Positive electrode for metal-air battery and metal-air battery including the same

Patent metadata

Field	Value
Publication number	US-10637073-B2
Application number	US-201715651406-A
Country	US
Kind code	B2
Filing date	Jul 17, 2017
Priority date	Sep 27, 2016
Publication date	Apr 28, 2020
Grant date	Apr 28, 2020

Abstract

A positive electrode for a metal-air battery, the positive electrode including: a first layer disposed on a surface of an electrolyte membrane or a separator and including a first carbon material, a first electrolyte, and a first binder having an affinity with the first electrolyte; and a second layer disposed on the first layer and including a second carbon material, a second electrolyte, and a second binder having an affinity with the second electrolyte, wherein the first carbon material is different from the second carbon material, the first carbon material has a Brunauer Emmett Teller specific surface area which is greater than a Brunauer Emmett Teller specific surface area of the second carbon material, and wherein an amount of the first binder may be about 1.5 times to about 3 times greater than an amount of the second binder.

First claim

What is claimed is:

1. A positive electrode for a metal-air battery, the positive electrode comprising:
a first layer disposed on a surface of an electrolyte membrane or a separator and comprising a first carbon material, a first electrolyte, and a first binder having an affinity with the first electrolyte; and
a second layer disposed on the first layer and comprising a second carbon material, a second electrolyte, and a second binder having an affinity with the second electrolyte,
wherein the first carbon material has a Brunauer Emmett Teller specific surface area of about 800 square meters per gram to about 1500 square meters per gram,
wherein the first carbon material is different from the second carbon material, the first carbon material has a Brunauer Emmett Teller specific surface area which is greater than a Brunauer Emmett Teller specific surface area of the second carbon material, and
wherein an amount of the first binder is about 1.5 times to about 3 times greater than an amount of the second binder.

2. The positive electrode of claim 1 , wherein the first layer has a thickness which is less than a thickness of the second layer.

3. The positive electrode of claim 1 , wherein a thickness of the first layer is about 1 percent to about 20 percent of a total thickness of the positive electrode.

4. The positive electrode of claim 3 , wherein the total thickness of the positive electrode is from about 10 micrometers to about 100 micrometers.

5. The positive electrode of claim 1 , wherein the first carbon material comprises activated carbon, mesoporous carbon, graphene, or a combination thereof.

6. The positive electrode of claim 1 , wherein the first carbon material has porosity of about 40 percent to about 80 percent.

7. The positive electrode of claim 1 , wherein the second carbon material has a Brunauer Emmett Teller specific surface area of about 200 square meters per gram to less than about 800 square meters per gram.

8. The positive electrode of claim 1 , wherein the second carbon material comprises carbon nanotubes, carbon nanofibers, carbon nanoribbons, carbon nanobelts, carbon nanorods, or a combination thereof.

9. The positive electrode of claim 1 , wherein the second carbon material has porosity of about 30 percent to about 60 percent.

10. The positive electrode of claim 1 , wherein at least one of the first electrolyte and the second electrolyte comprises an ionic liquid.

11. The positive electrode of claim 10 , wherein the ionic liquid comprises
a cation comprising an ammonium-containing cation, a pyrrolidinium-containing cation, a pyridinium-containing cation, a pyrimidinium-containing cation, an imidazolium-containing cation, a piperidinium-containing cation, a pyrazolium-containing cation, an oxazolium-containing cation, a pyridazinium-containing cation, a phosphonium-containing cation, a sulfonium-containing cation, a triazole-containing cation, or a combination thereof; and
an anion comprising BF 4 − , PF 6 − , AsF 6 − , SbF 6 − , AlCl 4 − , HSO 4 − , ClO 4 − , Cl − , Br − , I − , SO 4 − , CF 3 SO 3 − , CF 3 CO 2 − , (C 2 F 5 SO 2 )(CF 3 SO 2 )N—, NO 3 − , Al 2 Cl 7 − , CH 3 COO − , CH 3 SO 3 − , CF 3 SO 3 − , (CF 3 SO 2 ) 3 C − , (CF 3 CF 2 SO 2 ) 2 N − , (CF 3 SO 2 ) 2 N − , (FSO 2 ) 2 N − , (CF 3 ) 2 PF 4 − , (CF 3 ) 3 PF 3 − , (CF 3 ) 4 PF 2 − , (CF 3 ) 5 PF − , (CF 3 ) 6 P − , SF 5 CF 2 SO 3 − , SF 5 CHFCF 2 SO 3 − , CF 3 CF 2 (CF 3 ) 2 CO − , (CF 3 SO 2 ) 2 CH − , (SF 5 ) 3 C − , (O(CF 3 ) 2 C 2 (CF 3 ) 2 O) 2 PO − , or a combination thereof.

12. The positive electrode of claim 10 , wherein the ionic liquid comprises a compounds comprising a N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium cation and an anion comprising (C 2 F 5 SO 2 )(CF 3 SO 2 )N − , (CF 3 CF 2 SO 2 ) 2 N − , (CF 3 SO 2 ) 2 N − , (FSO 2 ) 2 N − , or a combination thereof.

13. The positive electrode of claim 1 , wherein each of the first binder and the second binder is a hydrophobic binder.

14. The positive electrode of claim 1 , wherein each of the first binder and the second binder independently comprises polytetrafluoroethylene, a tetrafluoroethylene-hexafluoropropylene copolymer, a tetrafluoroethylene-perfluoroalkylvinylether copolymer, ethylene/tetrafluoroethylene, an ethylenechlorotrifluoro-ethylene copolymer, polyvinylidene fluoride, a polyvinylidenefluoride-hexafluoropropylene copolymer, or a combination thereof.

15. The positive electrode of claim 1 , wherein a total amount of the first binder and the second binder is from about 10 weight percent to about 80 weight percent, based on a total weight of the first carbon material and the second carbon material.

16. A metal-air battery comprising:
a negative electrode comprising Li or a Li alloy;
the positive electrode according to claim 1 ; and
a separator between the negative electrode and the positive electrode.

17. The metal-air battery of claim 16 , wherein the separator comprises a coating layer comprising a lithium ion conductive polymer, a lithium ion conductive inorganic material, or a combination thereof.

18. The metal-air battery of claim 17 , wherein the lithium ion conductive polymer comprises an ionic liquid polymer.

19. The metal-air battery of claim 18 , wherein the ionic liquid polymer comprises a polymer represented by Formula 1 below:

wherein, in Formula 1,

 represents a 3 to 31-membered ring containing at least one heteroatom and 2 to 30 carbon atoms;
X is —N(R 2 )(R 3 )—, —N(R 2 ) 2 —, —P(R 2 ) 2 —, or —P(R 2 )(R 3 )—;
each of R 1 to R 4 is independently hydrogen, a substituted or unsubstituted C 1 -C 30 alkyl group, a substituted or unsubstituted C 1 -C 30 alkoxy group, a substituted or unsubstituted C 6 -C 30 aryl group, a substituted or unsubstituted C 6 -C 30 aryloxy group, a substituted or unsubstituted C 3 -C 30 heteroaryl group, a substituted or unsubstituted C 3 -C 30 heteroaryloxy group, a substituted or unsubstituted C 4 -C 30 cycloalkyl group, a substituted or unsubstituted C 3 -C 30 heterocycloalkyl group, or a substituted or unsubstituted C 2 -C 100 alkylene oxide group;
Y − is an anion;
each of a and b is independently an integer of 1 to 5; and
n is an integer of 500 to 2800.

20. The metal-air battery of claim 17 , wherein the lithium ion conductive inorganic material comprises a lithium ion conductive glass-ceramic.

21. The metal-air battery of claim 17 , wherein the coating layer has a thickness of about 0.01 micrometer to about 50 micrometers.

22. The metal-air battery of claim 16 , wherein the metal-air battery is foldable.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Park Jungock
• Kim Mokwon
• Kim Joonhee
• Choi Kyounghwan

Classifications

• H01M12/08

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M4/96 Primary

  Carbon-based electrodes · CPC title

• H01M2004/8689

  Positive electrodes · CPC title

• H01M4/8657 Primary

  layered · CPC title

• H01M4/405

  Alloys based on lithium · CPC title