Flow battery with carbon paper

Patent metadata

Field	Value
Publication number	US-10637082-B2
Application number	US-201114364685-A
Country	US
Kind code	B2
Filing date	Dec 20, 2011
Priority date	Dec 20, 2011
Publication date	Apr 28, 2020
Grant date	Apr 28, 2020

Abstract

A flow battery includes a liquid electrolyte having an electrochemically active specie. A flow field plate includes a first flow field channel and a second flow field channel that is separated from the first flow field channel by a rib. There is a flow path for the liquid electrolyte to flow over the rib between the channels. An electrode is arranged adjacent the flow field plate such that the liquid electrolyte that flows over the rib must flow through the electrode. The electrode includes a carbon paper that is catalytically active with regard to liquid electrolyte. The carbon paper defines a compressive strain of less than 20% at a compressive stress of 0.8 MPa and an uncompressed porosity in the range 60-85%.

First claim

What is claimed is:

1. A redox flow battery comprising:
a liquid electrolyte including an electrochemically active specie;
a flow field plate defining flow field channels and ribs that separate the flow field channels;
an ion exchange membrane; and
an electrode sandwiched between the flow field plate and the ion exchange membrane, there being flow paths of the liquid electrolyte over the ribs between the flow field channels such that the liquid electrolyte that flows over the ribs must flow through the electrode, the electrode including a carbon paper that bridges over the flow field channels from the ribs, wherein the carbon paper has oxides that serve as active catalytic sites that are catalytically active with regard to the electrochemically active specie and defines a compressive strain of less than 20% at a compressive stress of 0.8 MPa, to provide a stiffness that reduces intrusion into the flow field channels, and an uncompressed porosity in the range 60-85%.

2. The redox flow battery as recited in claim 1 , wherein the carbon paper comprises carbon fibers and carbon binder residue and has a uniform porosity through the thickness.

3. The redox flow battery as recited in claim 1 , wherein the carbon paper comprises carbon fibers and carbon binder residue and has a graded porosity through the thickness.

4. The redox flow battery as recited in claim 3 , wherein the carbon paper has a maximum porosity at the side near the flow field plate.

5. The redox flow battery as recited in claim 1 , wherein the carbon paper has a thickness of 150-400 micrometers.

6. The redox flow battery as recited in claim 1 , wherein the electrochemically active specie is based on vanadium, bromine, iron, chromium, zinc, cerium, lead or combinations thereof.

7. The flow battery as recited in claim 6 , wherein the electrochemically active specie is based on vanadium.

8. The redox flow battery as recited in claim 1 , wherein the carbon paper has a thickness of 150-400 micrometers.

9. The redox flow battery as recited in claim 8 , wherein the carbon paper includes carbon fibers and carbon binder residue and carbon particles disposed on the carbon fibers.

10. The redox flow battery as recited in claim 9 , wherein the carbon paper includes 1-10 wt % of the carbon particles.

11. The redox flow battery as recited in claim 9 , wherein the carbon particles have an average diameter of 10-100 nanometers.

12. The redox flow battery as recited in claim 9 , wherein the carbon particles have a multi-modal size distribution.

13. The redox flow battery as recited in claim 8 , wherein the thickness is 150-250 micrometers.

14. A redox flow battery comprising:
a liquid electrolyte including an electrochemically active specie is based on vanadium, bromine, iron, chromium, zinc, cerium, lead or combinations thereof;
a flow field plate having a broad side and flow field channels with open channel tops at the broad side, the flow field channels being separated from each other by ribs;
an ion exchange membrane;
a carbon paper electrode between the flow field plate and the ion exchange membrane, the carbon paper electrode bridging from the ribs over the open channel tops, wherein the carbon paper electrode is catalytically active in electrochemically reversible redox reactions with regard to the electrochemically active specie and has an uncompressed porosity in the range 60-85%, wherein the carbon paper electrode has a compressive strain of less than 20% at a compressive stress of 0.8 MPa.

15. The redox flow battery as recited in claim 14 , wherein the carbon paper electrode has a thickness of 150-400 micrometers.

16. The redox flow battery as recited in claim 15 , wherein the carbon paper electrode includes carbon fibers, carbon binder residue, and carbon particles disposed on the carbon fibers, the carbon paper includes 1-10 wt % of the carbon particles, and the carbon particles have an average diameter of 10-100 nanometers.

17. The redox flow battery as recited in claim 16 , wherein the carbon particles have a multi-modal size distribution.

Assignees

• Darling Robert Mason
• Stolar Laura Roen
• United Technologies Corp

Inventors

• Darling Robert Mason
• Stolar Laura Roen

Classifications

• H01M8/20

  Indirect fuel cells, e.g. fuel cells with redox couple being irreversible (H01M8/18 takes precedence) · CPC title

• H01M4/861

  with a gradient in the porosity · CPC title

• H01M8/188 Primary

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M8/04186 Primary

  of liquid-charged or electrolyte-charged reactants · CPC title

• H01M4/8605

  Porous electrodes · CPC title