Hardener composition for addition-polymerisation-based synthetic fixing mortar systems, and the use and production thereof
US-2017253529-A1 · Sep 7, 2017 · US
US10633286B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10633286-B2 |
| Application number | US-201716326386-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 20, 2017 |
| Priority date | Aug 30, 2016 |
| Publication date | Apr 28, 2020 |
| Grant date | Apr 28, 2020 |
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A two-component mortar compound contains at least one resin component (A), which, as the curable ingredient, contains at least one epoxy-base resin that can be polymerized by addition reaction; and a hardener component (B), which contains a hardening agent for the resin of the resin component (A), wherein at least one of the components contains at least one siloxane, which has at least one functional moiety that is capable of addition reaction with an epoxide but does not have any hydrolyzable group bound to a silicon atom, especially no alkoxy moieties.
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The invention claimed is: 1. A two-component mortar composition, comprising: at least one resin component (A), which contains at least one epoxy-base resin as a curable ingredient that can be polymerized by addition reaction; and a hardener component (B), which contains a hardening agent for the resin of the resin component (A), wherein at least one of the components contains at least one siloxane which has at least one functional moiety that is capable of addition reaction with an epoxide but does not have any hydrolyzable group bound to a silicon atom. 2. The two-component mortar composition according to claim 1 , wherein the functional moiety capable of addition reaction with epoxy groups is a terminal moiety. 3. The two-component mortar composition according to claim 2 , wherein the functional moiety is selected from the group consisting of hydroxy, carboxy, amino, sec-amino, mercapto, isocyanato, alkenyl, (meth)acryloyl, anhydrido and epoxy moieties. 4. The two-component mortar composition according to claim 1 , wherein the siloxane has the structure R 3 Si—[O—Si(R 1 ) 2 ]n-O—SiR 3 , where n stands for 0 or a whole number from 1 to 1000 inclusive, R and R 1 , independently of one another, respectively stand for a C 1 -C 20 alkyl moiety or aralkyl moiety that optionally contains a hetero atom and optionally has at least one moiety capable of addition reaction with an epoxy group. 5. The two-component mortar composition according to claim 1 , wherein the siloxane has two or more identical or different terminal functional moieties capable of addition reaction with an epoxy group. 6. The two-component mortar composition according to claim 1 , wherein the siloxane is selected from the group consisting of 1,3-bis(2-aminoethylaminoethyl)tetramethyldisiloxane, 1,3-bis(glycidoxypropyl)tetramethyl-disiloxane, tris(glycidoxypropyldimethylsiloxy)phenylsilane, 3-methacryloxy-propylpentamethyldisiloxane, poly(acryloxypropylmethyl)siloxane, 1,3-bis(acryloxypropylmethyl)siloxane, 1,3-bis(3-methacryloxypropyl)tetrakis-(trimethylsiloxy)disiloxane, 1,3-bis(3-methacryloxypropyl)tetramethyldisiloxane, monomethacryloxypropyl-terminated polydimethylsiloxane, poly[dimethylsiloxane-co-(3-(monomethacryloxy)propyl)methylsiloxane], 1,3-bis(4-methacryloxybutyl)-tetramethyldisiloxane, (methacryloxypropyl)methylsiloxane/dimethylsiloxane copolymer, dodecamethylpentasiloxane, 1,1,1,3,5,7,7,7-octamethyl-3,5-bis(trimethylsilanyloxy)tetrasiloxane, trimethylsilyl-terminated poly(methylhydrosiloxane), bis(hydroxyalkyl)-terminated poly(dimethylsiloxane), poly[di-methylsiloxane-co-(2-(3,4-epoxycyclohexyl)ethyl)methylsiloxane], diglycidylether-terminated poly(dimethylsiloxane), poly[dimethylsiloxane-co-[3-(2-(3-hydroxy-ethoxy)ethoxy)propyl]methylsiloxane] and monoglycidylether-terminated poly(di-methylsiloxane). 7. The two-component mortar composition according to claim 1 , wherein a proportion of the siloxane is 0.5 to 20 wt %, relative to the total weight of the two-component composition. 8. The two-component mortar composition according to claim 1 , wherein the resin component (A) and/or the hardener component (B) contains at least one thixotropic agent as a further ingredient. 9. The two-component mortar composition according to claim 1 , wherein the resin component (A) and/or the hardener component (B) contains at least one inorganic filler as a further ingredient. 10. The two-component mortar composition according to claim 1 , wherein the composition is present in a casing, a cartridge or a foil bag, wherein the resin component (A) and the hardener component (B) are disposed in chambers separated from one another. 11. A method for chemical fastening of a structural part which is present in a mineral substrate, said method comprising: applying the composition of claim 1 to the mineral substrate and/or the structural part; wherein said structural part is selected from the group consisting of a threaded anchor rod, a rebar, a threaded sleeve and a screw in a drilled hole.
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