Shielding formulations using discrete carbon nanotubes with targeted oxidation levels and formulations thereof

Patent metadata

Field	Value
Publication number	US-10638649-B2
Application number	US-201816157457-A
Country	US
Kind code	B2
Filing date	Oct 11, 2018
Priority date	Oct 11, 2017
Publication date	Apr 28, 2020
Grant date	Apr 28, 2020

Abstract

Discrete, individualized carbon nanotubes having targeted, or selective, oxidation levels and/or content on the interior and exterior of the tube walls are claimed. Such carbon nanotubes can have little to no inner tube surface oxidation, or differing amounts and/or types of oxidation between the tubes' inner and outer surfaces. These new discrete carbon nanotubes are useful in electromagnetic and radio frequency shielding applications, especially where the shielding is essentially constant over a relatively wide range of frequencies. Additives such as plasticizers, can be used in compounding and formulation of elastomeric, thermoplastic and thermoset composite for improvement of mechanical, electrical and thermal properties.

First claim

We claim:

1. An electromagnetic shielding composition comprising a plurality of discrete carbon nanotubes and at least one magnetic metal and/or alloy thereof, wherein the discrete carbon nanotubes comprise an interior and exterior surface, the interior surface comprising an interior surface oxidized species content and the exterior surface comprising an exterior surface oxidized species content, wherein the interior surface oxidized species content differs from the exterior surface oxidized species content by at least 20%, and as high as 100% wherein the composition further comprises (1) at least one rubber; or (2) at least one thermoplastic polymer, at least one thermoplastic elastomer, or combinations thereof; or (3) at least one thermoset polymer selected from the group consisting of an epoxy, a polyurethane, and combinations thereof.

2. The electromagnetic shielding composition of claim 1 , wherein the interior surface oxidized species content comprises from about 0.01 to less than about 0.8 percent relative to carbon nanotube weight and the exterior surface oxidized species content comprises more than about 1.2 to about 3 percent relative to carbon nanotube weight.

3. The electromagnetic shielding composition of claim 1 , wherein the magnetic metal and/or alloy thereof is selected from the group consisting of iron, chromium, aluminum, uranium, platinum, copper, cobalt, lithium, nickel, neodymium, and samarium.

4. The electromagnetic shielding composition of claim 1 , wherein the magnetic metal and/or alloy thereof comprises a metal and/or alloy oxide.

5. The composition of claim 1 , wherein the plurality of discrete carbon nanotubes comprises a plurality of open ended tubes.

6. The composition of claim 1 , wherein the interior surface oxidized species content is less than the exterior surface oxidized species content.

7. The composition of claim 1 , wherein the interior surface oxidized species content is up to 3 weight percent relative to carbon nanotube weight.

8. The composition of claim 1 , wherein the exterior surface oxidized species content is from about 1 to about 6 weight percent relative to carbon nanotube weight.

9. The composition of claim 1 , wherein the interior and exterior surface oxidized species content totals from about 1 to about 9 weight percent relative to carbon nanotube weight.

10. The composition of claim 1 , wherein the oxidized species is selected from the group consisting of carboxylic acids, phenols, aldehydes, ketones, ether linkages, and combinations thereof.

11. The composition of claim 1 , wherein the total oxidized species content of the interior surface and exterior surface comprises from about 1% to 15% by weight of the carbon nanotubes.

12. The composition of claim 1 , in the form of free flowing particles.

13. The composition of claim 1 , wherein the composition comprises at least one rubber.

14. The composition of claim 1 , wherein the composition comprises at least one thermoplastic polymer, at least one thermoplastic elastomer, or combinations thereof.

15. The composition of claim 1 , wherein the composition comprises at least one thermoset polymer selected from the group consisting of an epoxy, a polyurethane, and combinations thereof.

16. The composition of claim 1 , wherein the at least one magnetic metal and/or alloy thereof is bound or attached to the plurality of discrete carbon nanotubes.

17. The composition of claim 1 , wherein the plurality of discrete carbon nanotubes comprise multi-wall carbon nanotubes.

Assignees

• Molecular Rebar Design Llc

Inventors

• Bosnyak Clive P
• Swogger Kurt W

Classifications

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• C08K9/02

  Ingredients treated with inorganic substances · CPC title

• B82Y25/00

  Nanomagnetism, e.g. magnetoimpedance, anisotropic magnetoresistance, giant magnetoresistance or tunneling magnetoresistance · CPC title

• C08K5/12

  of cyclic polycarboxylic acids · CPC title

• C08K9/04

  Ingredients treated with organic substances {(treated with macromolecular compounds C08K9/08)} · CPC title