Colorant for plastic, coloring composition for plastic using the same, and plastic molded article

Patent metadata

Field	Value
Publication number	US-10633510-B2
Application number	US-201415128431-A
Country	US
Kind code	B2
Filing date	Jul 4, 2014
Priority date	Mar 24, 2014
Publication date	Apr 28, 2020
Grant date	Apr 28, 2020

Abstract

A colorant for plastic containing a halogenated phthalocyanine pigment (A) that satisfies conditions (1) to (4) below: (1) the average number of halogen substitutions is at least 2.0 but not more than 7.0, (2) the halogen distribution width is at least 5, (3) the amount of aluminum phthalocyanine and halogenated aluminum phthalocyanine is not more than 1.0% by mass, and (4) the central element is at least one element selected from the group consisting of hydrogen, manganese, iron, cobalt, zinc, nickel and copper. As a result, a colorant for plastic can be shown that can color a resin without changing the mechanical or chemical properties of the resin, and in particular can produce a plastic molded article having essentially no migration, extremely low discoloration due to heat, and no deformation such as warping and distortion.

First claim

The invention claimed is:

1. A colorant for plastic comprising:
a halogenated phthalocyanine pigment (A) that satisfies conditions (1) to (4) below:
(1) an average number of halogen substitutions is at least 2.0 but not more than 7.0,
(2) a halogen distribution width is at least 5,
(3) an amount of aluminum phthalocyanine and halogenated aluminum phthalocyanine is less than 0.1% by mass, and
(4) a central element is at least one element selected from the group consisting of hydrogen, manganese, iron, cobalt, zinc, nickel and copper; and
a phthalocyanine pigment (B), wherein a central element of the phthalocyanine pigment (B) is copper, an amount of free copper within the phthalocyanine pigment (B) is not more than 200 mg/kg, a crystal form of the phthalocyanine pigment (B) is an α-form or a β-form, and the phthalocyanine pigment (B) has been halogenated so that the average number of halogen substitutions is not more than 1.1,
wherein an amount of the halogenated phthalocyanine pigment (A) is from 10 to 50% by mass relative to a total mass of the halogenated phthalocyanine pigment (A) and the phthalocyanine pigment (B).

2. The colorant for plastic according to claim 1 , wherein an amount of free copper within the halogenated phthalocyanine pigment (A) is not more than 200 mg/kg.

3. A coloring composition for plastic comprising the colorant for plastic according to claim 1 .

4. The coloring composition for plastic according to claim 3 , further comprising at least one compound selected from the group consisting of aromatic carboxylic acids, aliphatic carboxylic acids, metal salts of aromatic carboxylic acids, metal salts of aliphatic carboxylic acids, and aliphatic carboxylic acid esters.

5. The coloring composition for plastic according to claim 3 , further comprising a resin.

6. The coloring composition for plastic according to claim 5 , wherein the resin comprises a polyethylene wax.

7. A plastic molded article molded using the coloring composition for plastic according to claim 3 .

8. The colorant for plastic according to claim 1 , wherein
the average number of halogen substitutions is at least 3.0 but not more than 7.0,
the halogen distribution width is at least 5 but not more than 7,
an amount of free copper within the halogenated phthalocyanine pigment (A) is not more than 200 mg/kg, and
the crystal form of the phthalocyanine pigment (B) is the α-form.

9. The colorant for plastic according to claim 1 , wherein the halogen distribution width is at least 5 and not more than 6.

10. The colorant for plastic according to claim 1 , wherein the crystal form of the phthalocyanine pigment (B) is the α-form.

Assignees

• Toyo Ink Sc Holdings Co Ltd
• Toyocolor Co Ltd

Inventors

• Takahata Noriyoshi
• Mochizuki Akimitsu
• Hamada Naoki
• Kasuya Takashi

Classifications

• C09B67/0019

  of phthalocyanines · CPC title

• C08K5/0091 Primary

  Complexes with metal-heteroatom-bonds · CPC title

• C08K5/0041

  Optical brightening agents, organic pigments · CPC title

• C08L101/00

  Compositions of unspecified macromolecular compounds · CPC title

• C09B67/0035

  Mixtures of phthalocyanines · CPC title