Positive active material for rechargeable lithium battery and rechargeable lithium battery including the same

Patent metadata

Field	Value
Publication number	US-10637047-B2
Application number	US-201715722953-A
Country	US
Kind code	B2
Filing date	Oct 2, 2017
Priority date	Oct 6, 2016
Publication date	Apr 28, 2020
Grant date	Apr 28, 2020

Abstract

A positive active material for a rechargeable lithium battery and a rechargeable lithium battery including the same are provided. The positive active material includes a lithium intercalation compound and a Si-containing TiO2 present on the surface of the compound. When TiO2 is present on the surface of the lithium intercalation compound, the rate characteristics and low temperature characteristics of batteries including the lithium intercalation compound may be improved. Further, when Si-containing TiO2 is present on the surface of the lithium intercalation compound, the cycle-life characteristic and high temperature storage characteristics of batteries including the lithium intercalation compound may be further improved, compared to batteries having only TiO2. As such, the positive active material including Si-containing TiO2 provides a rechargeable lithium battery having excellent rate capability, low temperature characteristics, cycle-life characteristics and high temperature storage characteristics.

First claim

What is claimed is:

1. A positive active material for a rechargeable lithium battery, the positive active material comprising:
a lithium intercalation compound, and
a composite formed from a mixture of Si and TiO 2 on the surface of the lithium intercalation compound,
wherein the Si is included in a molar amount of about 0.1 mol % to about 25 mol % based on 100 mol % of the Ti.

2. The positive active material of claim 1 , wherein the Ti is included in a molar amount of about 0.05 mol % to about 2.0 mol % based on 100 mol % of the lithium intercalation compound.

3. The positive active material of claim 1 , wherein the composite formed from the mixture of Si and TiO 2 is included in an amount of about 0.04 wt % to about 1.6 wt % based on 100 wt % of the lithium intercalation compound.

4. The positive active material of claim 1 , wherein the composite formed from the mixture of Si and TiO 2 has an average particle diameter (D50) of about 10 nm to about 300 nm.

5. The positive active material of claim 1 , wherein the composite formed from the mixture of Si and TiO 2 has a layer-type or island-type form on the surface of the lithium intercalation compound.

6. The positive active material of claim 1 , wherein the composite formed from the mixture of Si and TiO 2 is present on the surface of the lithium intercalation compound in a thickness of about 20 nm to about 300 nm.

7. The positive active material of claim 1 , wherein the lithium intercalation compound has an average particle diameter (D50) of about 15 μm to about 20 μm.

8. A rechargeable lithium battery comprising:
a positive electrode including the positive active material of claim 1 ;
a negative electrode including a negative active material; and
an electrolyte.

9. The rechargeable lithium battery of claim 8 , wherein the Ti is included in a molar amount of about 0.05 mol % to about 2.0 mol % based on 100 mol % of the lithium intercalation compound.

10. The rechargeable lithium battery of claim 8 , wherein the composite formed from the mixture of Si and TiO 2 is included in an amount of about 0.04 wt % to about 1.6 wt % based on 100 wt % of the lithium intercalation compound.

11. The rechargeable lithium battery of claim 8 , wherein the composite formed from the mixture of Si and TiO 2 has an average particle diameter (D50) of about 10 nm to about 300 nm.

12. The rechargeable lithium battery of claim 8 , wherein the composite formed from the mixture of Si and TiO 2 has a layer-type or island-type form on the surface of the lithium intercalation compound.

13. The rechargeable lithium battery of claim 8 , wherein the composite formed from the mixture of Si and TiO 2 is present on the surface of the lithium intercalation compound in a thickness of about 20 nm to about 300 nm.

14. The rechargeable lithium battery of claim 8 , wherein the lithium intercalation compound has an average particle diameter (D50) of about 15 μm to about 20 μm.

15. A method of forming a positive active material for a rechargeable lithium battery, the method comprising:
providing a lithium intercalation compound; and
coating a composite formed from a mixture of Si and TiO 2 on the surface of the lithium intercalation compound,
wherein the Si is included in a molar amount of about 0.1 mol % to about 25 mol % based on 100 mol % of the Ti.

16. The method of claim 15 , wherein the composite formed from the mixture of Si and TiO 2 is coated in a layer-type or island-type form on the surface of the lithium intercalation compound.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Kim Jihyun
• Kim Changwook
• Park Sooyoun
• Sheem Kyouyoon
• Je Hyunjoo

Classifications

• H01M2004/028

  Positive electrodes · CPC title

• C01G23/047

  Titanium dioxide · CPC title

• C01P2004/03

  obtained by SEM · CPC title

• H01M10/052

  Li-accumulators · CPC title

• C01P2002/50

  Solid solutions · CPC title