Method for producing gas sensor element

Patent metadata

Field	Value
Publication number	US-10634639-B2
Application number	US-201815974268-A
Country	US
Kind code	B2
Filing date	May 8, 2018
Priority date	May 9, 2017
Publication date	Apr 28, 2020
Grant date	Apr 28, 2020

Abstract

A method for producing a gas sensor element (10), the gas sensor element including a diffusive porous layer (113) disposed in a measurement chamber (111) and exposed to the outside and a ceramic insulating layer (115) forming sidewalls of the measurement chamber. The method includes transferring green diffusive porous layer pieces (113x) cut in advance so as to have prescribed dimensions onto a first ceramic green sheet (110x); applying an insulating paste which later becomes the ceramic insulating layer to the first ceramic green sheet; laminating the first ceramic green sheet onto a second ceramic green sheet (120x) to form a ceramic laminate (200x); cutting the ceramic laminate along prescribed cutting lines C to obtain a plurality of gas sensor element pieces 10x; and firing the gas sensor element pieces.

First claim

What is claimed is:

1. A method for producing gas sensor elements each extending in an axial direction and including a solid electrolyte body, a reference gas-side electrode and a measurement gas-side electrode disposed on surfaces of the solid electrolyte body, a measurement chamber to which the measurement gas-side electrode is exposed, a diffusive porous layer disposed in the measurement chamber and exposed to an outside, and a ceramic insulating layer forming sidewalls of the measurement chamber, the method comprising at least:
a transferring step of preparing a sheet including a plurality of green diffusive porous layer pieces that are cut in advance to have prescribed dimensions and that later become, through firing, the diffusive porous layer and transferring the plurality of green diffusive porous layer pieces from the sheet onto an insulating first ceramic green sheet having a size that allows for production of a plurality of the gas sensor elements therefrom;
an application step of applying an insulating paste that later becomes the ceramic insulating layer through firing to the first ceramic green sheet;
a laminating step of preparing a second ceramic green sheet provided with a plurality of the solid electrolyte bodies each provided with the reference gas-side electrode and the measurement gas-side electrode and laminating the first ceramic green sheet onto the second ceramic green sheet to thereby form a ceramic laminate;
a cutting step of cutting the ceramic laminate along prescribed cutting lines to obtain a plurality of gas sensor element pieces; and
a firing step of firing the gas sensor element pieces to thereby obtain the gas sensor elements.

2. The method for producing gas sensor elements as claimed in claim 1 , wherein, in the transferring step, each green diffusive porous layer piece is transferred such that the green diffusive porous layer piece extends across a corresponding one of the cutting lines and a centerline of the green diffusive porous layer piece extending along its longitudinal direction is aligned with the corresponding one of the cutting lines.

3. The method for producing gas sensor elements as claimed in claim 1 , wherein, in the application step, the insulating paste is applied in a state in which a forward end of an elongated region where the measurement chamber is to be formed is flush with forward ends of the green diffusive porous layer pieces located adjacent to the elongated region.

4. The method for producing gas sensor elements as claimed in claim 2 , wherein, in the application step, the insulating paste is applied in a state in which a forward end of an elongated region where the measurement chamber is to be formed is flush with forward ends of the green diffusive porous layer pieces located adjacent to the elongated region.

Assignees

• Ngk Spark Plug Co

Inventors

• Igarashi Ai
• Toida Kouji
• Kojima Akinori
• Hara Akihiro
• Furuta Hitoshi

Classifications

• C04B37/001

  directly with other burned ceramic articles · CPC title

• C04B2237/62

  Forming laminates or joined articles comprising holes, channels or other types of openings · CPC title

• G01N27/4072 Primary

  characterized by the diffusion barrier · CPC title

• G01N27/40

  Semi-permeable membranes or partitions · CPC title

• B28B1/48

  by removing material from solid section preforms for forming hollow articles, e.g. by punching or boring · CPC title