Flow battery that includes redox mediator

Patent metadata

Field	Value
Publication number	US-10629910-B2
Application number	US-201816010164-A
Country	US
Kind code	B2
Filing date	Jun 15, 2018
Priority date	Jul 13, 2017
Publication date	Apr 21, 2020
Grant date	Apr 21, 2020

Abstract

A flow battery includes: a liquid including a redox mediator; an electrode at least partially immersed in the liquid; a second electrode; an active material at least partially immersed in the liquid, and a circulator that circulates the liquid between the electrode and the active material.

First claim

What is claimed is:

1. A flow battery comprising:
a liquid including a redox mediator;
an electrode at least partially immersed in the liquid;
an active material at least partially immersed in the liquid; and
a circulator that circulates the liquid between the electrode and the active material,
wherein the redox mediator includes a compound represented by the following general formula (1):

where R 1 to R 6 each independently denote a hydrogen atom, a chain saturated hydrocarbon group, a chain unsaturated hydrocarbon group, a cyclic saturated hydrocarbon group, or a cyclic unsaturated hydrocarbon group,
R 1 to R 6 may each independently include at least one selected from the group consisting of an oxygen atom, a nitrogen atom, a sulfur atom, and a silicon atom, and
the compound represented by the general formula (1) is a compound represented by the following general formula (2):

where R 5 to R 10 each independently denote a hydrogen atom, a chain saturated hydrocarbon group, a chain unsaturated hydrocarbon group, a cyclic saturated hydrocarbon group, or a cyclic unsaturated hydrocarbon group, and
R 5 to R 10 may each independently include at least one selected from the group consisting of an oxygen atom, a nitrogen atom, a sulfur atom, and a silicon atom.

2. The flow battery according to claim 1 , wherein R 1 , R 2 , R 3 , and R 4 each independently denote a hydrogen atom, a straight-chain saturated hydrocarbon group, or a straight-chain unsaturated hydrocarbon group, and
the straight-chain saturated hydrocarbon group and the straight-chain unsaturated hydrocarbon group may each independently include at least one sulfur atom.

3. The flow battery according to claim 1 , wherein R 1 , R 2 , R 3 , and R 4 each independently denote a hydrogen atom or SCH 3 .

4. The flow battery according to claim 1 , wherein R 5 and R 6 each independently denote a hydrogen atom or an aromatic group.

5. A flow battery comprising:
a liquid including a redox mediator;
an electrode at least partially immersed in the liquid;
an active material at least partially immersed in the liquid; and
a circulator that circulates the liquid between the electrode and the active material,
wherein the redox mediator includes a compound represented by the following general formula (1):

where R 1 to R 6 each independently denote a hydrogen atom, a chain saturated hydrocarbon group, a chain unsaturated hydrocarbon group, a cyclic saturated hydrocarbon group, or a cyclic unsaturated hydrocarbon group,
R 1 to R 6 may each independently include at least one selected from the group consisting of an oxygen atom, a nitrogen atom, a sulfur atom, and a silicon atom, and
the compound represented by the general formula (1) is a compound represented by the following formula (3)

6. A flow battery comprising:
a liquid including a redox mediator;
an electrode at least partially immersed in the liquid;
an active material at least partially immersed in the liquid; and
a circulator that circulates the liquid between the electrode and the active material,
wherein the redox mediator includes a compound represented by the following general formula (1):

where R 1 to R 6 each independently denote a hydrogen atom, a chain saturated hydrocarbon group, a chain unsaturated hydrocarbon group, a cyclic saturated hydrocarbon group, or a cyclic unsaturated hydrocarbon group,
R 1 to R 6 may each independently include at least one selected from the group consisting of an oxygen atom, a nitrogen atom, a sulfur atom, and a silicon atom, and
the compound represented by the general formula (1) is a compound represented by the following formula (4)

7. The flow battery according to claim 1 , wherein
the circulator includes a container,
the active material and at least part of the liquid are housed in the container, and are in contact with each other to cause at least either an oxidation reaction or a reduction reaction between the active material and the redox mediator, and
the circulator circulates the liquid between the electrode and the container.

8. The flow battery according to claim 5 , wherein
the circulator includes a container,
the active material and at least part of the liquid are housed in the container, and are in contact with each other to cause at least either an oxidation reaction or a reduction reaction between the active material and the redox mediator, and
the circulator circulates the liquid between the electrode and the container.

9. The flow battery according to claim 6 , wherein
the circulator includes a container,
the active material and at least part of the liquid are housed in the container, and are in contact with each other to cause at least either an oxidation reaction or a reduction reaction between the active material and the redox mediator, and
the circulator circulates the liquid between the electrode and the container.

10. The flow battery according to claim 1 , wherein
the circulator includes a transfer prevention filter unit that prevents transfer of the active material, and
the transfer prevention filter unit is disposed on a path through which the liquid flows from the container to the electrode.

11. The flow battery according to claim 5 , wherein
the circulator includes a transfer prevention filter unit that prevents transfer of the active material, and
the transfer prevention filter unit is disposed on a path through which the liquid flows from the container to the electrode.

12. The flow battery according to claim 6 , wherein
the circulator includes a transfer prevention filter unit that prevents transfer of the active material, and
the transfer prevention filter unit is disposed on a path through which the liquid flows from the container to the electrode.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Otsuka yu

Classifications

• H01M8/04186

  of liquid-charged or electrolyte-charged reactants · CPC title

• H01M8/04201

  Reactant storage and supply, e.g. means for feeding, pipes · CPC title

• H01M8/188

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M4/60 Primary

  of organic compounds · CPC title

• H01M4/368

  Liquid depolarisers · CPC title