Cathode material for a lithium-sulphur cell

Patent metadata

Field	Value
Publication number	US-10629894-B2
Application number	US-201515315764-A
Country	US
Kind code	B2
Filing date	Jun 5, 2015
Priority date	Jun 6, 2014
Publication date	Apr 21, 2020
Grant date	Apr 21, 2020

Abstract

A cathode material for an electrochemical cell, in particular a lithium-sulfur cell, including at least one cathode active material and at least one in particular lithium ion-conducting or lithium ion-conductive polymer electrolyte and/or at least one inorganic ion conductor, in particular a lithium ion conductor. The at least one cathode active material includes a polymer containing in particular covalently bound sulfur. Moreover, also described is a cell and a battery equipped with same.

First claim

What is claimed is:

1. A cathode material for an alkali metal-sulfur cell or a lithium-sulfur cell, comprising:
at least one cathode active material, wherein the at least one cathode active material includes a polymer containing covalently bound sulfur;
at least one lithium ion-conducting or lithium ion-conductive polymer electrolyte and/or at least one inorganic ion conductor; and
(a) at least one metal sulfide, wherein the at least one metal sulfide is one of (i) at least one transition metal sulfide, or (ii) at least one metal sulfide of at least one metal of the third, fourth, and/or fifth main group; and/or (b) at least one electrically conductive metal compound, wherein the at least one electrically conductive metal compound is one of (i) at least one electrically conducting metal oxide or (ii) at least one electrically conducting metal carbide,
wherein the at least one metal sulfide includes electrochemically active sulfur, contains more than one sulfur atom for each metal atom, or contains more than one metal atom for each sulfur atom.

2. The cathode material of claim 1 , wherein the at least one transition metal sulfide and/or the at least one metal sulfide of at least one metal of the third, fourth, and/or fifth main group is contained or incorporated, in the at least one cathode active material, in the polymer containing covalently bound sulfur.

3. An alkali metal-sulfur cell or a lithium-sulfur cell, comprising:
a cathode material, including:
at least one cathode active material;
at least one lithium ion-conducting or lithium ion-conductive polymer electrolyte and/or at least one inorganic ion conductor;
wherein the at least one cathode active material includes a polymer containing covalently bound sulfur, and
wherein the polymer containing covalently bound sulfur, and the at least one polymer electrolyte and/or the at least one inorganic ion conductor form ion-conductive or ion-conducting channels that extend along a polymer backbone of the polymer containing covalently bound sulfur and/or of the at least one polymer electrolyte;

a cathode;
an anode; and
a separator and/or a protective layer between the cathode and the anode,
wherein the separator and/or the protective layer includes
at least one polystyrene-polyethylene oxide block copolymer that includes at least one polystyrene component, at least one polyethylene oxide component, and at least one polyisoprene component,
at least one polyacrylate-polyethylene oxide block copolymer that includes at least one polyacrylate component, at least one polyethylene oxide component, and at least one polyisoprene component, and at least one polymer electrolyte, which includes at least one repeating unit of the general chemical formula:

wherein:
-[A]- stands for a polymer backbone-forming unit,
X stands for a spacer,
x stands for the number of spacers X and is 1 or 0, and
Q stands for a positively charged group Q + and a counterion Z − , or Q stands for a negatively charged group Q and a counterion Z + , or Q stands for an uncharged group.

Assignees

• Bosch Gmbh Robert

Inventors

• Fanous Jean
• Schumann Bernd
• Thielen Joerg

Classifications

• H01M10/052

  Li-accumulators · CPC title

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title

• H01M4/137

  Electrodes based on electro-active polymers · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/5815

  Sulfides · CPC title