Lithographic printing plate precursor, method of producing same, lithographic printing plate precursor laminate, plate-making method for lithographic printing plate, and lithographic printing method

Patent metadata

Field	Value
Publication number	US-10639924-B2
Application number	US-201916371121-A
Country	US
Kind code	B2
Filing date	Apr 1, 2019
Priority date	Mar 31, 2017
Publication date	May 5, 2020
Grant date	May 5, 2020

Abstract

A lithographic printing plate precursor including a hydrophilized aluminum support, and a water-soluble or water-dispersible negative type image recording layer provided on the aluminum support, in which an arithmetic average height Sa of a surface of an outermost layer on a side where the image recording layer is provided is in a range of 0.3 μm to 20 μm; a method of producing a lithographic printing plate precursor; a lithographic printing plate precursor laminate formed of the lithographic printing plate precursor; a plate-making method for a lithographic printing plate; and a lithographic printing method.

First claim

What is claimed is:

1. A lithographic printing plate precursor comprising:
a hydrophilized aluminum support; and
a water-soluble or water-dispersible negative type image recording layer provided on the aluminum support,
wherein an arithmetic average height Sa of a surface of an outermost layer on a side where the image recording layer is provided is in a range of 0.3 μm to 20 μm,
the image recording layer contains a polymer compound having a particle shape,
the polymer compound having a particle shape has a hydrophobic main chain and both of (i) constitutional unit which contains a pendant-cyano group directly bonded to the hydrophobic main chain and (ii) constitutional unit which contains a pendant group having a hydrophilic polyalkylene oxide segment;
the aluminum support includes an aluminum plate and an aluminum anodized film disposed on the aluminum plate,
the anodized film is positioned closer to the image recording layer side than to the aluminum plate,
the anodized film has micropores extending in a depth direction from the surface of the image recording layer side, and
the average diameter of the micropores in the surface of the anodized film is in a range of 7 nm to 150 nm.

2. The lithographic printing plate precursor according to claim 1 ,
wherein the image recording layer contains an infrared absorbing agent, a polymerization initiator, a polymerizable compound, and the polymer compound having a particle shape.

3. The lithographic printing plate precursor according to claim 1 , further comprising:
a protective layer on the image recording layer.

4. The lithographic printing plate precursor according to claim 1 ,
wherein the image recording layer contains at least one kind of particles having an average particle diameter of 0.5 μm to 20 μm and two or more kinds of particles having different average particle diameters.

5. The lithographic printing plate precursor according to claim 3 ,
wherein the protective layer contains at least one kind of particles having an average particle diameter of 0.5 pin to 20 μm.

6. The lithographic printing plate precursor according to claim 4 ,
wherein an in-plane density of the particles having an average particle diameter of 0.5 μm to 20 μm is 10000 pcs/mm 2 or less.

7. The lithographic printing plate precursor according to claim 4 ,
wherein the particles having an average particle diameter of 0.5 μm to 20 μm are at least one kind of particles selected from the group consisting of organic resin particles and inorganic particles.

8. The lithographic printing plate precursor according to claim 2 ,
wherein the image recording layer is an outermost layer and has a plurality of protrusions containing, as a main component, a polymer compound on the image recording layer.

9. The lithographic printing plate precursor according to claim 3 ,
wherein the protective layer is an outermost layer and has a plurality of protrusions containing, as a main component, a polymer compound on the protective layer.

10. The lithographic printing plate precursor according to claim 8 ,
wherein the polymer compound constituting the protrusions contains at least one selected from the group consisting of a phenol formaldehyde resin, an m-cresol formaldehyde resin, a p-cresol formaldehyde resin, an m-/p-mixed cresol formaldehyde resin, or a phenol/cresol-mixed formaldehyde resin, a resol resin, pyrogallol, an acetone resin, an epoxy resin, a saturated copolymer polyester resin, a phenoxy resin, a polyvinyl acetal resin, a vinylidene chloride copolymer resin, polybutene, polybutadiene, polyamide, an unsaturated copolymer polyester resin, polyurethane, polyurea, polyimide, polysiloxane, polycarbonate, chlorinated polyethylene, an aldehyde condensation resin of alkyl phenol, polyvinyl chloride, polyvinylidene chloride, polystyrene, polyacrylate, a carboxyvinyl polymer, an acrylic resin copolymer resin, hydroxy cellulose, hydroxymethyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone, cellulose acetate, methyl cellulose, and carboxymethyl cellulose.

11. The lithographic printing plate precursor according to claim 1 ,
wherein an arithmetic average height Sa of a surface of an outermost layer on a side opposite to the side where the image recording layer is provided is in a range of 0.1 μm to 20 μm.

12. The lithographic printing plate precursor according to claim 1 ,
wherein a total value of the arithmetic average height Sa of the surface of the outermost layer on the side where the image recording layer is provided and the arithmetic average height Sa of the surface of the outermost layer on a side opposite to the side where the image recording layer is provided is greater than 0.3 μm and 20 μm or less.

13. The lithographic printing plate precursor according to claim 1 , which satisfies Expression (1) and Expression (2) in a case where a Bekk smoothness of the surface of the outermost layer on the side where the image recording layer is provided is set as a seconds and a Bekk smoothness of a surface of an outermost layer on a side opposite to the side where the image recording layer is provided is set as b seconds
a≤ 1000, b≤ 1000  (1)

1/ a+ 1/ b≥ 0.002  (2).

14. The lithographic printing plate precursor according to claim 11 ,
wherein a back coat layer which contains particles having an average particle diameter of 0.1 μm to 20 μm is provided, as the outermost layer, on the side opposite to the side where the image recording layer is provided.

15. The lithographic printing plate precursor according to claim 11 ,
wherein the surface of the outermost layer on the side opposite to the side where the image recording layer is provided has a plurality of protrusions.

16. The lithographic printing plate precursor according to claim 15 , which includes at least one layer between the protrusions, provided on the side opposite to the side where the image recording layer is provided, and the aluminum support.

17. The lithographic printing plate precursor according to claim 1 ,
wherein the average diameter of the micropores in the surface of the anodized film is in a range of 10 nm to 100 nm.

18. The lithographic printing plate precursor according to claim 1 ,
wherein the micropores are formed of large-diameter pores extending to a position at a depth of 10 nm to 1000 nm from the surface of the anodized film and small-diameter pores communicating with a bottom of the large-diameter pores and extending to a position at a depth of 20 nm to 2000 nm from a communication position,
the average diameter of the large-diameter pores in the surface of the anodized film is in a range of 15 to 150 nm, and
the average diameter of the small-diameter pores in the communication position is 13 nm or less.

19. A method of producing the lithographic printing plate precursor according to claim 1 , comprising:
a step of forming the image recording layer on the aluminum support after one or more days from an anodization treatment performed thereon.

20. A plate-making method for a lithographic printing plate, comprising:
a step of image-exposing the lithographic printing plate precursor according to claim 1 ; and
a step of supplying at least any of printing ink or dampening water and removing an unexposed portion of an image recording layer on a printing press to prepare a lithographic printing plate.

21. A plate-making method for a lithographic printing plate, comprising:
a step of image-exposing the lithographic printing plate precursor according to claim

Assignees

• Fujifilm Corp

Inventors

• Watanabe Shumpei
• Ikeyama yusuke
• Oshima Atsushi
• Shimanaka Shuji

Classifications

• B41C2210/20

  characterised by inorganic additives, e.g. pigments, salts · CPC title

• G03F7/004

  Photosensitive materials (G03F7/12, G03F7/14 take precedence) · CPC title

• B41N1/083

  made of aluminium or aluminium alloys or having such surface layers (B41N1/086 takes precedence) · CPC title

• B41C2210/06

  Developable by an alkaline solution · CPC title

• B41C2201/10

  characterised by inorganic compounds, e.g. pigments · CPC title