid, cysteine, glutamine, glycine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, proline, serine, threonine, tryptophan, tyrosine, valine, and a compound according to Formula (II),

with independently from each other
w being an integer from 0 to 12;
R 13 and R 14 independently for each repetition unit w being selected from the group consisting of H, linear alkyl, branched alkyl, and cycloalkyl;
R 15 , R 16 , R 17 , and Rig being selected from the group consisting of H, linear alkyl, branched alkyl, and cycloalkyl,
wherein said compound according to Formula (II) connects to the compound according to Formula (I) via the bond labeled with *, with the proviso that at least one substituent Z 1 and/or Z 2 is not OH, and with the proviso that R 3 contains equal to or more than 2 carbon atoms.

4. A cleaning composition according to claim 1 , wherein
n and p are individually equal to or greater than 1,
r is equal to or greater than 0, and
Z 1 , and/or Z 2 , and/or Z 3 , and/or Z 4 , independently for each repetition unit n, p, and r, are selected from the group consisting of OH, alanine, arginine, asparagine, aspartic acid, cysteine, glutamine, glycine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, proline, serine, threonine, tryptophan, tyrosine, valine, and a compound according to Formula (II),

with independently from each other
w being an integer from 0 to 12;
R 13 and R 14 independently for each repetition unit w being selected from the group consisting of H, linear alkyl, branched alkyl, and cycloalkyl;
R 15 , R 16 , R 17 , and Rig being selected from the group consisting of H, linear alkyl, branched alkyl, and cycloalkyl,
wherein said compound according to Formula (II) connects to the compound according to Formula (I) via the bond labeled with *, with the proviso that at least one substituent Z 1 , and/or Z 2 , and/or Z 3 , and/or Z 4 , is not OH, and

wherein if n and p equal to 1 and r equal to 0 at least one unit A 1 , A 2 , or A 3 is selected from the group consisting of propyleneoxy group, 1,2-butyleneoxy group, 2,3-butyleneoxy group, i-butyleneoxy group, pentyleneoxy group, hexyleneoxy group, styryloxy group, decenyloxy group, dodecenyloxy group, tetradecenyloxy group, and hexadecanyloxy group.

5. A cleaning composition according to claim 1 , wherein the composition comprises a salt of the esteramine according to claim

Assignees

• Procter & Gamble

Inventors

• Scialla Stefano
• Jackson Michelle
• Ludolph Bjoern
• Ebert Sophia Rosa
• Bittner Christian
• Hulskotter Frank

Classifications

• C07C229/08

  the nitrogen atom of the amino group being further bound to hydrogen atoms · CPC title

• C11D3/3409

  Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates · CPC title

• C11D3/30 Primary

  Amines; Substituted amines {; Quaternized amines} · CPC title

• C11D11/0017

  Chemistry & Metallurgy · mapped topic

• C11D3/33 Primary

  Amino carboxylic acids · CPC title