Glasses with low excess modifier content

Patent metadata

Field	Value
Publication number	US-10633279-B2
Application number	US-201816202691-A
Country	US
Kind code	B2
Filing date	Nov 28, 2018
Priority date	Nov 29, 2017
Publication date	Apr 28, 2020
Grant date	Apr 28, 2020

Abstract

A glass composition includes: from 55.0 mol % to 70.0 mol % SiO 2 ; from 12.0 mol % to 20.0 mol % Al 2 O 3 ; from 5.0 mol % to 15.0 mol % Li 2 O; and from 4.0 mol % to 15.0 mol % Na 2 O. The glass composition has the following relationships −8.00 mol %≤R 2 O+RO—Al 2 O 3 —B 2 O 3 —P 2 O 5 ≤−1.75 mol %, 9.00≤(SiO 2 +Al 2 O 3 +Li 2 O)/Na 2 O, and (Li 2 O+Al 2 O 3 +P 2 O 5 )/(Na 2 O+B 2 O 3 )≤3.50. The glass composition may be used in a glass article or a consumer electronic product.

First claim

What is claimed is:

1. A glass composition comprising:
from greater than or equal to 55.0 mol % to less than or equal to 70.0 mol % SiO 2 ;
from greater than or equal to 12.0 mol % to less than or equal to 20.0 mol % Al 2 O 3 ;
from greater than 0 mol % to less than or equal to 7.5 mol % B 2 O 3 ;
from greater than or equal to 5.0 mol % to less than or equal to 15.0 mol % Li 2 O; and
from greater than or equal to 4.0 mol % to less than or equal to 9.5 mol % Na 2 O, wherein:
−8.00 mol %≤R 2 O+RO—Al 2 O 3 —B 2 O 3 —P 2 O 5 ≤−1.75 mol %,
9.10≤(SiO 2 +Al 2 O 3 +Li 2 O)/Na 2 O,
1.80≤(Li 2 O+Al 2 O 3 +P 2 O 5 )/(Na 2 O+B 2 O 3 )≤3.50,
Al 2 O 3 +Li 2 O is greater than 21.4 mol %, and
RO is a sum of divalent cation oxides selected from the group consisting of MgO, CaO, SrO, BaO, FeO, and ZnO, and R 2 O is a sum of alkali metal oxides selected from the group consisting of Li 2 O, Na 2 O, K 2 O, Rb 2 O, Cs 2 O, and Fr 2 O.

2. The glass composition of claim 1 , wherein −7.50 mol %≤R 2 O+RO—Al 2 O 3 —B 2 O 3 —P 2 O 5 ≤−2.50 mol %.

3. The glass composition of claim 1 , wherein 9.10≤(SiO 2 +Al 2 O 3 +Li 2 O)/Na 2 O≤16.00.

4. The glass composition of claim 1 , wherein 9.20≤(SiO 2 +Al 2 O 3 +Li 2 O)/Na 2 O≤15.50.

5. The glass composition of claim 1 , wherein 1.80≤(Li 2 O+Al 2 O 3 +P 2 O 5 )/(Na 2 O+B 2 O 3 )≤3.35.

6. The glass composition of claim 1 , wherein B 2 O 3 +P 2 O 5 is greater than 0.0 mol %.

7. The glass composition of claim 1 , wherein 1.00≤(Li 2 O+Al 2 O 3 )/(Na 2 O+B 2 O 3 +P 2 O 5 )≤2.75.

8. The glass composition of claim 1 , wherein Al 2 O 3 +Li 2 O+Na 2 O is greater than 25.0 mol %.

9. The glass composition of claim 1 , wherein 0.90<Al 2 O 3 /(R 2 O+RO)<1.20.

10. The glass composition of claim 1 , wherein 1.0<(Al 2 O 3 +B 2 O 3 +P 2 O 5 )/(R 2 O+RO).

11. The glass composition of claim 1 , wherein 6.96Al 2 O 3 −1.90B 2 O 3 +2.16CaO+3.30MgO−1.50Na 2 O+12.74Li 2 O−1.10SrO−14.50K 2 O−1.87La 2 O 3 +6.13ZrO 2 −76.40 mol %>50.00 mol %.

12. A glass composition comprising:
from greater than or equal to 60.0 mol % to less than or equal to 70.0 mol % SiO 2 ;
from greater than or equal to 12.0 mol % to less than or equal to 18.0 mol % Al 2 O 3 ;
from greater than 0 mol % to less than or equal to 7.5 mol % B 2 O 3 ;
from greater than or equal to 5.0 mol % to less than or equal to 10.0 mol % Li 2 O;
from greater than or equal to 4.0 mol % to less than or equal to 9.5 mol % Na 2 O; and
greater than or equal to 0.75 mol % P 2 O 5 , wherein:
Li 2 O/Na 2 O greater than or equal to 1.00, and
Al 2 O 3 +Li 2 O less than or equal to 25.25 mol % and greater than 21.4 mol %.

Assignees

• Corning Inc

Inventors

• Gross Timothy Michael
• Guo Xiaoju
• Lezzi Peter Joseph
• Mitchell Alexandra Lai Ching Kao Andrews
• Roussev Rostislav Vatchev

Classifications

• C03C3/091

  containing aluminium · CPC title

• C03C3/085 Primary

  containing an oxide of a divalent metal · CPC title

• C03C4/18

  for ion-sensitive glass · CPC title

• C03C3/097 Primary

  containing phosphorus, niobium or tantalum · CPC title

• C03C2204/00

  Glasses, glazes or enamels with special properties · CPC title