Alkylation catalyst

Patent metadata

Field	Value
Publication number	US-10639619-B2
Application number	US-201816018202-A
Country	US
Kind code	B2
Filing date	Jun 26, 2018
Priority date	Jul 19, 2017
Publication date	May 5, 2020
Grant date	May 5, 2020

Abstract

Catalyst compositions with improved alkylation activity and corresponding methods for making such catalyst compositions are provided. The catalyst(s) correspond to solid acid catalysts formed by exposing a catalyst precursor with a zeolitic framework structure to a molten metal salt that includes fluorine, such as a molten metal fluoride. The resulting fluorinated solid acid catalysts can have improved alkylation activity while having a reduced or minimized amount of structural change due to the exposure to the molten metal fluoride. This is in contrast to fluorinated solid acid catalysts that are exposed to higher severity forms of fluorination, such as exposure to ammonium fluoride or HF. SnF2 is an example of a suitable molten metal fluoride.

First claim

The invention claimed is:

1. A catalyst composition comprising an MWW framework structure, tin and fluorine, wherein the catalyst comprises 0.1 wt % to 2.5 wt % fluorine relative to a weight of the catalyst composition, and a weight ratio of Sn to F in the catalyst composition of 0.1 to 2.0.

2. The catalyst composition of claim 1 , wherein the catalyst composition comprises MCM-49, MCM-22, MCM-56, or a combination thereof.

3. The catalyst composition of claim 1 , wherein the MWW framework structure comprises a silicon to aluminum ratio of 2 to 100.

4. The catalyst composition of claim 1 , wherein at least one of the MWW framework structure and the catalyst composition comprises 2.5 wt % or less Sn.

5. The catalyst composition of claim 1 , wherein the catalyst composition further comprises a binder.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Nandi Partha
• Ide Matthew S
• Dakka Jihad M
• Nizami Quddus A
• Afeworki Mobae

Classifications

• B01J37/0009

  Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• C07C2/12

  with crystalline alumino-silicates {or with catalysts comprising} molecular sieves · CPC title

• C10G29/205

  by reaction with hydrocarbons added to the hydrocarbon oil · CPC title

• C10G29/12

  Halides · CPC title