Methods for plasticizing poly(ethylene furanoate) films by water sorption

US10633501B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-10633501-B2
Application numberUS-201515511450-A
CountryUS
Kind codeB2
Filing dateSep 15, 2015
Priority dateSep 16, 2014
Publication dateApr 28, 2020
Grant dateApr 28, 2020

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  1. Title

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  2. Abstract

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  3. Assignees and inventors

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  4. Key dates

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  5. First independent claim

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  6. CPC / IPC classifications

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  7. Citations and related patents

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Abstract

Official abstract text for this publication.

This disclosure provides an investigation of the kinetic uptake properties of water in amorphous PEF and PET across the entire water activity interval at various temperatures, and also investigates the corresponding equilibrium uptake properties at the same conditions. Uptake data were measured using three independent and complementary methodologies, and excellent agreement was observed among all three methodologies. Accordingly, this disclosure provides for methods of plasticizing poly(ethylene furanoate) film by cold water sorption, and provides a plasticized poly(ethylene furanoate) (PEF) film made according to the disclosed methods. Methods for making thin films of PEF are also provided.

First claim

Opening claim text (preview).

We claim: 1. A method of modifying a poly(ethylene furanoate) film, the method comprising: a) plasticizing a poly(ethylene furanoate) (PEF) film by contacting the PEF film with (1) water at a temperature at or below 25° C. for a time period from about 0.25 h to about 40 h or (2) at least about 90% relative humidity air at a temperature at or below 25° C. for a time period from about 1 h to about 40 h; and b) subjecting the plasticized PEF film to a dynamic strain oscillation within the PEF linear viscoelastic range. 2. The method of claim 1 , wherein the PEF film is contacted with at least about 90% relative humidity air at a temperature at or below 25° C. for a time period from about 1 h to about 25 h. 3. The method of claim 1 , wherein the PEF film is contacted with water at a temperature at or below 25° C. for a time period from about 0.5 h to about 25 h. 4. A poly(ethylene furanoate) (PEF) film modified according to the method of claim 1 . 5. A method of modifying a poly(ethylene furanoate) film, the method comprising: a) plasticizing a poly(ethylene furanoate) (PEF) film by contacting the PEF film with (1) water at a temperature greater than 25° C. for a time period from about 0.5 h to about 25 h or (2) at least about 90% relative humidity air at a temperature greater than 25° C. for a time period from about 1 h to about 25 h; and b) subjecting the plasticized PEF film to a dynamic strain oscillation within the PEF linear viscoelastic range. 6. A poly(ethylene furanoate) (PEF) film modified according to the method of claim 5 . 7. A method of modifying a poly(ethylene furanoate) film, the method comprising: a) plasticizing a poly(ethylene furanoate) (PEF) film by contacting the PEF film with at least about 95% relative humidity air at a temperature at or below 25° C. for a time period from about 0.25 h to about 50 h; and b) subjecting the plasticized PEF film to a dynamic strain oscillation within the PEF linear viscoelastic range. 8. A poly(ethylene furanoate) (PEF) film modified according to the method of claim 7 . 9. A method of modifying a poly(ethylene furanoate) film, the method comprising: a) plasticizing a poly(ethylene furanoate) (PEF) film by contacting the PEF film with at least about 95% relative humidity air at a temperature greater than 25° C. for a time period from about 0.5 h to about 50 h; and b) subjecting the plasticized PEF film to a dynamic strain oscillation within the PEF linear viscoelastic range. 10. A poly(ethylene furanoate) (PEF) film modified according to the method of claim 9 .

Assignees

Inventors

Classifications

  • Use of polyesters {or derivatives thereof}, as moulding material · CPC title

  • biaxial · CPC title

  • Plasticising macromolecular compounds (plasticisers C08K) · CPC title

  • Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

  • C08J7/02Primary

    with solvents, e.g. swelling agents · CPC title

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What does patent US10633501B2 cover?
This disclosure provides an investigation of the kinetic uptake properties of water in amorphous PEF and PET across the entire water activity interval at various temperatures, and also investigates the corresponding equilibrium uptake properties at the same conditions. Uptake data were measured using three independent and complementary methodologies, and excellent agreement was observed among a…
Who is the assignee on this patent?
Coca Cola Co, Georgia Tech Res Inst
What technology area does this patent fall under?
Primary CPC classification C08J7/02. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Apr 28 2020 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 1 related publication on this page (citations in our corpus or others sharing the same primary CPC).