Method and device for treating and utilizing bypass dusts

Patent metadata

Field	Value
Publication number	US-10633283-B2
Application number	US-201615577225-A
Country	US
Kind code	B2
Filing date	May 20, 2016
Priority date	May 28, 2015
Publication date	Apr 28, 2020
Grant date	Apr 28, 2020

Abstract

A method for treating and utilizing bypass dusts from a cement production process involves a) contacting the bypass dust with an aqueous phase and mixing the same to obtain a suspension, wherein water-soluble components of the bypass dust are dissolved in the aqueous phase; b) performing a solid/liquid separation, in particular a vacuum filtration or a filter press filtration, to separate the solids contained in the suspension, wherein a brine remains; c) precipitating a partial amount of the heavy metals present in the brine, and optionally Ca, and separating the precipitate from the brine; and d) subjecting the brine to an electrocoagulation, wherein a flocculate containing the heavy metals remaining in the brine is separated.

First claim

The invention claimed is:

1. A method for treating and utilizing bypass dusts from a cement production process, comprising the steps of
a) contacting the bypass dust with an aqueous phase and mixing the same to obtain a homogenous suspension, wherein water-soluble components of the bypass dust are dissolved in the aqueous phase,
b) performing a solid/liquid separation in order to separate the solids contained in the suspension, wherein a brine remains,
c) precipitating a partial amount of the heavy metals present in the brine, and optionally Ca, and separating the precipitate from the brine,
d) subjecting the brine to an electrocoagulation, wherein a flocculate containing the heavy metals remaining in the brine is separated.

2. The method according to claim 1 , wherein step c), the precipitating comprises adding a precipitant.

3. The method according to claim 2 , wherein the precipitant comprises CO 2 or a carbonate(s), wherein the carbonate(s) comprises an alkali carbonate.

4. The method according to claim 3 , wherein the alkali carbonate comprises Na 2 CO 3 or K 2 CO 3 .

5. The method according to claim 2 , wherein the precipitant comprises CO 2 -containing exhaust gas from a kiln.

6. The method according to claim 1 , wherein step c), the precipitating comprises reducing the pH of the brine.

7. The method according to claim 6 , wherein the pH of the brine is reduced by adding an inorganic acid comprising HCl or H 2 SO 4 .

8. The method according to claim 1 , wherein the method further comprises subjecting a treated brine obtained according to step d) to fractional crystallization.

9. The method according to claim 1 , wherein in step c), the separating comprises gravity sedimentation.

10. The method according to claim 1 , wherein separating the flocculate in step d) further comprises filtering or centrifuging out the flocculate.

11. The method according to claim 10 , wherein the filtering comprises using a filter press.

12. The method according to claim 1 , wherein the solid-liquid separation according to step b) is performed by a continuous separation method, wherein the suspension and an aqueous phase are conducted in counter-current, and contacted, in a continuously operating separation device comprising a belt filter or vacuum belt filter.

13. The method according to claim 1 , wherein said method further comprises, after optionally drying the solids separated in step c) and/or step d), returning the solids recovered as a cement grinding additive(s) or as raw meal component to a cement production process.

14. The method according to claim 1 , wherein the electrocoagulation in step d) is conducted using a Fe and/or Al anode.

15. The method according to claim 1 , wherein in step c) a calcium salt is precipitated, and wherein the precipitated calcium salt from step c) is added to the suspension in step a) and separated as a solid in step b).

16. The method according to claim 1 , wherein the solid/liquid separation comprises a vacuum filtration or a filter press filtration.

17. An apparatus adapted and configured for carrying out the method according to claim 1 , wherein said device comprises
a mixing device for contacting the bypass dust with an aqueous phase,
a first separation device for performing a solid-liquid separation on a mixture obtained from the mixing device, wherein the first separation device is arranged upwards the electrocoagulation device, and
a treatment device downstream of the first separation device for treating the brine discharged from the first separation device, said treatment device comprising an electrocoagulation device that is separate from the mixing device.

18. The apparatus according to claim 17 , wherein the apparatus further comprises a second separation device for separating the flocculate obtained in the electrocoagulation device, said second separation device comprising a centrifuge or a filtration device.

19. The apparatus according to claim 17 , wherein the treatment device further comprises a bath before the electrocoagulation device and including a mixing device for precipitating calcium and a partial amount of the heavy metals present in the brine.

20. The apparatus according to claim 17 , wherein the electrocoagulation device comprises a Fe and/or Al anode.

21. The apparatus according to claim 17 , wherein the apparatus further comprises a device for carrying out a fractional crystallization treatment following the treatment device.

22. The apparatus according to claim 17 , wherein the first separation device for performing a solid-liquid separation is a separation device for performing a vacuum filtration or a filter press filtration.

Assignees

• Holcim Technology Ltd

Inventors

• Zihlmann Serge Lukas
• Gross Florian Christian

Classifications

• C04B7/436 Primary

  Special arrangements for treating part or all of the cement kiln dust · CPC title

• C04B7/60

  Methods for eliminating alkali metals or compounds thereof {, e.g. from the raw materials or during the burning process; methods for eliminating other harmful components (avoiding environmental pollution C04B7/364)} · CPC title

• C02F9/00

  Multistage treatment of water, waste water or sewage · CPC title

• C02F2103/34

  from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 · CPC title

• B01D47/02

  by passing the gas or air or vapour over or through a liquid bath · CPC title