Resin composition for optical material and optical film comprising the same

Patent metadata

Field	Value
Publication number	US-10633530-B2
Application number	US-201715765298-A
Country	US
Kind code	B2
Filing date	Aug 8, 2017
Priority date	Aug 9, 2016
Publication date	Apr 28, 2020
Grant date	Apr 28, 2020

Abstract

The resin composition for an optical material according to the present invention has features that it can implement a low retardation value during the preparation of an optical film, by using a polycarbonate composition satisfying a specific condition as a retardation-adjusting agent while using polymethyl methacrylate not containing a monomer having a cyclic structure at the main chain of the polymer.

First claim

The invention claimed is:

1. A resin composition for optical material, comprising
1) 90% to 99% by weight of polymethyl methacrylate; and
2) 1% to 10% by weight of polycarbonate,
wherein the polymethyl methacrylate includes methyl acrylate, and
wherein the polymethyl methacrylate does not include a monomer having a cyclic structure,
the polymethyl methacrylate has a glass transition temperature of 100° C. or more and less than 120° C.
the polycarbonate has a glass transition temperature of 125° C. or more and less than 135° C., and
the glass transition temperature difference between the polymethyl methacrylate and the polycarbonate is less than 20° C.

2. The resin composition for optical material according to claim 1 , wherein the polymethyl methacrylate has a glass transition temperature of 110° C. or more and 117° C. or less.

3. The resin composition for optical material according to claim 1 , wherein the polymethyl methacrylate has a weight average molecular weight of 100,000 to 160,000.

4. An optical film comprising the resin composition for optical material according to claim 1 .

5. The optical film according to claim 4 , wherein the optical film is prepared by biaxially stretching the film produced from the resin composition for optical material by 1.5 times to 2.5 times in the machine direction (MD) and by 1.5 times to 3.0 times in the transverse direction (TD).

6. The optical film according to claim 5 , wherein the ratio of the MI) stretching magnification factor and the TD stretching magnification factor (TD stretch ratio/MD stretch ratio) is 1.05 or more and 1.70 or less.

7. The optical film according to claim 5 , wherein the stretching is carried out at a temperature of 10° C. to 30° C. higher than the glass transition temperature of the polymethyl methacrylate.

8. The optical film according to claim 4 , wherein the temperature of thermal shrinkage (TTS) in the MD direction and the TI'S in the TD direction of the optical film are respectively 100° C. to 120° C.

9. The optical film according to claim 4 , wherein the optical film has an impact energy value of the following Mathematical Equation 1 of 400 kN·m/m 3 or more:
Impact energy=(gravitational acceleration×weight of falling-ball×height of falling-ball)/(thickness of optical film×area of optical film)  [Mathematical Equation 1]

wherein the weight of falling ball is 16.4 grams,
the thickness of optical film is from 10 μm to 100 μm, and
the area of optical film is about 20 mm by about 200 mm.

10. The optical film according to claim 4 , wherein the optical film exhibits a retardation of Mathematical Equations 2 and 3:
0 nm≤ R in≤10 nm ( R in=( nx−ny )× d )  [Mathematical Equation 2]

−10 nm≤ Rth≤ 10 nm ( Rth =(( nx+ny )/2− nz )× d )  [Mathematical Equation 3]

in Mathematical Equations 2 and 3,
nx, ny, and nz represent refractive indices in a x-axis direction, a y-axis direction and a z-axis direction, respectively, and d means a thickness (nm) of the optical film.

11. A polarizing plate comprising the optical film according to claim 4 .

12. An optical film comprising a resin composition for optical material, wherein the resin composition comprises:
1) 90% to 99% by weight of polymethyl methacrylate; and
2) 1% to 10% by weight of polycarbonate,
wherein the polymethyl methacrylate includes methyl acrylate, and
wherein the polymethyl methacrylate does not include a monomer having a cyclic,
the polymethyl methacrylate has a glass transition temperature of 100° C. or more and less than 120° C.,
the polycarbonate has a glass transition temperature of 125° C. or more and less than 135° C.,
and
the glass transition temperature difference between the polymethyl methacrylate and the polycarbonate is less than 20° C., wherein the optical film comprises the resin composition, and wherein the optical film exhibits a retardation of Mathematical Equations 2 and 3:
0 nm≤ R in≤10 nm ( R in=( nx−ny )× d )  [Mathematical Equation 2]

−10 nm≤ Rth≤ 10 nm ( Rth =(( nx+ny )/2− nz )× d )  [Mathematical Equation 3]

in Mathematical Equations 2 and 3,
nx, ny, and nz represent refractive indices in an x-axis direction, a y-axis direction and a z-axis direction, respectively, and d means a thickness (nm) of the optical film.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Joong Hoon
• Park Sei Jung
• Hwang Sung Ho
• Mun Byoung Jun
• Song Heon-Sik

Classifications

• C08L69/00

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• B29K2995/0034

  Polarising · CPC title

• G02B1/14

  Protective coatings, e.g. hard coatings · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08L33/12 Primary

  Homopolymers or copolymers of methyl methacrylate · CPC title