Method of making a urea product

Patent metadata

Field	Value
Publication number	US-10633331-B2
Application number	US-201515326434-A
Country	US
Kind code	B2
Filing date	Jul 16, 2015
Priority date	Jul 17, 2014
Publication date	Apr 28, 2020
Grant date	Apr 28, 2020

Abstract

Disclosed is a process for the preparation of a urea product suitable for being diluted with water so as to form an aqueous urea comprising solution for use in a unit for the reduction of NOx in combustion engine exhaust gases, also known as Diesel Exhaust Fluid (DEF) or to be used in De NOx systems of exhaust vapor from industrial furnaces. The process comprises obtaining an aqueous urea solution from or after a recovery section in a urea production process. This solution, which has a low content of impurities, is subjected to flash crystallization at a low pressure, so as to obtain a solid crystallized urea containing product, which is a free-flowing powder containing less than 0.2 wt. % water. This product is packaged under conditions such that the water content in the packaged product is maintained below 0.2 wt. %. The invention can also be used in a method of increasing the capacity of an existing urea plant.

First claim

The invention claimed is:

1. A method for the production of a packaged product which is a free-flowing urea suitable for easily dissolving in water to obtain an aqueous urea comprising solution, the process comprising:
(a) obtaining an aqueous urea stream from or after a recovery section in a urea production process;
(b) subjecting said aqueous urea stream to flash crystallization at subatmospheric pressure, so as to obtain a free flowing crystallized urea powder and an ammonia and water containing vapor, wherein the crystallized urea powder contains less than 0.2 wt. % water;
(c) directly packaging the crystallized urea powder as obtained in (b) into a non-water permeable package under conditions such that the water content in the packaged product is maintained below 0.2 wt. % to obtain said packaged product which is a free-flowing urea powder.

2. The method of claim 1 , wherein the flash crystallization is conducted at a pressure below 15 kPa.

3. The method of claim 1 , wherein the flash crystallization is conducted as dry flashing.

4. The method of claim 1 , wherein the aqueous urea comprising solution is suitable for use in a unit for the reduction of NOx in combustion engine exhaust gases.

5. The method of claim 1 , wherein the aqueous urea stream subjected to flash crystallization of (b) has a urea concentration in a range of from 85 wt. % to 95 wt. %.

6. The method of claim 1 , wherein the biuret content of the crystallized urea powder obtained in (b) is at most 0.5 wt. %.

7. The method of claim 1 , wherein the crystallized urea powder obtained in (b) has a particle size in the range of from 1 μm to 800 μm.

8. A method of making an aqueous solution comprising 30-70 wt. % urea, which method comprises dissolving the crystallized urea powder obtainable by the method of claim 1 .

9. The method of claim 8 that results in an aqueous urea comprising solution comprising 30-35 wt. % urea suitable for use in a unit for the reduction of NOx in combustion engine exhaust gases.

10. The method of claim 8 that results in an aqueous urea comprising solution suitable for use in a unit for the reduction of NOx in exhaust vapors from industrial furnaces.

11. The method of claim 2 , wherein the flash crystallization in (b) is conducted at a pressure from 1 to 10 kPa.

12. The method of claim 1 , wherein the aqueous urea stream subjected to flash crystallization of (b) has a urea concentration in a range of between 87 wt. % and 92 wt. %.

Assignees

• Stamicarbon

Inventors

• Mennen Johannes Henricus

Classifications

• B01D21/262

  by using a centrifuge · CPC title

• B01D9/0022

  by reducing pressure · CPC title

• C07C273/16 Primary

  Separation; Purification · CPC title

• C07C275/02

  Salts; Complexes; Addition compounds · CPC title