Separation membrane

Patent metadata

Field	Value
Publication number	US-10639595-B2
Application number	US-201615563315-A
Country	US
Kind code	B2
Filing date	Mar 31, 2016
Priority date	Mar 31, 2015
Publication date	May 5, 2020
Grant date	May 5, 2020

Abstract

A problem to be solved by the present invention is to provide a separation membrane having excellent separation performance, having high membrane strength and high permeation performance, and mainly including a cellulose-based resin. The present invention is concerned with a separation membrane including a cellulose ester, having, in the interior thereof, voids each having a specified structure, and having a tensile elasticity of 1,000 to 6,500 MPa.

First claim

The invention claimed is:

1. A separation membrane comprising at least a first layer, wherein
the first layer comprises, as a main component thereof, at least one compound selected from the group consisting of a cellulose ester, a polyamide, and a polyester,
the first layer has, in an interior thereof, a plurality of voids each having a depth (D 1 ) of 10 nm or more and 500 nm or less, a length (L 1 ) of 30 nm or more, and a ratio L 1 /D 1 of the length to the depth in a range of 4 or more, and
the separation membrane has a tensile elasticity of 1,800 to 6,500 MPa.

2. The separation membrane according to claim 1 , wherein a lengthwise direction of the void follows a lengthwise direction of the separation membrane.

3. The separation membrane according to claim 1 , wherein, when a projected area of a cross-section of the separation membrane is defined as S 10 , and an occupation area of the voids is defined as S 1 , an occupancy rate of the voids in the cross-section, expressed by {(S 1 /S 10 )×100}, is 0.5% or more and 30% or less.

4. The separation membrane according to claim 1 , having, on at least one surface thereof, a plurality of grooves each having a length (L 2 ) of 30 nm or more, a width (W 2 ) of 5 nm or more and 500 nm or less, and a ratio L 2 /W 2 of the length to the width in a range of 2 or more.

5. The separation membrane according to claim 4 , wherein a lengthwise direction of the grooves follow a lengthwise direction of the separation membrane.

6. The separation membrane according to claim 1 , further comprising a second layer that has a rate of hole area which is different from an occupancy rate of the voids of the first layer.

7. The separation membrane according to claim 6 , wherein a lengthwise direction of the voids follow a lengthwise direction of the separation membrane in the first layer.

8. The separation membrane according to claim 6 , wherein, when a projected area of a cross-section of the separation membrane is defined as S 10 , and an occupation area of the voids is defined as S 1 , an occupancy rate of the voids in the cross-section, as expressed by {(S 1 /S 10 )×100}, is 0.5% or more and 30% or less in the first layer.

9. The separation membrane according to claim 6 , having, on at least one surface of the first layer thereof, a plurality of grooves each having a length (L 2 ) of 30 nm or more, a width (W 2 ) of 5 nm or more and 500 nm or less, and a ratio L 2 /W 2 of the length to the width in a range of 2 or more.

10. The separation membrane according to claim 9 , wherein a lengthwise direction of the grooves follow a lengthwise direction of the separation membrane in the first layer.

11. The separation membrane according to claim 9 , wherein, when a projected area of a surface of the separation membrane is defined as S 20 , and an occupation area of the grooves is defined as S 2 , an occupancy rate of the grooves in the surface, as expressed by {(S 2 /S 20 )×100}, is 0.5% or more and 20% or less in the first layer.

12. The separation membrane according to claim 6 , wherein an occupancy rate V A of voids in a cross-section of the first layer and a rate of hole area H B of the second layer satisfy a relation: V A <H B ; and wherein the rate of hole area H B corresponds to (average pore area m 2 )×(fine pore density per m 2 )×100.

13. The separation membrane according to claim 1 , wherein the separation membrane has a shape of a hollow fiber.

14. The separation membrane according to claim 13 , wherein the hollow fiber has an outer diameter of 20 μm to 400 μm.

15. The separation membrane according to claim 1 , wherein
the separation membrane comprises, as the main component thereof, the cellulose ester, and
the separation membrane comprises, as the cellulose ester, at least one of cellulose acetate propionate and cellulose acetate butyrate.

16. The separation membrane according to claim 1 , wherein the separation membrane is at least one selected from the group consisting of a nanofiltration membrane, a reverse osmosis membrane, a forward osmosis membrane, and a gas separation membrane.

17. A membrane module comprising the separation membrane according to claim 1 .

Assignees

• Toray Industries

Inventors

• Takada Koichi
• Yamamura Gohei
• Hiranabe Ryuichiro
• Tomioka Hiroki

Classifications

• B01D69/02 Primary

  characterised by their properties · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• B01D69/08

  Hollow fibre membranes (manufacture of hollow fibres D01D5/24, D01F1/08) · CPC title

• B01D71/56

  Polyamides, e.g. polyester-amides · CPC title

• B01D71/18 Primary

  Mixed esters, e.g. cellulose acetate-butyrate · CPC title