Propylene-based polymers and plasticizers for use in adhesive compositions

Patent metadata

Field	Value
Publication number	US-10633565-B2
Application number	US-201615148817-A
Country	US
Kind code	B2
Filing date	May 6, 2016
Priority date	Jun 24, 2015
Publication date	Apr 28, 2020
Grant date	Apr 28, 2020

Abstract

The present invention is related to an adhesive composition comprising a 30-80 wt % polymer blend and 2 to about 20 wt % of an oil. The blend has a first and second propylene-based polymer, both different homopolymers of propylene or a copolymer of propylene and ethylene or a C4 to C10 alpha-olefin.

First claim

We claim:

1. An adhesive composition comprising:
(a) about 30 wt % to about 80 wt % of a polymer blend, based on the total weight of the adhesive composition comprising:
a first propylene-based polymer, wherein the first propylene-based polymer is a semi-crystalline copolymer of propylene and ethylene, and wherein the first propylene-based polymer has an ethylene content in the range of about 10 wt % to about 20 wt % based on the weight of the first propylene-based polymer; and
a second propylene-based polymer, wherein the second propylene-based polymer is a copolymer of propylene and ethylene, and wherein the second propylene-based polymer has an ethylene content in the range of about 2 wt % to about 10 wt % based on the weight of the second propylene-based polymer,
wherein the second propylene-based polymer is different than the first propylene-based polymer, and
wherein the polymer blend has a melt viscosity, measured at 190° C. of about 1,000 to about 30,000 cP;

(b) about 1 to about 10 wt % of a propylene-based elastomer having an ethylene content of about 13 wt % a melt mass-flow rate as measured at 230° C. and 2.16 kg of about 48 g/10 min and a density of about 0.865 g/cm 3 ; and
(c) about 2 wt % to about 15 wt % of an oil selected from at least one of a white oil, naphthenic oil, polyalphaolefin, mineral oil, and combinations thereof, based on the total weight of the adhesive composition.

2. The adhesive composition of claim 1 , wherein the composition is substantially free of a wax.

3. The adhesive composition of claim 1 , further comprising a wax, wherein the wax is present in the amount of about 5 wt % to about 10 wt % of the adhesive composition.

4. The adhesive composition of claim 1 , further comprising an antioxidant.

5. The adhesive composition of claim 1 , further comprising a tackifier, where in the tackifier is present in the amount of about 15 wt % to about 60 wt % of the adhesive composition.

6. The adhesive composition of claim 1 , wherein the composition substantially free of sunflower oil or castor oil.

7. An article comprising the adhesive composition of claim 1 , wherein the adhesive composition adheres one or more substrates, and wherein at least one of the one or more substrates comprises paper, cardboard, plastic, nonwoven, metal, wood, other natural fiber based material, or combinations thereof.

8. A process to prepare an adhesive composition, comprising combining:
(a) about 30 wt % to about 80 wt % of a polymer blend, based on the total weight of the adhesive composition, comprising
a first propylene-based polymer, wherein the first propylene-based polymer is a semi-crystalline copolymer of propylene and, and wherein the first propylene-based polymer has an ethylene content in the range of about 10 wt % to about 20 wt % based on the weight of the first propylene-based polymer; and
a second propylene-based polymer, wherein the second propylene-based polymer is a copolymer of propylene and ethylene, and wherein the second propylene-based polymer has an ethylene content in the range of about 2 wt % to about 10 wt % based on the weight of the second propylene-based polymer,
wherein the second propylene-based polymer is different than the first propylene-based polymer, and
wherein the polymer blend has a melt viscosity, measured at 190° C. of about 1,000 to about 30,000 cP;

(b) about 1 to about 10 wt % of a propylene-based elastomer having an ethylene content of about 13 wt % a melt mass-flow rate as measured at 230° C. and 2.16 kg of about 48 g/10 min and a density of about 0.865 g/cm 3 ; and
(c) about 2 wt % to about 15 wt % of an oil selected from at least one of a white oil, naphthenic oil, polyalphaolefin, mineral oil, and combinations thereof, based on the total weight of the adhesive composition.

9. The process of claim 8 , wherein the adhesive composition substantially free of sunflower oil or castor oil.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Austin Jennifer J
• Schroeyers Jurgen J M

Classifications

• C09J123/142

  at least partially crystalline copolymers of propene with other olefins · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L23/10

  Homopolymers or copolymers of propene · CPC title

• C08L23/12

  Polypropene · CPC title

• C09J123/14

  Copolymers of propene (C09J123/16 takes precedence) · CPC title