Ethoxylated amines for use in subterranean formations

Patent metadata

Field	Value
Publication number	US-10640698-B2
Application number	US-201515765166-A
Country	US
Kind code	B2
Filing date	Nov 16, 2015
Priority date	Nov 16, 2015
Publication date	May 5, 2020
Grant date	May 5, 2020

Abstract

Methods for treating subterranean formations are provided. In one embodiment, the methods comprise providing a treatment fluid comprising an aqueous base fluid and a surfactant comprising an ethoxylated amine or derivative thereof; introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation; and producing fluids from the wellbore during or subsequent to introducing the treatment fluid into the wellbore.

First claim

What is claimed is:

1. A method comprising:
providing a treatment fluid comprising:
an aqueous base fluid;
a first surfactant comprising an ethoxylated amine or derivative thereof;
a second surfactant comprising an ethoxylated alcohol or a salt of an ethoxylated alcohol;
a third surfactant selected from the group consisting of an alkoxylated alkyl alcohol, an alkoxylated alkyl alcohol salt, an alkyl sulfonate, an aryl sulfonate, a sulfate, a phosphate, a carboxylate, a polyoxyalkyl glycol, a polyoxyethylene glycol sorbitan alkyl ester, a sorbitan alkyl ester, a polysorbate, a glucoside, a quaternary amine compound, and any combination thereof; and
a solvent comprising glycerine and acetone;

introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation; and
producing fluids from the wellbore during or subsequent to introducing the treatment fluid into the wellbore.

2. The method of claim 1 , wherein the ethoxylated amine or derivative thereof inhibits corrosion in at least a portion of the subterranean formation.

3. The method of claim 1 , wherein the first surfactant is present in the treatment fluid in an amount from about 1×10 −5 gpt up to about 50 gpt based on the total volume of the treatment fluid.

4. The method of claim 1 , wherein the treatment fluid further comprises an additional surfactant.

5. The method of claim 1 , wherein the treatment fluid further comprises an additional solvent.

6. The method of claim 5 , wherein the additional solvent is selected from the group consisting of: a non-aqueous solvent, a non-aromatic solvent, an alcohol, glycerol, carbon dioxide, isopropanol, any combination, and any derivative thereof.

7. The method of claim 1 , wherein the subterranean formation comprises an unconventional reservoir.

8. The method of claim 1 , further comprising:
allowing at least one of the surfactants to reduce capillary pressure in at least a portion of the subterranean formation.

9. The method of claim 1 , wherein the amount of fluids produced from the wellbore during or subsequent to introducing the treatment fluid comprising the surfactants is greater than the amount of fluids that would be produced during or subsequent to introducing the same treatment fluid without the surfactants.

10. The method of claim 1 , further comprising:
allowing at least one of the surfactants to alter a wettability of a surface of the formation.

11. The method of claim 1 , further comprising:
allowing at least one of the surfactants to reduce interfacial tension between a fluid in the formation and a surface of the formation.

12. The method of claim 1 , further comprising:
allowing at least one of the surfactants to remove at least a portion of an oil block, a water block, or both.

13. A method comprising:
providing a treatment fluid comprising:
an aqueous base fluid;
a first surfactant comprising an ethoxylated amine or derivative thereof;
a second surfactant comprising an ethoxylated alcohol or a salt of an ethoxylated alcohol;
a third surfactant selected from the group consisting of an alkoxylated alkyl alcohol, an alkoxylated alkyl alcohol salt, an alkyl sulfonate, an aryl sulfonate, a sulfate, a phosphate, a carboxylate, a polyoxyalkyl glycol, a polyoxyethylene glycol sorbitan alkyl ester, a sorbitan alkyl ester, a polysorbate, a glucoside, a quaternary amine compound, and any combination thereof; and
a solvent comprising glycerine and acetone;

introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation at or above a pressure sufficient to create or enhance one or more fractures in the subterranean formation.

14. The method of claim 13 , further comprising:
producing fluids from the wellbore.

15. The method of claim 13 , further comprising:
allowing at least one of the surfactants to reduce capillary pressure in at least a portion of the subterranean formation.

16. The method of claim 13 , further comprising:
allowing at least one of the surfactants to remove at least a portion of an oil block, a water block, or both.

17. The method of claim 13 , wherein the subterranean formation comprises an unconventional reservoir.

18. A method comprising:
providing a treatment fluid comprising:
an aqueous base fluid;
a first surfactant comprising an ethoxylated amine or derivative thereof;
a second surfactant comprising an ethoxylated alcohol or a salt of an ethoxylated alcohol;
a third surfactant selected from the group consisting of an alkoxylated alkyl alcohol, an alkoxylated alkyl alcohol salt, an alkyl sulfonate, an aryl sulfonate, a sulfate, a phosphate, a carboxylate, a polyoxyalkyl glycol, a polyoxyethylene glycol sorbitan alkyl ester, a sorbitan alkyl ester, a polysorbate, a glucoside, a quaternary amine compound, and any combination thereof; and
a solvent comprising glycerine and acetone;

introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation comprising an unconventional reservoir; and
producing fluids from the wellbore during or subsequent to introducing the treatment fluid into the wellbore, wherein the amount of fluids produced from the wellbore during or subsequent to introducing the treatment fluid comprising the surfactant is greater than the amount of fluids that would be produced during or subsequent to introducing the same treatment fluid without the surfactant.

19. The method of claim 18 , further comprising:
allowing at least one of the surfactants to remove at least a portion of an oil block, a water block, or both.

Assignees

• Halliburton Energy Services Inc
• Multi Chem Group Llc

Inventors

• Peng Yang
• Yue Zhiwei
• He Kai
• Rane Jayant
• Xu Liang

Classifications

• C09K2208/32

  Anticorrosion additives · CPC title

• C09K8/604

  Polymeric surfactants · CPC title

• C09K8/584 Primary

  characterised by the use of specific surfactants · CPC title

• C09K8/68 Primary

  containing organic compounds · CPC title

• C09K8/60

  Compositions for stimulating production by acting on the underground formation · CPC title